Synthesis and Characterization of New poly β-Lactam from poly acrolein and Study Corrosion Inhibition for Stainless steel in Hydrochloric Acid Solution

2021 ◽  
pp. 3039-3944
Author(s):  
Amaal S. Sadiq ◽  
Entesar O. Al-Tamimi
Keyword(s):  
Stainless Steel ◽  
Schiff Base ◽  
Corrosion Inhibition ◽  
Inhibition Efficiency ◽  
The Novel ◽  
Inhibition Effect ◽  
Organic Inhibitors ◽  
Corrosion Inhibition Efficiency ◽  
Loss Method

A new poly chain derivative of polyacrolein has been synthesized from the two basic precursors, polyacrolein and aromatic amine/substituted amine in chloroform to prepare poly Schiff base compounds (A1-A4). The novel poly subs.β-lactam derivative is obtained via coupling of poly schiff base with chloroacetyl chloride and trimethylamine (B1-B4). Newly synthesized compound was identified via spectral methods; their [13C-NMR, 1H-NMR, and FTIR] also measurement of some of its physical properties. Furthermore the inhibition effect of synthesized compounds (B1-B4) on the corrosion of stainless steel in 1N HCl was studied by wight loss method. The results of weight loss measurements showed that corrosion inhibition efficiency by increasing the concentration of organic inhibitors for stainless steel in 1M HCl solution at 30°C.

Synthesis, Characterization of New Polytriazole Derivatives from Polyacryloyl chloride and Theoretical with Corrosion Inhibitor Study for Stainless steel in acidic medium

2021 ◽  
pp. 3721-3726
Author(s):  
Amaal S. Sadiq ◽  
Entesar O. Al-Tamimi
Keyword(s):  
Weight Loss ◽  
Stainless Steel ◽  
Inhibition Efficiency ◽  
Theoretical Study ◽  
Acid Hydrazide ◽  
Geometric Configurations ◽  
Inhibitor Study ◽  
Organic Inhibitors ◽  
Corrosion Inhibition Efficiency

The purpose of the study is to synthesize and characterize a new polytriazole derivative from polyacryloyl chloried, first reaction of polyacryloyl chloride with hydrazine hydrate in the presence of DMF as a solvent to obtained acid hydrazide (1) than reacted with different amide to give poly 1,2,4-triazole derivatives(1a-1c). Newly synthesized compounds were characterized by spectral methods [13C-NMR, 1H-NMR, and FTIR] and calculated some of its physical properties. Also, we worked theoretical study involving calculated the geometric configurations, total energy, dipole moment etc..,. In addition, the inhibition effect of the synthesized compounds (1a-1c) on corrosion of stainless steel in 1M HCl were studied by method of weight loss. The results of weight loss measurements showed that corrosion inhibition efficiency by increasing the concentration of organic inhibitors for stainless steel in 1M HCl solution at 30oC.

scholarly journals Comparative Corrosion Inhibition Effect of Imidazole Compounds and ofTrichodesma indicum(Linn) R. Br. on C38 Steel in 1 M HCl Medium

2013 ◽  
Vol 2013 ◽  
pp. 1-4 ◽  
Author(s):  
S. Alarmal Mangai ◽  
Subban Ravi
Keyword(s):  
Corrosion Inhibition ◽  
Inhibition Efficiency ◽  
Inhibition Effect ◽  
Maximum Inhibition ◽  
Weight Loss Method ◽  
Organic Inhibitors ◽  
C38 Steel ◽  
Loss Method ◽  
Imidazole Compounds ◽  
Hcl Medium

Corrosion inhibition effect of alkaloid extract part of the plantTrichodesma indicum(Linn) R. Br. of Boraginaceae family was studied and compared with that of imidazole compounds (imidazole, benzimidazole) on C38 steel in 1 M HCl solution by weight loss method at various temperatures. The study showed that the alkaloid part of the plant extract acts as a better inhibitor in comparison to the selected organic inhibitors. The maximum inhibition efficiency of the extract ofTrichodesma indicumR. Br. was found to be 94.5% at a concentration of 75 mg/L at 30°C.

Inhibition Action of Complex of Triethanolamine (TEA) and Na2WO4 for Brass in Simulated Cooling Water

2011 ◽  
Vol 347-353 ◽  
pp. 542-546
Author(s):  
Qun Jie Xu ◽  
Xian Qin Deng ◽  
Wen Li
Keyword(s):  
Synergistic Effect ◽  
Corrosion Inhibition ◽  
Inhibition Efficiency ◽  
Cooling Water ◽  
Ac Impedance ◽  
Inhibitor Concentration ◽  
Optimum Ratio ◽  
Inhibition Effect ◽  
Corrosion Inhibition Efficiency ◽  
Dc Polarization

The corrosion inhibition of brass in simulated cooling water by complex of triethanolamine (TEA) and Na2WO4 had been investigated by means of electrochemical (AC impedance and dc polarization) techniques. The results indicated that both TEA and Na2WO4 were able to inhibit the corrosion of brass in simulated cooling water. TEA showed the best inhibition effect for brass corrosion at the TEA concentration of 30 mg/L, and the inhibition efficiency was 45.35%. At the total inhibitor concentration of 20 mg/L, the complex of TEA and Na2WO4 had a good synergistic effect, and the optimum ratio of TEA to Na2WO4 is 1:9, corrosion inhibition efficiency was 89.08%.

scholarly journals Influence of Benzotriazole on Corrosion Inhibition of Mild Steel in Citric Acid Medium

2010 ◽  
Vol 7 (3) ◽  
pp. 1090-1094 ◽  
Author(s):  
P. Matheswaran ◽  
A. K. Ramasamy
Keyword(s):  
Citric Acid ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Inhibition Efficiency ◽  
First Order ◽  
First Order Kinetics ◽  
Weight Loss Method ◽  
Corrosion Inhibition Efficiency ◽  
Loss Method ◽  
Kinetic Treatment

Benzotriazole an organic compounds has been studied as corrosion inhibition for mild steel in 1 N citric acid by weight loss method. The result showed that the corrosion inhibition efficiency of the compound was found to be varying with the temperature and acid concentration. Also it was found that the corrosion inhibition behaviour of benzotriazole is better when the concentration of inhibitor is increased. The kinetic treatment of the results shows first order kinetics.

scholarly journals Effect of Silver Nanoparticles on the Corrosion Behaviour of Mild Steel and 316 Austenitic Stainless Steel in 0.5 M H2SO4

2019 ◽  
Vol 4 (4) ◽  
pp. 4-10
Author(s):  
Oluwatoyin Adenike Olaseinde ◽  
Olajesu F. Olarenwaju ◽  
Silifa T. Mohammed
Keyword(s):  
Silver Nanoparticles ◽  
Stainless Steel ◽  
Austenitic Stainless Steel ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Potentiodynamic Polarization ◽  
Ipomoea Batatas ◽  
Inhibition Efficiency ◽  
Corrosion Behaviour ◽  
Corrosion Inhibition Efficiency

The research investigated the effect of silver nanoparticles on the corrosion behaviour of Mild steel and 316 Austenitic stainless steel in 0.5M H2SO4 using the potentiodynamic polarization method. The nanoparticles were synthesized from the sweet potato (Ipomoea batatas) plant extracts using Silver Nitrate (AgNO3) and were characterized using Atomic Adsorption Spectroscopy, Fourier Transform Infrared Spectroscopy and the Ultraviolet Visible Spectroscopy Technique. The AAS results showed that the plant extract is eco-friendly as it does not contain heavy metals. The FTIR results showed the different functional groups present in the extracts obtained from the different parts of the plant to be Alcohol O-H, Nitrile C≡N, Alkyne C≡C, Alkene C=C and Benzene Ring C=C. The UV-Vis results showed the presence of phenolic compound which aided inhibition. The results from the potentiodynamic polarization showed that the nanoparticle obtained from the leaf has the highest corrosion inhibition efficiency and the corrosion inhibition efficiency increases as the concentration of inhibitors increases.

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