Acid Catalyzed Synthesis of substituted-n-((1, 3-diphenyl-1h-pyrazol-4-yl) methyl) benzenamine

Author(s):  
Havale Shrikant Hanumantappa ◽  
Bhavani Singh ◽  
Jaya Dwivedi ◽  
Dharma kishore ◽  
S. Venkat Rao

A new derivative synthesis of Substituted-N-((1, 3-diphenyl-1h-pyrazol-4-yl) methyl) benzenamine has attempted by using commonly available key starting materials Acetophenone (1) and substituted phenyl hydrazine in presence of sulfuric acid catalyst and alcohol solvent to afford potential antiviral active analogues. The synthesis proceeds through Vilsmeier-Haack reaction followed by reductive amination by using sodium borohydride.

2021 ◽  
Vol 2094 (5) ◽  
pp. 052043
Author(s):  
R A Marchenko ◽  
R Z Pen ◽  
I L Shapiro ◽  
Y A Ambrosovich

Abstract Hemp fire (Cannabis sativa) was delignified with the reaction mix “acetic acid - hydrogen peroxide - sulfuric acid catalyst - water” under sulfuric acid concentration of 0.45%, liquid module of 6, and temperature of 85 ° C. The cellulose was ground to 34 … 36°SHR and mixed in different ratios in compliance with the simplex-centroid experimental design with bleached sulfate softwood and hardwood pulp. The influence of the mixed composition formulations on the main strength properties of paper castings has been studied. It has been concluded that technical cellulose obtained from hemp fire applying this method, can be used for paper products manufacturing in combination with sulphate cellulose from coniferous and deciduous wood.


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