scholarly journals Application of mechanical filters for purification of electrolyte from solid products of the air and aluminum chemical cell reaction

2020 ◽  
Vol 18 (4) ◽  
pp. 713-718
Author(s):  
Nadezhda Okorokova ◽  
Aleksandr Perchenok ◽  
Stanislav Sevruk ◽  
Elena Suvorova ◽  
Ariadna Farmakovskaya ◽  
...  

This work presents the results of the development and application of a filtration unit - a cartridge filter with a throttle (discharge) hole - for separating the solid phase - crystalline aluminum hydroxide Al(OH)3, formed during long-term operation of an air and aluminum chemical cell with alkaline electrolyte and power plants based on them. The main theoretical provisions on the filtration mechanism using the discharge hole are formulated, according to which the filtration process consists of two types of filtration - blowout piping and particle coupling. The developed method made it possible to: purify electrolyte with low friction to electrolyte flow at high concentrations of the solid phase; ensure long-term performance of the purification system with large masses of the solid phase formed; be able to quickly regenerate the electrolyte; have a small mass and volume; leave a sufficient amount of solid phase in the electrolyte so that the crystals of aluminum hydroxide passing through the filter are a seed for the crystallization of dissolved aluminum in the circuit. The studies carried out allowed us to conclude that the use of mechanical cartridge filters with an orifice hole is an effective and reliable method for cleaning the electrolyte of a power plant with an air and aluminum chemical cell.

Energies ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1261
Author(s):  
Christopher Gradwohl ◽  
Vesna Dimitrievska ◽  
Federico Pittino ◽  
Wolfgang Muehleisen ◽  
András Montvay ◽  
...  

Photovoltaic (PV) technology allows large-scale investments in a renewable power-generating system at a competitive levelized cost of electricity (LCOE) and with a low environmental impact. Large-scale PV installations operate in a highly competitive market environment where even small performance losses have a high impact on profit margins. Therefore, operation at maximum performance is the key for long-term profitability. This can be achieved by advanced performance monitoring and instant or gradual failure detection methodologies. We present in this paper a combined approach on model-based fault detection by means of physical and statistical models and failure diagnosis based on physics of failure. Both approaches contribute to optimized PV plant operation and maintenance based on typically available supervisory control and data acquisition (SCADA) data. The failure detection and diagnosis capabilities were demonstrated in a case study based on six years of SCADA data from a PV plant in Slovenia. In this case study, underperforming values of the inverters of the PV plant were reliably detected and possible root causes were identified. Our work has led us to conclude that the combined approach can contribute to an efficient and long-term operation of photovoltaic power plants with a maximum energy yield and can be applied to the monitoring of photovoltaic plants.


2011 ◽  
Vol 63 (9) ◽  
pp. 1906-1912 ◽  
Author(s):  
Simos Malamis ◽  
Andreas Andreadakis ◽  
Daniel Mamais ◽  
Constantinos Noutsopoulos

The aim of this work was to evaluate the long-term performance of a Membrane Bioreactor (MBR) that operated continuously for 2.5 years and to assess membrane fouling and biomass activity under various operating conditions. Furthermore, a method for the characterisation of influent wastewater was developed based on its separation into various fractions. The MBR system operated at the solids retention times (SRT) of 10, 15, 20 and 33 days. The increase of SRT resulted in a decrease of the fouling rate associated with the reduction of extracellular polymeric substances. Moreover, the SRT increase resulted in a significant reduction of the Oxygen Uptake Rate (OUR) due to the lower availability of substrate and in a notable decrease of the maximum OUR since high SRT allowed the development of slower growing microorganisms. Biomass consisted of small flocs due to extensive deflocculation caused by intense aeration. Finally, the method developed for wastewater characterisation is straightforward and less time consuming than the usual method that is employed.


Author(s):  
Alexander M. Summe ◽  
Douglas P. Munson ◽  
Kenneth Oliphant ◽  
Sarah Chung

Degradation of service water systems is a major issue facing nuclear power plants and many plants will require repair or replacement of existing carbon steel piping components. High-density polyethylene (HDPE) has been used in non-safety service water systems for over ten years and has demonstrated superior performance. However, there still exist knowledge gaps around material properties, inspectability, and long-term performance. Specifically, there is a lack of insight on the aging of HDPE piping in disinfectant treated service water systems. This paper summarizes the methodology and results of predicting the expected life time of HDPE piping exposed to oxidizing biocides in numerous end-use scenarios. The aging mechanism of concern is Stage III Chemical-Mechanical degradation, where the polymer is oxidized by biocides and then experiences slow crack growth (SCG). An Aging Model is used to provide general predictions of pipe service life. The results were analyzed for trends and limiting or sensitive operating parameters were identified. For most applications, the specific resin used in the model demonstrated good performance for lifetimes of well over 40 years.


2019 ◽  
Vol 5 (1) ◽  
Author(s):  
Mauro Cappelli ◽  
Francesco Cordella ◽  
Francesco Bertoncini ◽  
Marco Raugi

Guided wave (GW) testing is regularly used for finding defect locations through long-range screening using low-frequency waves (from 5 to 250 kHz). By using magnetostrictive sensors, some issues, which usually limit the application to nuclear power plants (NPPs), can be fixed. The authors have already shown the basic theoretical background and simulation results concerning a real steel pipe, used for steam discharge, with a complex structure. On the basis of such theoretical framework, a new campaign has been designed and developed on the same pipe, and the obtained experimental results are now here presented as a useful benchmark for the application of GWs as nondestructive techniques. Experimental measures using a symmetrical probe and a local probe in different configurations (pulse-echo and pitch-catch) indicate that GW testing with magnetostrictive sensors can be reliably applied to long-term monitoring of NPPs components.


Author(s):  
Oliver Martin ◽  
Antonio Ballesteros ◽  
Christiane Bruynooghe ◽  
Michel Bie`th

The energy supply of the future in the EU will be a mix of renewable, fossil and nuclear. There are 145 nuclear power reactors in operation in 15 out of the 27 EU countries, with installed power ∼132 GWe. The age distribution of current nuclear power plants in EU is such that in 2010 most of them will have passed 20-years and approximately 25% of them 30 years of age. The decrease of energy supply from nuclear generated electricity can not always be compensated in a reliable and economical way within a short time span. For this situation utilities may be keen to upgrade the reactor output and /or to ask their regulatory bodies for longer term operation. Under the research financed in the Euratom part of the Research Directorate (RTD) of the European Commission several projects explicitly address the safe long term operation of nuclear power plants (NULIFE, LONGLIFE) and the topics proposed in the 2010 call explicitly address issues concerning component ageing, in particular non metallic components, i.e. instrumentation and cables (I&C) and concrete ageing. This paper presents an overview of the plans for long term operation (LTO) of nuclear power plants in the EU. Special emphasis is given on research activities on component ageing management and long term operation issues related to safety.


Author(s):  
Otso Cronvall

This study concerns the long-term operation (LTO) of a boiling water reactor (BWR) reactor pressure vessel (RPV) and its internals. The main parts of this study are: survey on susceptibility to degradation mechanisms, and computational time limited ageing analyses (TLAAs). The ageing of nuclear power plants (NPPs) emphasises the need to anticipate the possible degradation mechanisms. The BWR survey on susceptibility to these uses the OL1/OL2 RPVs and significant internals as a pilot project. It is not necessary to carry out the TLAAs for all components. Some components were excluded from the TLAAs with a screening process. To do this, it was necessary to determine the component specific load induced stresses, strains and temperature distributions as well as cumulative usage factor (CUF) values. For the screened-in components, the TLAAs covered all significant time dependent degradation mechanisms. These include (but are not limited to): • irradiation embrittlement, • fatigue, • stress corrosion cracking (SCC), and • irradiation accelerated SCC (IASCC). For the components that were screened-in, the potential to brittle, ductile or other degradation was determined. Only some of the most significant cases and results are presented. According to the analysis results, the operational lifetime of the OL1/OL2 RPVs and internals can safely be extended from 40 to 60 years.


Author(s):  
P. M. James ◽  
M. Berveiller

SOTERIA is focused on the ‘safe long term operation of light water reactors’. This will be achieved through an improved understanding of radiation effects in nuclear structural materials. This project has received funding from the European Union’s Horizon 2020 research and innovation programme under agreement No 661913. The overall aim of the SOTERIA project is to improve the understanding of the ageing phenomena occurring in ferritic reactor pressure vessel steels and in the austenitic internals in order to provide crucial information to regulators and operators to ensure safe long-term operation (LTO) of existing European nuclear power plants (NPPs). SOTERIA has set up a collaborative research consortium which gathers the main European research centers and industrial partners who will combine advanced modelling tools with the exploitation of experimental data to focus on two major objectives: i) to identify ageing mechanisms when materials face environmental degradation (such as e.g. irradiation and corrosion) and ii) to provide a single platform containing data and tools for reassessment of structural components during NPPs lifetime. This paper provides an overview of the ongoing activities within the SOTERIA Project that are contained within the analytical work-package (WP5.3). These fracture aspects are focused on the estimates of fracture in both ferritic steels and irradiation assisted stress corrosion cracking (IASCC) in austenitic stainless steels, under irradiated conditions. This analytical development is supported by analytical estimates of irradiation damage and the resulting changes in tensile behaviour of the steels elsewhere in SOTERIA, as well as a wider number of experimental programmes. Cleavage fracture estimates are being considered by a range of modelling estimates including the Beremin, Microstructurally Informed Brittle Fracture Model (MIBF), JFJ and Bordet Models with efforts being made to understand the influence of heterogeneity on the predicted toughness’s. Efforts are also being considered to better understand ductile void evolution and the effect of plasticity on the cleavage fracture predictions. IASCC is being modelled through the INITEAC code previously developed within the predecessor project Perform 60 which is being updated to incorporate recent developments from within SOTERIA and elsewhere.


Energies ◽  
2020 ◽  
Vol 13 (20) ◽  
pp. 5366
Author(s):  
Fiseha Tesfaye ◽  
Daniel Lindberg ◽  
Mykola Moroz ◽  
Leena Hupa

Besides the widely applied hydropower, wind farms and solar energy, biomass and municipal and industrial waste are increasingly becoming important sources of renewable energy. Nevertheless, fouling, slagging and corrosion associated with the combustion processes of these renewable sources are costly and threaten the long-term operation of power plants. During a high-temperature biomass combustion, alkali metals in the biomass fuel and the ash fusion behavior are the two major contributors to slagging. Ash deposits on superheater tubes that reduce thermal efficiency are often composed of complex combinations of sulfates and chlorides of Ca, Mg, Na, and K. However, thermodynamic databases involving all the sulfates and chlorides that would favor a better understanding and control of the problems in combustion processes related to fouling, slagging and corrosion are not complete. In the present work, thermodynamic properties including solubility limits of some phases and phase mixtures in the K2SO4-(Mg,Ca)SO4 system were reviewed and experimentally investigated. Based on the new and revised thermochemical data, binary phase diagrams of the K2SO4-CaSO4 and K2SO4-MgSO4 systems above 400 °C, which are of interest in the combustion processes of renewable-energy power plants, were optimized.


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