scholarly journals Ex-situ Analysis of Lithium Distribution in a Sulfide-based All-solid-state Lithium Battery by Particle-induced X-ray and Gamma-ray Emission Measurements

2020 ◽  
Vol 88 (1) ◽  
pp. 45-49
Author(s):  
Yuto YAMADA ◽  
Kota SUZUKI ◽  
Kazuhiro YOSHINO ◽  
Sou TAMINATO ◽  
Takahiro SATOH ◽  
...  
2017 ◽  
Vol 27 (01n02) ◽  
pp. 11-20 ◽  
Author(s):  
K. Yoshino ◽  
K. Suzuki ◽  
Y. Yamada ◽  
T. Satoh ◽  
M. Finsterbusch ◽  
...  

For confirming the feasibility of micrometer scale analysis of lithium distribution in the all-solid-state lithium battery using a sulfide-based solid electrolyte, the cross-section of pellet type battery was analyzed by microbeam particle-induced X-ray emission (PIXE) and particle-induced gamma-ray emission (PIGE) measurements. A three-layered pellet-type battery (cathode: LiNbO3-coated [Formula: see text]/solid electrolyte: [Formula: see text]/anode: [Formula: see text]) was prepared for the measurements. Via elemental mapping of the cross-section of the prepared battery, the difference in the yields of gamma rays from the [Formula: see text] inelastic scattering (i.e., the lithium concentrations) between the composite electrodes and the solid electrolyte layer was clarified. The difference in the number of lithium ions at the composite anode/solid electrolyte interface of ([Formula: see text] mol) in the battery can be clearly detected by the microbeam PIGE technique. Therefore, lithium distribution analysis with a micrometer-scale spatial resolution is demonstrated. Further analysis of the cathode/anode composite electrodes with the different states of charge could provide important information to design a composite for high-performance all-solid-state lithium batteries.


1998 ◽  
Vol 502 (1) ◽  
pp. 428-436 ◽  
Author(s):  
Igor V. Moskalenko ◽  
Werner Collmar ◽  
Volker Schonfelder

1993 ◽  
Vol 405 ◽  
pp. L59 ◽  
Author(s):  
D. Barret ◽  
P. Mandrou ◽  
M. Denis ◽  
J. F. Olive ◽  
P. Laurent ◽  
...  

Author(s):  
G. L. CASE ◽  
E. ANZALONE ◽  
M.L. CHERRY ◽  
J. C. RODI ◽  
J. C. LING ◽  
...  

Galaxies ◽  
2020 ◽  
Vol 8 (3) ◽  
pp. 63
Author(s):  
Varsha Chitnis ◽  
Amit Shukla ◽  
K. P. Singh ◽  
Jayashree Roy ◽  
Sudip Bhattacharyya ◽  
...  

Gamma-ray emission from the bright radio source 3C 84, associated with the Perseus cluster, is ascribed to the radio galaxy NGC 1275 residing at the centre of the cluster. Study of the correlated X-ray/gamma-ray emission from this active galaxy, and investigation of the possible disk-jet connection, are hampered because the X-ray emission, particularly in the soft X-ray band (2–10 keV), is overwhelmed by the cluster emission. Here we present a method to spectrally decouple the cluster and active galactic nucleus (AGN) emission in imaging X-ray detectors. We use three sets of simultaneous Niel Gehrels Swift XRT and NuStar data. These observations were made during the period 2015 November to 2017 February, when a huge increase in the gamma-ray emission was observed. We find that the gamma-ray emission shows a very high degree of variability (40%–50%) on time scales of 1–10 days, whereas the hard X-ray emission, associated with the AGN, shows a low variability (∼15%–30%), on various time scales in the range of 0.01–60 days.


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