Inhibition Action of Complex of Triethanolamine (TEA) and Na2WO4 for Brass in Simulated Cooling Water

2011 ◽  
Vol 347-353 ◽  
pp. 542-546
Author(s):  
Qun Jie Xu ◽  
Xian Qin Deng ◽  
Wen Li
Keyword(s):  
Synergistic Effect ◽  
Corrosion Inhibition ◽  
Inhibition Efficiency ◽  
Cooling Water ◽  
Ac Impedance ◽  
Inhibitor Concentration ◽  
Optimum Ratio ◽  
Inhibition Effect ◽  
Corrosion Inhibition Efficiency ◽  
Dc Polarization

The corrosion inhibition of brass in simulated cooling water by complex of triethanolamine (TEA) and Na2WO4 had been investigated by means of electrochemical (AC impedance and dc polarization) techniques. The results indicated that both TEA and Na2WO4 were able to inhibit the corrosion of brass in simulated cooling water. TEA showed the best inhibition effect for brass corrosion at the TEA concentration of 30 mg/L, and the inhibition efficiency was 45.35%. At the total inhibitor concentration of 20 mg/L, the complex of TEA and Na2WO4 had a good synergistic effect, and the optimum ratio of TEA to Na2WO4 is 1:9, corrosion inhibition efficiency was 89.08%.

scholarly journals Improvement in Corrosion Inhibition Efficiency of Molybdate-Based Inhibitors via Addition of Nitroethane and Zinc in Stimulated Cooling Water

2012 ◽  
Vol 2012 ◽  
pp. 1-9 ◽  
Author(s):  
Saeed Mohammadi ◽  
Fatemeh Baghaei Ravari ◽  
Athareh Dadgarinezhad
Keyword(s):  
Electron Microscopy ◽  
Weight Loss ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Inhibition Efficiency ◽  
Cooling Water ◽  
Ac Impedance ◽  
Uniform Corrosion ◽  
Corrosion Inhibition Efficiency ◽  
Zinc Inhibition

An investigation was conducted to improve the corrosion inhibition efficiency of molybdate-based inhibitors for mild steel which is the main construction material of cooling water systems, using nitroethane as an organic compound beside zinc. In this study a new molybdate-based inhibitor was introduced with the composition of 60 ppm molybdate, 20 ppm nitrite, 20 ppm nitroethane, and 10 ppm zinc. Inhibition efficiency of molybdate alone and with nitrite, nitroethane, and zinc on the uniform corrosion of mild steel in stimulated cooling water (SCW) was assessed by electrochemical techniques such as potentiodynamic polarization and electrochemical impedance (AC impedance) measurements. Weight loss measurements were made with coupon testing specimens in the room temperature for 48 h. Studies of electron microscopy, including scanning electron microscopy (SEM) photograph and X-ray energy dispersive spectrometry (EDS) microanalysis, were used. The results obtained from the polarization and AC impedance curves were in agreement with those from the corrosion weight loss results. The results indicate that the new inhibitor is as effective as molybdate alone, though at one-ninth of the concentration range of molybdate, which is economically favorable.

scholarly journals Synergistic Effect of Thiourea-Zn2+ and L-Phenylalanine on the Inhibition of Corrosion of Mild Steel in Acid Medium

2019 ◽  
Vol 7 (2) ◽  
pp. 72-77
Author(s):  
M.B. Geetha ◽  
◽  
J. Sathish ◽  
S. Rajendran ◽  
◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Mild Steel ◽  
Acid Medium ◽  
Corrosion Inhibition ◽  
Metal Surface ◽  
Inhibition Efficiency ◽  
Protective Film ◽  
Surface Smoothness ◽  
Polarization Study ◽  
Corrosion Inhibition Efficiency

The formulation consisting of 100 ppm Thiourea, 25 ppm Zn2+ and 250 ppm of L-Phenylalanine has 95% corrosion inhibition efficiency with a synergistic effect among Thiourea, L-Phenylalanine and Zn2+ ions. Polarization study shows that this formulation as a mixed inhibitor. FTIR spectra exposed the presence of Fe2+-Thiourea, Fe2+-L-Phenylalanine complex and Zn(OH)2 in protective film. AFM study confirmed the metal surface smoothness following engrossed in the inhibitor and the presence of formed protective film on the metal surface.

Inhibition Action and Adsorption Behavior of 3-Amino-1,2,4-Triazole on Copper in 3% NaCl Solution

2010 ◽  
Vol 148-149 ◽  
pp. 1343-1346 ◽  
Author(s):  
Qun Jie Xu ◽  
Si Jing Ding ◽  
Hong Yun ◽  
Shi Feng Shi
Keyword(s):  
Adsorption Isotherm ◽  
Corrosion Inhibition ◽  
Adsorption Mechanism ◽  
Inhibition Efficiency ◽  
Ac Impedance ◽  
Adsorption Behavior ◽  
Nacl Solution ◽  
Maximum Value ◽  
Dc Polarization

The corrosion inhibition of copper in 3% NaCl solution by 3-amino-1, 2, 4-triazole (ATA) has been studied in relation to the concentration of the inhibitor using electrochemical (AC impedance and dc polarization) techniques. The results indicate that ATA has good corrosion inhibition for copper in 3% NaCl solution. The inhibition efficiency attains the maximum value of 97.65% when the concentration of ATA is 20 mg•L-1.Polarisation curves show that ATA behaves as a type of cathodal inhibition in 3% NaCl solution. Adsorption of the ATA is found to follow the Langmuir’s adsorption isotherm, and the adsorption mechanism is typical of chemisorption.

Synthesis and Characterization of New poly β-Lactam from poly acrolein and Study Corrosion Inhibition for Stainless steel in Hydrochloric Acid Solution

2021 ◽  
pp. 3039-3944
Author(s):  
Amaal S. Sadiq ◽  
Entesar O. Al-Tamimi
Keyword(s):  
Stainless Steel ◽  
Schiff Base ◽  
Corrosion Inhibition ◽  
Inhibition Efficiency ◽  
The Novel ◽  
Inhibition Effect ◽  
Organic Inhibitors ◽  
Corrosion Inhibition Efficiency ◽  
Loss Method

A new poly chain derivative of polyacrolein has been synthesized from the two basic precursors, polyacrolein and aromatic amine/substituted amine in chloroform to prepare poly Schiff base compounds (A1-A4). The novel poly subs.β-lactam derivative is obtained via coupling of poly schiff base with chloroacetyl chloride and trimethylamine (B1-B4). Newly synthesized compound was identified via spectral methods; their [13C-NMR, 1H-NMR, and FTIR] also measurement of some of its physical properties. Furthermore the inhibition effect of synthesized compounds (B1-B4) on the corrosion of stainless steel in 1N HCl was studied by wight loss method. The results of weight loss measurements showed that corrosion inhibition efficiency by increasing the concentration of organic inhibitors for stainless steel in 1M HCl solution at 30°C.

scholarly journals Organic Phosphorus Compounds as Inhibitors of Corrosion of Carbon Steel in Circulating Cooling Water: Weight Loss Method and Thermodynamic and Quantum Chemical Studies

2018 ◽  
Vol 2018 ◽  
pp. 1-9 ◽  
Author(s):  
Liang Liu ◽  
Ting-Ting Cao ◽  
Qi-Wei Zhang ◽  
Chong-Wei Cui
Keyword(s):  
Carbon Steel ◽  
Corrosion Inhibition ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Organic Phosphorus ◽  
Cooling Water ◽  
Circulating Cooling Water ◽  
Weight Loss Method ◽  
Corrosion Inhibition Efficiency ◽  
Loss Method

Circulating cooling water plays an important role in industrial water use. In this study, the corrosion inhibition effects of PBTCA, HEDP, and ATMP organic phosphorus inhibitors were investigated using the weight loss method by varying the dosage of inhibitors, ClO2 concentrations, and pH values on carbon steel in recirculating cooling water with a low concentration of ClO2 solution. The results showed that the three corrosion inhibitors had a satisfactory corrosion inhibition effect and that corrosion inhibition efficiency is positively correlated with the concentration of organic phosphorus inhibitors and pH. The average corrosion inhibition efficiency of the three inhibitors was about 80% at the concentration of inhibitors = 35 mg/L, pH = 9.0, and the concentration of ClO2 = 7.0 mg/L, of which the single-phosphorus molecular corrosion inhibitor proved to be the best inhibitor. When the ClO2 concentration was 7 mg/L, the corrosion inhibition efficiencies of the three corrosion inhibitors were relatively stable. Using the density functional theory (DFT) algorithm in the Gaussian 09 program, the optimization calculation was completed by the B3LYP/6-31G (d, p) method at the microlevel. The molecular structures of the three organic phosphorus inhibitors and the number of phosphorus-containing atoms were compared to the sustained-release properties. Organic phosphorus inhibitors, as an electronic buffer, not only provided electrons but also received electrons. They formed a complex with iron and zinc ions in water in order to attach to the surface of the carbon steel and to alleviate corrosion. In addition, the adsorption with a metal surface followed the Langmuir adsorption isotherm.

Preparation of Eco-Friendly Acidic Corrosion Inhibitors from Ilex Chinensis Sims Leaves

2021 ◽  
Vol 15 (4) ◽  
pp. 472-477
Author(s):  
Qianlong Wang ◽  
Ruquan Zhang ◽  
Liyuan Zhang ◽  
Minlan Gao ◽  
Weichao Du ◽  
...  
Keyword(s):  
Corrosion Inhibition ◽  
Corrosion Inhibitors ◽  
Adsorption Mechanism ◽  
Protocatechuic Acid ◽  
Inhibition Efficiency ◽  
Langmuir Adsorption Isotherm ◽  
Inhibition Effect ◽  
Acidic Corrosion ◽  
Langmuir Adsorption ◽  
Corrosion Inhibition Efficiency

Preparing chemicals from natural product is a simple way to green chemistry. May flavonoids and protocatechuic acid have been found in Ilex Chinensis Sims leaves extracts, which indicates its extracts suitable to be used as an effective corrosion inhibitor. Extracts of Ilex Chinensis Sims leaves (HE) were modified with hydroxymethylation reaction and Mannich reaction to produce the relative stable green acidic corrosion inhibitors (HM1 and HM2). The extracts of Ilex Chinensis Sims leaves and the modified samples were investigated on the corrosion inhibition of A3 steel accordingly. The results show that these inhibitors have effective corrosion inhibition effect on A3 steel. The HM2 are the most effective for corrosion inhibition, and the inhibition efficiency can reach to 78.36%. At 60 °C, the corrosion inhibition efficiency of these three extracts is HM2 > HM1 > HE. And the extracts inhibit corrosion mainly by adsorption mechanism. This adsorption accords with Langmuir adsorption isotherm.

Adsorption and corrosion inhibition characteristics of two medicinal molecules

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Hydrochloric Acid ◽  
Corrosion Rate ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Half Life ◽  
Thermodynamic Data ◽  
Inhibition Efficiency ◽  
Gravimetric Method ◽  
Corrosive Environment ◽  
Corrosion Inhibition Efficiency

The corrosion inhibition characteristics of two medicinal molecules phenylalanine and rutin on mild steel in 1.0M Hydrochloric acid were evaluated using gravimetric method. Corrosion inhibition efficiency of 83.78 and 90.40 % was obtained respectively after seven days. However, phenylalanine showed weak accumulative higher corrosion inhibition efficiency. The presence of both molecules in the corrosive environment reduced the corrosion rate constant and increased the material half-life. Thermodynamic data calculated suggests a spontaneous adsorption of the molecules on the mild steel’s surface.

Inhibition of pipeline steel corrosion in acidic environment using sulphadoxine and pyrimethamine

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Inhibition Efficiency ◽  
Pipeline Steel ◽  
Electrochemical Techniques ◽  
Steel Corrosion ◽  
Acidic Environment ◽  
Inhibitor Concentration ◽  
Adsorption Data ◽  
Corrosion Inhibition Efficiency ◽  
Inhibitive Action ◽  
Sulphadoxine Pyrimethamine

The anti-corrosive properties of sulphadoxine + pyrimethamine (S+P) on the corrosion of pipeline steel in acidic environment were investigated using electrochemical techniques. The results obtained showed an excellent inhibition efficiency which increased with increase in inhibitor concentration. The corrosion inhibition efficiency increased up to 99.04 % at 0.01M S+P and decreased with rise in temperature down to 85.93 % at 333 K and 0.01 M S+P, suggesting a physiosorptive mechanism of adsorption. Also the adsorption data was fitted into Langmuir and Temkin adsorption isotherms, while the inhibitive action was shown to proceed by mixed inhibition mode.

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