Nature of the Diffusion Process in Rubber

1937 ◽  
Vol 10 (4) ◽  
pp. 673-674 ◽  
Author(s):  
Richard M. Barrer

Abstract It is known that silica-gas diffusion systems exemplify a type of non-specific activated diffusion process, as opposed to the specific type of diffusion system, such as hydrogen-palladium. It seemed that the diffusion of gases through other “glass-like” materials such as some organic membranes, for example rubber, might offer further examples of non-specific activated diffusion. The data needed to test this hypothesis were available in papers by Edwards and Pickering, and by Dewar. Graham first noted the large temperature coefficient of the diffusion process through rubber, and that the diffusion velocities had no connection with the molecular weights.

1921 ◽  
Vol 3 (3) ◽  
pp. 285-290 ◽  
Author(s):  
Selig Hecht

The temperature coefficient of the bleaching of visual purple by light is 1.00 over a range of 30 degrees. This indicates that the monomolecular course of the reaction represents a real chemical process, as opposed to a possible diffusion process, and that the reaction is probably simple in nature.


2004 ◽  
Vol 43 (No. 8B) ◽  
pp. L1054-L1056 ◽  
Author(s):  
Kais Daoudi ◽  
Tetsuo Tsuchiya ◽  
Susumu Mizuta ◽  
Iwao Yamaguchi ◽  
Takaaki Manabe ◽  
...  

2020 ◽  
Vol 116 (20) ◽  
pp. 203105 ◽  
Author(s):  
Asir Intisar Khan ◽  
Pedram Khakbaz ◽  
Kevin A. Brenner ◽  
Kirby K. H. Smithe ◽  
Michal J. Mleczko ◽  
...  

2009 ◽  
Vol 283-286 ◽  
pp. 583-588
Author(s):  
J. Escudero ◽  
J. Lázaro ◽  
E. Solórzano ◽  
Miguel A. Rodríguez-Pérez ◽  
Jose A. de Saja

In this work, the effective diffusion coefficient of the gas contained in closed cell polyethylene foams under static loading is measured. To do this, compressive creep experiments were performed on low density polyethylene foams produced under a gas diffusion process. Density dependence of this coefficient has been analysed as well as the variation of pressure with time inside the cells. Finally, immediately after compressive creep, the recovery behaviour of the foams was also characterised. Different abilities for recovering were observed depending on the density of the foam and the absolute recovery resulted independent of the initial stress applied.


2015 ◽  
Vol 3 (34) ◽  
pp. 8776-8779 ◽  
Author(s):  
Toan Dinh ◽  
Hoang-Phuong Phan ◽  
Dzung Viet Dao ◽  
Peter Woodfield ◽  
Afzaal Qamar ◽  
...  

We report on the thermoresistive properties of graphite on paper (GOP). A large temperature coefficient of resistance was observed and a highly sensitive GOP-based anemometer was demonstrated, indicating strong feasibility of using the GOP for low-cost thermoresistive sensors.


2001 ◽  
Vol 12 (10) ◽  
pp. 1417-1423 ◽  
Author(s):  
YI-TIAN GAO ◽  
BO TIAN ◽  
GUANG-MEI WEI

The reaction–diffusion systems represent various problems in the real world. For the Abrahams–Tsuneto reaction–diffusion system arising in superconductivity, we perform computerized symbolic computation and find its new exact analytic solutions, which are solitonic. We see the possibility that by way of the shock waves, the self–consistent superconducting interaction drives the Ginzburg–Landau order parameter, which might be observable.


Science ◽  
2019 ◽  
Vol 363 (6425) ◽  
pp. 387-391 ◽  
Author(s):  
Cheng Gu ◽  
Nobuhiko Hosono ◽  
Jia-Jia Zheng ◽  
Yohei Sato ◽  
Shinpei Kusaka ◽  
...  

Design of the gas-diffusion process in a porous material is challenging because a contracted pore aperture is a prerequisite, whereas the channel traffic of guest molecules is regulated by the flexible and dynamic motions of nanochannels. Here, we present the rational design of a diffusion-regulatory system in a porous coordination polymer (PCP) in which flip-flop molecular motions within the framework structure provide kinetic gate functions that enable efficient gas separation and storage. The PCP shows substantial temperature-responsive adsorption in which the adsorbate molecules are differentiated by each gate-admission temperature, facilitating kinetics-based gas separations of oxygen/argon and ethylene/ethane with high selectivities of ~350 and ~75, respectively. Additionally, we demonstrate the long-lasting physical encapsulation of ethylene at ambient conditions, owing to strongly impeded diffusion in distinctive nanochannels.


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