Surface Properties of Carbon

1971 ◽  
Vol 44 (2) ◽  
pp. 307-343 ◽  
Author(s):  
Donald Rivin
Keyword(s):  
Carbon Black ◽  
Surface Chemistry ◽  
Functional Groups ◽  
Surface Reactivity ◽  
Point Of View ◽  
Background Information ◽  
Carbon Surface ◽  
Functional Behavior ◽  
Defect Sites

Abstract Carbon surface chemistry is relatively new as an independent subject of inquiry, and, judging by the volume of publications, is receiving increasing attention throughout the world. Our conception of carbon black and its functional behavior has changed significantly since the pioneering publication by Studebaker in 1957. Within the last few years there have been a number of excellent reviews covering various aspects of carbon chemistry by authors who are presently active in this field. Donnet, Puri, and Boehm discuss reactions of carbon and the characterization of surface functional groups while van der Plas is particularly thorough on the subject of adsorption properties and porosity. Deviney explores the relationship between surface chemistry and carbon-elastomer interactions, as does Studebaker from the point of view of the practical application of carbon black in rubber. Current monographs containing useful background information are collected in “Les Carbones” and in Walker's continuing series, “Chemistry and Physics of Carbon”. This review will describe how information from diverse sources has contributed to our understanding of the surface reactivity and fundamental adsorption behavior of carbon. It will be shown that most properties of carbon blacks are consistent with a surface structure wherein large deformed basal layers conforming to the topography of the surface are composed of several planar aromatic domains with functional groups at edge and defect sites. Examples of strong molecular interactions are given which involve specific reaction with the basal surface, individual functional groups, or a combination of both.

Radiotracer Studies of Carbon Black Surface Interactions with Organic Systems. I. Experimental Approach and Initial Results from Chemisorption and Vinyl Polymerization Studies

1968 ◽  
Vol 41 (2) ◽  
pp. 382-399 ◽  
Author(s):  
Marvin L. Deviney ◽  
Lawrence E. Whittington
Keyword(s):  
Carbon Black ◽  
Functional Groups ◽  
Reaction Mechanisms ◽  
Hydrogen Abstraction ◽  
Surface Interactions ◽  
Carbon Surface ◽  
Organic Systems ◽  
Carbon Black Surface ◽  
Basic Reaction ◽  
Black Surface

Abstract Radiotracer techniques have been applied to the study of interactions of carbon black surface functional groups with two chosen organic systems. The basic reaction mechanisms demonstrated in this study may have implications in elastomer reinforcement. Direct radiochemical evidence supports the conclusions of Hallum and Drushel (based on less direct polarographic data) that surface quinonic groups exhibit hydrogen abstraction activity toward tertiary hydrogens in paraffinic hydrocarbons. Studies on the system carbon black and styrene using tritium radiotracer have provided direct evidence that phenolic hydrogens participate in the polymerization acceleration and graft polymer formation reaction and are transferred to the growing polystyrene chains as postulated by Donnet. Several methods have been developed for specifically labelling certain oxygenated functional groups on the carbon surface with tritium and for tritium labelling carbon black in aromatic hydrogen positions. The techniques developed in this work and the basic reaction mechanisms derived will permit this investigation to be extended into a radiochemical study of carbon black surface interactions with elastomer related systems of interest to the rubber industry.

The Analyses of Learning Strategies in English as a Second Language: Theoretical Classification and Measurement Test

2020 ◽  
Vol 4 (2) ◽  
pp. 118-129
Author(s):  
Asti Gumartifa ◽  
◽  
Indah Windra Dwie Agustiani
Keyword(s):  
Language Learning ◽  
Learning Outcomes ◽  
Learning Strategies ◽  
Learning Process ◽  
English Learners ◽  
English Language ◽  
Point Of View ◽  
Effective Learning ◽  
The Impact

Gaining English language learning effectively has been discussed all years long. Similarly, Learners have various troubles outcomes in the learning process. Creating a joyful and comfortable situation must be considered by learners. Thus, the implementation of effective learning strategies is certainly necessary for English learners. This descriptive study has two purposes: first, to introduce the classification and characterization of learning strategies such as; memory, cognitive, metacognitive, compensation, social, and affective strategies that are used by learners in the classroom and second, it provides some questionnaires item based on Strategy of Inventory for Language Learning (SILL) version 5.0 that can be used to examine the frequency of students’ learning strategies in the learning process. The summary of this study explains and discusses the researchers’ point of view on the impact of learning outcomes by learning strategies used. Finally, utilizing appropriate learning strategies are certainly beneficial for both teachers and learners to achieve the learning target effectively.

The Algorithm of Characterization of an Action as a Jointly Committed Crime

2018 ◽  
pp. 37-44
Keyword(s):  
Criminal Code ◽  
Point Of View

The article discusses a sequence of activities to identify a crime as jointly committed. The requirements to the algorithm of such activities are formulated. Programme-based and targeted methods applied by the authors allowed detecting a range of stages of the algorithm. The first four stages aim at defining mandatory elements of a crime allowing to characterize it as a jointly committed action. The rest of the stages focus on identifying a type of criminal complicity. In the article, each stage is described. It is emphasized that in each stage there is a special objective. At the same time, all these stages, taken together, constitute a separate module of the program of criminal characterization of an action. From the authors’ point of view, algorithms are necessary not only for detection of crimes and their criminal characterization, but also for answering the question on existence of criminal complicity in each case. Also the authors give their opinions on interpretation of criminal complicity as a legal category. In particular, it is emphasized that not all of crimes merely committed with participation of two or more persons should be understood as jointly committed. It is joint participation that makes a crime jointly committed. Various forms of criminal complicity and types of co-offenders are considered in the article as well. In various crimes, criminal complicity manifests itself differently. Therefore the proposed algorithm can be applied only after identification a specific article of the Russian Criminal Code stipulating the responsibility for the crime committed.

Application of FT Spectroscopy in the Study of Fungi

2008 ◽  
Vol 59 (2) ◽  
pp. 212-215 ◽  
Author(s):  
Catalin Tanase ◽  
Aurel Pui
Keyword(s):  
Functional Groups ◽  
Toxic Substances ◽  
Ft Spectroscopy

The present study is devoted to the IR�FT characterization of some fungi species, to the identification of their main functional groups, as well as to emphasize the presence of some toxic substances in the structure of certain sporiferous plants.

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