Degree of Unsaturation Dependence of Curing Reaction for Butyl Rubber Complexes

Polymer Korea ◽  
2021 ◽  
Vol 45 (4) ◽  
pp. 552-559
Author(s):  
Sangho Lee ◽  
Hyun-Uk Jeon ◽  
Soo-Hyung Choi
Keyword(s):  
Butyl Rubber ◽  
Curing Reaction ◽  
Degree Of Unsaturation

A common mechanism links activities of butyrate in the colon

2017 ◽  
Author(s):  
Mohit S. Verma ◽  
Michael J. Fink ◽  
Gabriel L Salmon ◽  
Nadine Fornelos ◽  
Takahiro E. Ohara ◽  
...  
Keyword(s):  
Stem Cells ◽  
Histone Deacetylases ◽  
Biological Activities ◽  
Short Chain Fatty Acids ◽  
Common Mechanism ◽  
Epithelial Stem Cells ◽  
Degree Of Unsaturation ◽  
Structure Activity ◽  
Starting Point ◽  
New Compounds

Two biological activities of butyrate in the colon (suppression of proliferation of colonic epithelial stem cells and inflammation) correlate with inhibition of histone deacetylases. Cellular and biochemical studies of molecules similar in structure to butyrate, but different in molecular details (functional groups, chain-length, deuteration, oxidation level, fluorination, or degree of unsaturation) demonstrated that these activities were sensitive to molecular structure, and were compatible with the hypothesis that butyrate acts by binding to the Zn<sup>2+</sup> in the catalytic site of histone deacetylases. Structure-activity relationships drawn from a set of 36 compounds offer a starting point for the design of new compounds targeting the inhibition of histone deacetylases. The observation that butyrate was more potent than other short-chain fatty acids is compatible with the hypothesis that crypts evolved (at least in part), to separate stem cells at the base of crypts from butyrate produced by commensal bacteria.

Thermoelastoplasts based on the mixture of thermoplastic polyolefins and butyl rubber

2018 ◽  
pp. 33-42
Author(s):  
Z. N. Guseynova ◽  
◽  
N. T. Kakhramanov ◽  
B. A. Mamedov ◽  
V. S. Osipchik ◽  
...  
Keyword(s):  
Butyl Rubber

Technological characteristics of injection molding of dynamic elastoplasts based on thermoplastic polyolefins and butyl rubber

2019 ◽  
pp. 58-67
Author(s):  
N. T. Kakhramanov ◽  
◽  
Z. N. Huseynova ◽  
V. S. Osipchik ◽  
R. V. Kurbanova ◽  
...  
Keyword(s):  
Injection Molding ◽  
Butyl Rubber ◽  
Technological Characteristics

Partial replacement of carbon black by nanoclay in butyl rubber compounds for tubeless tires

2017 ◽  
Vol 59 (11-12) ◽  
pp. 1054-1060 ◽  
Author(s):  
Mohan Kumar Harikrishna Kumar ◽  
Subramaniam Shankar ◽  
Rathanasamy Rajasekar ◽  
Pal Samir Kumar ◽  
Palaniappan Sathish Kumar
Keyword(s):  
Carbon Black ◽  
Butyl Rubber ◽  
Partial Replacement ◽  
Rubber Compounds

Application of hydrogenated butadiene-nitrile rubbers for products operated at high temperatures and in aggressive environments

2019 ◽  
pp. 129-136 ◽  
Author(s):  
E. A. Khorova ◽  
A. V. Myshlyavtsev
Keyword(s):  
Relative Elongation ◽  
Temperature Limit ◽  
Degree Of Unsaturation ◽  
Product Service ◽  
Nitrile Rubbers ◽  
The Subject ◽  
Maximum Content ◽  
Aging In Air ◽  
Hydrocarbon Media

The subject of the study were rubber mixtures based on hydrogenated butadiene-nitrile rubbers (HNBR) Therban, Zetpol, NBR-B with an acrylonitrile (AN) content of 34% to 49% and unsaturation of 0.9% to 22% with sulfuric, peroxide and sulfuric-peroxide cure systems. The purpose of the study was to determine the effect of the AN content and the degree of unsaturation of HNBR on the properties of rubbers in products designed for operation under the influence of fuels and oils at increased temperatures.The results of the determination of the mass swelling of rubbers in hydrocarbon media and the relative elongation in the process of thermal aging in air and in oil at increased temperatures are presented. The conclusion was made on the use of HNBR mixture with maximum content of AN (49%), with low (6%) and extremely low (0.9%) ODS content and sulfuric peroxide cure system to extend the product service temperature limit to 150°C.

The influence of oxidized technical carbon N121 on the properties of butyl-based rubbers

2019 ◽  
pp. 123-128
Author(s):  
M. N. Nagornaya ◽  
A. V. Myshliavtsev ◽  
S. Ya. Khodakova
Keyword(s):  
Hydrogen Peroxide ◽  
Carbon Black ◽  
Gas Permeability ◽  
Mechanical Tests ◽  
Butyl Rubber ◽  
Rubber Mixture ◽  
Active Forms Of Oxygen ◽  
Technical Carbon ◽  
Furnace Black ◽  
The Subject

The subject of the study were samples of channel technical carbon K354, furnace technical carbon N121 and experimental – based on TUN121, oxidized with active forms of oxygen. Samples of carbon black were studied in the composition of a rubber mixture based on BK 1675N butyl rubber. The purpose of this study was to determine the possibility of using oxidized technical carbon N121 in fillers of rubber based on butyl rubber, instead of carbon black K354. The physicochemical properties of the samples of technical carbon under study, the results of physical and mechanical tests, and the gas permeability tests of rubber mixtures filled with the samples under study are presented. A conclusion is made about the possibility of replacing channel technical carbon K354 with furnace black carbon N121 oxidized with 30% hydrogen peroxide.

scholarly journals Pattern-Type Separation of Triacylglycerols by Silver Thiolate×Non-Aqueous Reversed Phase Comprehensive Liquid Chromatography

Separations ◽  
2021 ◽  
Vol 8 (6) ◽  
pp. 88
Author(s):  
Paola Arena ◽  
Danilo Sciarrone ◽  
Paola Dugo ◽  
Paola Donato ◽  
Luigi Mondello
Keyword(s):  
Liquid Chromatography ◽  
Nutritional Value ◽  
Ion Trap ◽  
Edible Oils ◽  
Reversed Phase ◽  
Borago Officinalis ◽  
Animal Fats ◽  
Group Type ◽  
Degree Of Unsaturation ◽  
Main Components

Triacylglycerols (TAGs), as the main components of edible oils and animal fats, are responsible for the nutritional value, organoleptic features and technological properties of foods; each lipid matrix shows a unique TAG profile which can serve as fingerprint to ensure the quality and authenticity of food products. The high complexity of many foodstuffs often makes untargeted elucidation of TAG components a challenging task; thus, more efficient separation techniques may be mandatory. In this research, the TAG profile of a borage (Borago officinalis) seed oil was obtained by two-dimensional comprehensive liquid chromatography (LC×LC), by the coupling of silver thiolate and octadecylsilica monodisperse materials. A total 94 TAG compounds were identified by ion trap-time of flight detection, using atmospheric pressure ionization, with the degree of unsaturation varying from 0 to 9, and partition values ranging from 36 to 56. The group-type separation afforded by this analytical approach may be useful to quickly fingerprint TAG components of oil samples.

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