U-Pb and Sm-Nd Evidence for Episodic Orogenic Gold Mineralization in the Kalgoorlie Gold Camp, Yilgarn Craton, Western Australia

Different genetic and timing models for gold mineralization in the Kalgoorlie gold camp (Yilgarn craton, Western Australia) suggest either broadly synchronous, late-stage mineralization related to metamorphic fluids at ca. 2640 Ma or a punctuated mineralization history from ca. 2675 to 2640 Ma with the involvement of early magmatic-hydrothermal systems (represented by the Fimiston, Hidden Secret, and Oroya gold-telluride lodes) and late metamorphic fluids (represented by the Mt. Charlotte gold stockwork veins). The results of U-Pb and Sm-Nd geochronological studies of zircon, apatite, and titanite from pre-ore dikes and syn-ore dikes constrain the absolute timing of mineralization and provide new evidence to this timing controversy. Emplacement ages constrained by U-Pb sensitive high-resolution ion microprobe (SHRIMP) zircon data are interpreted to be similar for both the pre-ore dikes (n = 10) and syn-ore dikes (n = 7) at ca. 2675 Ma. An inferred emplacement age of ca. 2675 Ma for the syn-ore dikes is supported by a Sm-Nd isochron age from apatite (laser ablation-inductively coupled plasma-mass spectrometry; LA-ICP-MS) of 2678 ± 15 Ma and by a U-Pb titanite age (LA-ICP-MS) of 2679 ± 6 Ma. The results of chemical abrasion-isotope dilution-thermal ionization mass spectrometry U-Pb zircon analysis from the pre- and syn-ore dikes are complicated by multistage Pb loss, reverse discordance, and potential inheritance. However, the data are compatible with the emplacement of Fimiston/Hidden Secret gold mineralization at ca. 2675 Ma and suggest a younger age for Oroya mineralization at ca. 2665 Ma. These results contrast with models for orogenic gold deposits that invoke broadly synchronous, late-stage mineralization related to metamorphic fluids at ca. 2640 Ma. The bulk of the Kalgoorlie gold camp’s estimated 2,300 t Au endowment was emplaced at ca. 2675 Ma as Fimiston/Hidden Secret Au mineralization. This early Au mineralization was deformed and overprinted twice by subordinate Au mineralization at ca. 2665 (Oroya mineralization) and ca. 2640 Ma (Mt. Charlotte mineralization). Gold mineralization in the Kalgoorlie gold camp was protracted in nature from ca. 2675 to 2640 Ma and reflects the interplay of early magmatic (Fimiston, Hidden Secret, Oroya) and late metamorphic (Mt. Charlotte) hydrothermal fluid systems in the formation of hybrid intrusion-related and metamorphic orebodies.

Modelling of crustal composition and Moho depths and their Implications toward seismogenesis in the Kumaon–Garhwal Himalaya

We image the lateral variations in the Moho depths and average crustal composition across the Kumaon–Garhwal (KG) Himalaya, through the H–K stacking of 1400 radial PRFs from 42 three-component broadband stations. The modelled Moho depth, average crustal Vp/Vs, and Poisson’s ratio estimates vary from 28.3 to 52.9 km, 1.59 to 2.13 and 0.17 to 0.36, respectively, in the KG Himalaya. We map three NS to NNE trending transverse zones of significant thinning of mafic crust, which are interspaced by zones of thickening of felsic crust. These mapped transverse zones bend toward the north to form a NE dipping zone of maximum changes in Moho depths, below the region between Munsiari and Vaikrita thrusts. The 1991 Mw6.6 Uttarakashi and 1999 Mw6.4 Chamoli earthquakes have occurred on the main Himalayan thrust (MHT), lying just above the mapped zone of maximum changes in Moho depths. Modelled large values of average crustal Vp/Vs (> 1.85) could be attributed to the high fluid (metamorphic fluids) pressure associated with the mid-crustal MHT. Additionally, the serpentinization of the lowermost crust resulted from the continent–continent Himalayan collision process could also contribute to the increase of the average crustal Vp/Vs ratio in the region.

Gem-Grade Garnet With Metamorphic Origin in the Tiemurt Orogenic-Type Deposit, Chinese Altay Orogen: Texture, Chemistry, and Physicochemical Condition

The Chinese Altay Orogen represents an accretionary collage with episodic subduction-related accretion from the Neoproterozoic to Permian, followed by Triassic continent–continent collision. Reddish gem-grade garnet grains are widespread in Au–Cu–Pb–Zn sulfide deposits of the Chinese Altay Orogen, and how their formation links to regional geological processes such as seafloor sedimentation, magmatic hydrothermal metasomatic, or orogenic metamorphism remains unclear. In this context, we present an integrated set of geological occurrences, mineral texture, and major trace elemental geochemistry of six garnet grains from the representative Tiemurt Cu–Pb–Zn(-Au) deposit. Two categories of garnets, Grt1 and Grt2, are identified in terms of distinct mineral assemblages, textures, and geochemistry. The sub- to euhedral biotite inclusion–rich Grt1 with fine grains of less than 0.3 cm in diameter is intergrown with amphibole, chlorite, and biotite. Comparatively, the euhedral mineral inclusion–poor Grt2 with coarse grains of 0.5–5 cm in diameter is paragenetic with quartz, calcite, chlorite, and biotite. Forty-one EMPA analyses show that Grt1 and Grt2 have similar major elemental compositions of SiO2 (36.2–37.5 wt%), Al2O3 (19.9–20.7 wt%), and CaO (5.3–7.8 wt%) but host variable contents of FeO (31.7–35.9 wt% for Grt1 and 23.0–30.0 wt% for Grt2) and MnO (0.8–3.7 wt% for Grt1 and 4.3–12.7 wt% for Grt2). Both Grt1 (with a chemical formula of Alm49.3–54.6Spe19.7–24.6Gro14.6–18.4Pyr3.7–4.8And3.5–4.9) and Grt2 (Alm57.4–64.4Gro15.5–18.3Spe9.62–19.8Pyr3.8–5.7And1.1–4.4) are plotted into the field close to the end-member of almandine (Fe-Al–garnet). Compared to Grt1, Grt2 displays a Fe-enriched and Mn-depleted trend. Additionally, Mn is enriched in the core but Fe is enriched in the rim on the major elemental profile of Grt1. Regarding the trends of trace elements and REEs, Grt2 is believed to be produced during the detriment and replacement of Grt1 by an intense external metal-rich fluid. In combination with previous fluid inclusion research, the garnet-related fluids are characterized by CO2-rich, mesothermal, mildly acidic, and reduced redox, analogous to metamorphic fluids generated during orogenesis. Collectively, we conclude that the reddish gem-grade garnet crystals in the Chinese Altay Orogen are of metamorphic origin.

Intrusion-Associated Gold Systems and Multistage Metallogenic Processes in the Neoarchean Abitibi Greenstone Belt

In gold-endowed greenstone belts, ore bodies generally correspond to orogenic gold systems (OGS) formed during the main deformation stage that led to craton stabilization (syntectonic period). Most OGS deposits postdate and locally overprint magmatic-hydrothermal systems, such as Au-Cu porphyry that mostly formed during the main magmatic stage (synvolcanic period) and polymetallic intrusion-related gold systems (IRGS) of the syntectonic period. Porphyries are associated with tonalite-dominated and sanukitoid plutons, whereas most IRGS are related to alkaline magmatism. As reviewed here, most intrusion-associated mineralization in the Abitibi greenstone belt is the result of complex and local multistage metallogenic processes. A new classification is proposed that includes (1) OGS and OGS-like deposits dominated by metamorphic and magmatic fluids, respectively; (2) porphyry and IRGS that may contain gold remobilized during subsequent deformation episodes; (3) porphyry and IRGS that are overprinted by OGS. Both OGS and OGS-like deposits are associated with crustal-scale faults and display similar gold-deposition mechanisms. The main difference is that magmatic fluid input may increase the oxidation state and CO2 content of the mineralizing fluid for OGS-like deposits, while OGS are characterized by the circulation of reduced metamorphic fluids. For porphyry and IRGS, mineralizing fluids and metals have a magmatic origin. Porphyries are defined as base metal and gold-bearing deposits associated with large-volume intrusions, while IRGS are gold deposits that may display a polymetallic signature and that can be associated with small-volume syntectonic intrusions. Some porphyry, such as the Côté Gold deposit, demonstrate that magmatic systems can generate economically significant gold mineralization. In addition, many deposits display evidence of multistage processes and correspond to gold-bearing or gold-barren magmatic-hydrothermal systems overprinted by OGS or by gold-barren metamorphic fluids. In most cases, the source of gold remains debated. Whether magmatic activity was essential or marginal for fertilizing the upper crust during the Neoarchean remains a major topic for future research, and petrogenetic investigations may be paramount for distinguishing gold-endowed from barren greenstone belts.

Metamorphic Fluids in Orogenic Settings

Metamorphic reactions within the Earth’s crust produce fluids of variable composition that play a major role in the evolution of continents. Metamorphic fluids facilitate reactions that alter crustal rheology, reduce melting temperature, cycle elements between geological reservoirs and form ore deposits. These fluids are relatively inaccessible, other than by study of fluid inclusions, so most studies rely on a combination of indirect evidence and predictive thermodynamic models to determine the characteristics and roles of the fluids. In this article, the origins, compositions, controlling phase equilibria, and roles of metamorphic fluids are reviewed, followed by a discussion of selected areas of current and future research.

Fe-Ti Oxide Assemblages from the Contact-Metamorphosed Mafic-Ultramafic Rocks of the Sedova Zaimka Intrusion (Western Siberia, Russia): The Tracking of Metamorphic Transformations

Studies that track and compiled transformations of ilmenite and magnetite under conditions of different metamorphic grades are still very limited. The Sedova Zaimka intrusion in Western Siberia (Russia) is a good example to examine the effect of contact metamorphism from greenschist to low-amphibolite facies on magmatic Fe-Ti oxide minerals, as this small mafic-ultramafic body is located within contact metamorphic aureole of a large granite pluton. In the Sedova Zaimka, ilmenite with little to no magnetite is present as an accessory dissemination throughout metamorphosed rocks. Ilmenite is variably enriched in MnO (1 to 13.3 wt%) and depleted in MgO (less than 0.3 wt%), suggesting that its primary magmatic composition has been unevenly modified by diffusion re-equilibrium with coexisting metamorphic silicates. The elevated content of ZnO (up to 0.5 wt%) and NiO (up to 0.4 wt%) in ilmenite suggests that both ZnO and NiO, like MnO, must be strongly partitioned into ilmenite relatively to silicate minerals under the reducing contact metamorphic conditions, if chromite is absent. The textural observations of ilmenite–sulfide and ilmenite–titanite–sulfide relationships indicate that Ti-magnetite, in contrast to ilmenite, is an unstable phase in the presence of sulfur-rich reduced metamorphic fluids and is completely replaced by sulfides, with the development of specific “octahedral meshes” of ilmenite in sulfides.