The Determination of Unsaturation in Butadiene Synthetic Rubber
Abstract 1. It has been found that synthetic rubber does not precipitate from a solution of dichloromethane by the addition of Wijs reagent, whereas natural rubber does precipitate under the same conditions. The reverse relation occurs with carbon disulfide as solvent. 2. A method has been developed for the determination of the unsaturation of butadiene rubber in solution in dichloromethane by the use of Wijs reagent. 3. It has been demonstrated that, by the use of a solution of iodine chloride in carbon tetrachloride, the reaction with rubber is complicated by the hydrolysis of iodine chloride during titration, but not by the substitution of hydrogen by halogen nor by the hydrolysis of the rubber-halogen addition product. 4. The possibility of obtaining accurate values for unsaturation by a calculation of this hydrolysis is demonstrated. 5. Two methods have been developed for the determination of the unsaturation of natural and butadiene rubbers.