An upper bound visualization of design trade-offs in adsorbent materials for gas separations

2021 ◽  
Author(s):  
Matthew G. Cowan
2021 ◽  
Author(s):  
Ahmed H Elashkar ◽  
Gavin S. Hedley ◽  
Omid Taheri Qazvini ◽  
Shane Telfer ◽  
Matthew Cowan

The last 20 years has seen an explosion in the number of publications investigating porous solids for gas adsorption and separation. The combination of external drivers such as anthropogenic climate...


1998 ◽  
Vol 5 (10) ◽  
Author(s):  
Jakob Pagter ◽  
Theis Rauhe

We study the fundamental problem of sorting in a sequential model of computation and in particular consider the time-space trade-off (product of time and space) for this problem.<br />Beame has shown a lower bound of  Omega(n^2) for this product leaving a gap of a logarithmic factor up to the previously best known upper bound of O(n^2 log n) due to Frederickson. Since then, no progress has been made towards tightening this gap.<br />The main contribution of this paper is a comparison based sorting algorithm which closes this gap by meeting the lower bound of Beame. The time-space product O(n^2) upper bound holds for the full range of space bounds between log n and n/log n. Hence in this range our algorithm is optimal for comparison based models as well as for the very powerful general models considered by Beame.


2005 ◽  
Vol 16 (05) ◽  
pp. 943-956 ◽  
Author(s):  
CHRISTOS KAPOUTSIS

If the machines of some type A have enough resources to (i) solve problems that no machine of type B can solve, and (ii) simulate any unary two-way deterministic finite automaton that has access to a linearly-bounded counter, then typically no recursive function can upper bound the increase in the size of description when a machine of type A is replaced by an equivalent machine of type B.


2008 ◽  
Vol 19 (04) ◽  
pp. 795-811 ◽  
Author(s):  
MARTIN KUTRIB ◽  
JENS REIMANN

The simulation of weak restarting automata, i.e., classical restarting automata accepting exactly the regular languages, by finite automata is studied. Some of the trade-offs in the number of states when changing the representation are known. Here we continue the investigation in order to draw an almost complete picture of the descriptional power gained in the additional structural resources of weak restarting automata. In particular, for det-RR(1)-simulations of nondeterministic finite automata we obtain the same tight bounds as for simulations of R(1)-automata, though in some cases the latter class is much more efficient than the former. Moreover, the DFA-simulation of det-RR(1)-automata is considered. The shown bounds are of factorial order and are tight. The constructions are via alternating finite automata to DFAs. So, in addition, an upper bound for the AFA-simulation is obtained.


2011 ◽  
Vol 2 (2) ◽  
Author(s):  
Martin M. Merener

We review the attack given by Dinur and Nissim [6] on the output perturbation sanitizer, and generalize it to a setting that includes, as particular cases, databases with values in {0,1}---with the metric considered in [6]---and databases with real values, with other appropriate metrics (hence the binary case is not included in the real case). Previous works [12, 14] on the binary case gave results more efficient than ours. Those results could be used to extend the binary case to the real-valued case, hence implying our results. The contributions of this paper are: to make the implication explicit, and to give an alternative general proof. We state a property about the function dist that measures the error of the attacker's approximation of the database, which is satisfied in our cases of interest, and is sufficiently strong to prove the impossibility results regarding the privacy provided by the output-perturbation sanitizer, in both the real and binary cases. In this general context we establish an inequality (an upper bound to the probability of adversary's failure) that relates all the parameters of the problem---the size of the database, the relative error of the adversary, the number of queries made by the adversary (which determines its time complexity), its probability of failure, and the perturbation of the sanitizer---making explicit the trade-offs among them. From this inequality we deduce that for binary and real valued databases, the adversary described in [6] can defeat perturbation o(n1/2) with time complexity determined by o(n log n) number of queries (instead of O(n log2 n) as in [6]).


Molecules ◽  
2020 ◽  
Vol 25 (15) ◽  
pp. 3532
Author(s):  
Tiago Araújo ◽  
Gabriel Bernardo ◽  
Adélio Mendes

In the field of gas separation and purification, membrane technologies compete with conventional purification processes on the basis of technical, economic and environmental factors. In this context, there is a growing interest in the development of carbon molecular sieve membranes (CMSM) due to their higher permeability and selectivity and higher stability in corrosive and high temperature environments. However, the industrial use of CMSM has been thus far hindered mostly by their relative instability in the presence of water vapor, present in a large number of process streams, as well as by the high cost of polymeric precursors such as polyimide. In this context, cellulosic precursors appear as very promising alternatives, especially targeting the production of CMSM for the separation of O2/N2 and CO2/CH4. For these two gas separations, cellulose-based CMSM have demonstrated performances well above the Robeson upper bound and above the performance of CMSM based on other polymeric precursors. Furthermore, cellulose is an inexpensive bio-renewable feed-stock highly abundant on Earth. This article reviews the major fabrication aspects of cellulose-based CMSM. Additionally, this article suggests a new tool to characterize the membrane performance, the Robeson Index. The Robeson Index, θ, is the ratio between the actual selectivity at the Robeson plot and the corresponding selectivity—for the same permeability—of the Robeson upper bound; the Robeson Index measures how far the actual point is from the upper bound.


Filomat ◽  
2019 ◽  
Vol 33 (6) ◽  
pp. 1551-1559
Author(s):  
Behnam Hozzar ◽  
Ghasem Tohidi ◽  
Behrouz Daneshian

This paper aims to investigate proper effciency in multiobjective optimization. We suggest two nonlinear optimization problems to determine upper bound for trade-offs among objective functions. Based on these problems we introduce some properly effcient solutions which are closer to the ideal point. Weighted sum scalarization and Kuhn-Tucker conditions will be used to obtain these nonlinear optimization problems.


2015 ◽  
Vol 58 ◽  
pp. 83-100 ◽  
Author(s):  
Selena Gimenez-Ibanez ◽  
Marta Boter ◽  
Roberto Solano

Jasmonates (JAs) are essential signalling molecules that co-ordinate the plant response to biotic and abiotic challenges, as well as co-ordinating several developmental processes. Huge progress has been made over the last decade in understanding the components and mechanisms that govern JA perception and signalling. The bioactive form of the hormone, (+)-7-iso-jasmonyl-l-isoleucine (JA-Ile), is perceived by the COI1–JAZ co-receptor complex. JASMONATE ZIM DOMAIN (JAZ) proteins also act as direct repressors of transcriptional activators such as MYC2. In the emerging picture of JA-Ile perception and signalling, COI1 operates as an E3 ubiquitin ligase that upon binding of JA-Ile targets JAZ repressors for degradation by the 26S proteasome, thereby derepressing transcription factors such as MYC2, which in turn activate JA-Ile-dependent transcriptional reprogramming. It is noteworthy that MYCs and different spliced variants of the JAZ proteins are involved in a negative regulatory feedback loop, which suggests a model that rapidly turns the transcriptional JA-Ile responses on and off and thereby avoids a detrimental overactivation of the pathway. This chapter highlights the most recent advances in our understanding of JA-Ile signalling, focusing on the latest repertoire of new targets of JAZ proteins to control different sets of JA-Ile-mediated responses, novel mechanisms of negative regulation of JA-Ile signalling, and hormonal cross-talk at the molecular level that ultimately determines plant adaptability and survival.


2012 ◽  
Vol 11 (3) ◽  
pp. 118-126 ◽  
Author(s):  
Olive Emil Wetter ◽  
Jürgen Wegge ◽  
Klaus Jonas ◽  
Klaus-Helmut Schmidt

In most work contexts, several performance goals coexist, and conflicts between them and trade-offs can occur. Our paper is the first to contrast a dual goal for speed and accuracy with a single goal for speed on the same task. The Sternberg paradigm (Experiment 1, n = 57) and the d2 test (Experiment 2, n = 19) were used as performance tasks. Speed measures and errors revealed in both experiments that dual as well as single goals increase performance by enhancing memory scanning. However, the single speed goal triggered a speed-accuracy trade-off, favoring speed over accuracy, whereas this was not the case with the dual goal. In difficult trials, dual goals slowed down scanning processes again so that errors could be prevented. This new finding is particularly relevant for security domains, where both aspects have to be managed simultaneously.


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