U-Pb and Sm-Nd Evidence for Episodic Orogenic Gold Mineralization in the Kalgoorlie Gold Camp, Yilgarn Craton, Western Australia

2021 ◽  
Author(s):  
Jordan A. McDivitt ◽  
Steffen G. Hagemann ◽  
Anthony I.S. Kemp ◽  
Nicolas Thébaud ◽  
Christopher M. Fisher ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Western Australia ◽  
Late Stage ◽  
Gold Mineralization ◽  
Hydrothermal Systems ◽  
Orogenic Gold ◽  
Yilgarn Craton ◽  
Gold Telluride ◽  
Icp Ms ◽  
Metamorphic Fluids

Abstract Different genetic and timing models for gold mineralization in the Kalgoorlie gold camp (Yilgarn craton, Western Australia) suggest either broadly synchronous, late-stage mineralization related to metamorphic fluids at ca. 2640 Ma or a punctuated mineralization history from ca. 2675 to 2640 Ma with the involvement of early magmatic-hydrothermal systems (represented by the Fimiston, Hidden Secret, and Oroya gold-telluride lodes) and late metamorphic fluids (represented by the Mt. Charlotte gold stockwork veins). The results of U-Pb and Sm-Nd geochronological studies of zircon, apatite, and titanite from pre-ore dikes and syn-ore dikes constrain the absolute timing of mineralization and provide new evidence to this timing controversy. Emplacement ages constrained by U-Pb sensitive high-resolution ion microprobe (SHRIMP) zircon data are interpreted to be similar for both the pre-ore dikes (n = 10) and syn-ore dikes (n = 7) at ca. 2675 Ma. An inferred emplacement age of ca. 2675 Ma for the syn-ore dikes is supported by a Sm-Nd isochron age from apatite (laser ablation-inductively coupled plasma-mass spectrometry; LA-ICP-MS) of 2678 ± 15 Ma and by a U-Pb titanite age (LA-ICP-MS) of 2679 ± 6 Ma. The results of chemical abrasion-isotope dilution-thermal ionization mass spectrometry U-Pb zircon analysis from the pre- and syn-ore dikes are complicated by multistage Pb loss, reverse discordance, and potential inheritance. However, the data are compatible with the emplacement of Fimiston/Hidden Secret gold mineralization at ca. 2675 Ma and suggest a younger age for Oroya mineralization at ca. 2665 Ma. These results contrast with models for orogenic gold deposits that invoke broadly synchronous, late-stage mineralization related to metamorphic fluids at ca. 2640 Ma. The bulk of the Kalgoorlie gold camp’s estimated 2,300 t Au endowment was emplaced at ca. 2675 Ma as Fimiston/Hidden Secret Au mineralization. This early Au mineralization was deformed and overprinted twice by subordinate Au mineralization at ca. 2665 (Oroya mineralization) and ca. 2640 Ma (Mt. Charlotte mineralization). Gold mineralization in the Kalgoorlie gold camp was protracted in nature from ca. 2675 to 2640 Ma and reflects the interplay of early magmatic (Fimiston, Hidden Secret, Oroya) and late metamorphic (Mt. Charlotte) hydrothermal fluid systems in the formation of hybrid intrusion-related and metamorphic orebodies.

Chapter 12: Geologic Setting and Gold Mineralization of the Kalgoorlie Gold Camp, Yilgarn Craton, Western Australia

2020 ◽  
pp. 251-274
Author(s):  
Jordan A. McDivitt ◽  
Steffen G. Hagemann ◽  
Matthew S. Baggott ◽  
Stuart Perazzo
Keyword(s):  
Lava Flow ◽  
Western Australia ◽  
Gold Mineralization ◽  
Fault System ◽  
Yilgarn Craton ◽  
Stratigraphic Sequence ◽  
Geologic Setting ◽  
Multiple Deformation ◽  
Geochronological Constraints ◽  
Golden Mile

Abstract The Kalgoorlie gold camp in the Yilgarn craton of Western Australia comprises the supergiant Golden Mile and the smaller Mt. Charlotte, Mt. Percy, and Hidden Secret deposits. Since the camp’s discovery in 1893, ~1,950 metric tons (t) of Au have been produced from a total estimated endowment of ~2,300 t. The camp is located within Neoarchean rocks of the Kalgoorlie terrane, within the Eastern Goldfields superterrane of the eastern Yilgarn craton. Gold mineralization is distributed along an 8- × 2-km, NNW-trending corridor, which corresponds to the Boulder Lefroy-Golden Mile fault system. The host stratigraphic sequence, dated at ca. 2710 to 2660 Ma, comprises lower ultramafic and mafic lava flow rocks, and upper felsic to intermediate volcaniclastic, epiclastic, and lava flow rocks intruded by highly differentiated dolerite sills such as the ca. 2685 Ma Golden Mile Dolerite. Multiple sets of NNW-trending, steeply dipping porphyry dikes intruded this sequence from ca. 2675 to 2640 Ma. From ca. 2685 to 2640 Ma, rocks of the Kalgoorlie gold camp were subjected to multiple deformation increments and metamorphism. Early D1 deformation from ca. 2685 to 2675 Ma generated the Golden Mile fault and F1 folds. Prolonged sinistral transpression from ca. 2675 to 2655 Ma produced overprinting, NNW-trending sets of D2-D3 folds and faults. The last deformation stage (D4; < ca. 2650 Ma) is recorded by N- to NNE-trending, dextral faults which offset earlier structures. The main mineralization type in the Golden Mile comprises Fimiston lodes: steeply dipping, WNW- to NNW-striking, gold- and telluride-bearing carbonate-quartz veins with banded, colloform, and crustiform textures surrounded by sericite-carbonate-quartz-pyrite-telluride alteration zones. These lodes were emplaced during the earlier stages of regional sinistral transpression (D2) as Riedel shear-type structures. During a later stage of regional sinistral transpression (D3), exceptionally high grade Oroya-type mineralization developed as shallowly plunging ore shoots with “Green Leader” quartz-sericite-carbonate-pyrite-telluride alteration typified by vanadium-bearing muscovite. In the Hidden Secret orebody, ~3 km north-northwest of the Golden Mile, lode mineralization is a silver-rich variety characterized by increased abundance of hessite and petzite and decreased abundance of calaverite. At the adjacent Mt. Charlotte deposit, the gold-, silver-, and telluride-bearing lodes become subordinate to the Mt. Charlotte-type stockwork veins. The stockwork veins occur as planar, 2- to 50-cm thick, auriferous quartz-carbonate-sulfide veins that define steeply NW- to SE-dipping and shallowly N-dipping sets broadly coeval with D4 deformation. Despite extensive research, there is no consensus on critical features of ore formation in the camp. Models suggest either (1) distinct periods of mineralization over a protracted, ca. 2.68 to 2.64 Ga orogenic history; or (2) broadly synchronous formation of the different types of mineralization at ca. 2.64 Ga. The nature of fluids, metal sources, and mineralizing processes remain debated, with both metamorphic and magmatic models proposed. There is strong evidence for multiple gold mineralization events over the course of the ca. 2.68 to 2.64 orogenic window, differing in genesis and contributions from either magmatic or metamorphic ore-forming processes. However, reconciling these models with field relationships and available geochemical and geochronological constraints remains difficult and is the subject of ongoing research.

Magmatic-Hydrothermal Gold Mineralization at the Lone Tree Mine, Battle Mountain District, Nevada

2019 ◽  
Vol 114 (5) ◽  
pp. 811-856 ◽  
Author(s):  
Elizabeth A. Holley ◽  
Justin A. Lowe ◽  
Craig A. Johnson ◽  
Michael J. Pribil
Keyword(s):  
Mass Spectrometry ◽  
Late Stage ◽  
Carbonate Rocks ◽  
Main Stage ◽  
Argillic Alteration ◽  
Icp Ms ◽  
Submicron Scale ◽  
Sulfide Ore ◽  
Siliciclastic Rocks

Abstract The Lone Tree deposit is located in the northern Battle Mountain mining district, Nevada. Prior to mine closure in 2006, Santa Fe Pacific Gold and Newmont produced 4.2 Moz of gold at an average grade of 2.06 g/t at Lone Tree, primarily from the N-S– to NNW-SSE–striking Wayne zone. The ore is located between the Roberts Mountain and Golconda thrusts in siliciclastic rocks of the Ordovician Valmy Formation and in the Pennsylvanian-Permian Battle Mountain and Edna Mountain Formations, and above the Golconda thrust in siliciclastic and carbonate rocks of the Mississippian to Permian Havallah sequence. Ore is also hosted by rhyolitic dikes that were emplaced at 40.95 ± 0.06 Ma based on zircon U-Pb chemical abrasion-thermal ionization mass spectrometry. The gold is associated with sericitic and argillic alteration of the siliciclastic rocks and dikes and with decarbonatization and Fe carbonate alteration of the carbonate-bearing units, as well as in Fe-As sulfide and finegrained quartz alteration of all rock types. Oxidation affects 30 to 45% of the deposit, penetrating into the stratigraphy along numerous steeply dipping north-south, east-west, and north-northeast–south-southwest structures. Gold is positively correlated with Ag, As, Hg, and Sb. The highest Au grades occur in quartz-sulfide ore hosted in siliciclastic and carbonate sedimentary rocks and rhyolitic intrusions. In this ore style, fine-grained quartz and sericite are intergrown with disseminated sulfide minerals (quartz-sericite-pyrite alteration), constituting cores of weakly mineralized pyrite or marcasite, which are surrounded by fuzzy arsenopyrite rims that contain up to ~2,000 ppm Au. Low gold grades occur in late-stage banded pyrite breccias consisting of a finely zoned Au-poor pyrite matrix surrounding jigsaw-fit clasts of quartz-, illite-, barite-, and adularia-altered siliciclastic rock. The timing of main-stage mineralization is bracketed between the emplacement of the dikes and an adularia 40Ar/39Ar age of 40.14 ± 0.74 Ma. Sericite intergrown with arsenopyrite-rimmed pyrite in phenocrysts of the rhyolite dikes gave δ18O values of 1.6 to 9.5‰ and δD values of –105 to –145‰. For temperatures of 300 ± 100°C, the calculated fluid isotopic compositions are consistent with felsic magmatic water and minor modifications by mixing with meteoric water and exchange with wall rocks. In the silica-sulfide ore, in situ isotopic laser ablation-multicollector-inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS) analyses of pyrite cores yielded δ34S values ranging from 3.4 to 7.7‰, with average values of 5.6‰ in the felsic dikes, 4.5‰ in the siliciclastic rocks, and 5.3‰ in the carbonate rocks. These values match conventional pyrite δ34S data reported for Eocene porphyry systems elsewhere in the district. Nanoscale secondary ion mass spectrometry analyses show that gold and associated trace elements occur in submicron-scale zones within arsenopyrite rims on pyrite. The average δ34S values of the arsenopyrite rims are 5.3 to 6.5‰ heavier than the pyrite cores, indicating cooling and an increasing H2S/SO2 ratio. The highest grades resulted from episodic pulses of a gold-rich fluid that was partly derived from, or exchanged with, the sedimentary host rocks. In situ LA-MC-ICP-MS δ34S values for the late-stage banded pyrite breccia become progressively lighter from veinlet margin to center, reaching a low of –32‰. These veinlets indicate a shift from main-stage quartz-sericite-pyrite and intermediate argillic alteration to more neutral pH and oxidizing conditions during late-stage mineralization, indicating either increasing interaction between the fluid and sedimentary sulfur sources in the host-rock package or bacterial sulfate reduction and supergene sulfide precipitation.

Evidence for diachronous Archean lode gold mineralization in the Yilgarn Craton, Western Australia; a SHRIMP U-Pb study of intrusive rocks

1999 ◽  
Vol 94 (8) ◽  
pp. 1259-1276 ◽  
Author(s):  
C. J. Yeats ◽  
N. J. McNaughton ◽  
D. Ruettger ◽  
R. Bateman ◽  
David I. Groves ◽  
...  
Keyword(s):  
Western Australia ◽  
Gold Mineralization ◽  
Yilgarn Craton ◽  
Lode Gold ◽  
Intrusive Rocks

Structure and timing of Neoarchean gold mineralization in the Southern Cross district (Yilgarn Craton, Western Australia) suggest leading role of late Low-Ca I-type granite intrusions

2014 ◽  
Vol 67 ◽  
pp. 205-221 ◽  
Author(s):  
Michael P. Doublier ◽  
Nicolas Thébaud ◽  
Michael T.D. Wingate ◽  
Sandra S. Romano ◽  
Christopher L. Kirkland ◽  
...  
Keyword(s):  
Western Australia ◽  
Gold Mineralization ◽  
Yilgarn Craton ◽  
Leading Role ◽  
Type Granite
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