scholarly journals Heavy Metals Analysis and Health Risk Assessment of Three Fish Species, Surface Water and Sediment Samples in Ogbaru Axis of River Niger, Anambra State, Nigeria

2021 ◽  
pp. 64-81
Author(s):  
Opeyemi F. Ojaniyi ◽  
Patrice A. C. Okoye ◽  
Daniel O. Omokpariola
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Surface Water ◽  
Fish Species ◽  
Dry Season ◽  
Sediment Samples ◽  
Anambra State ◽  
Water And Sediment ◽  
River Niger ◽  
Water And Sediment Samples

Human activities on environmental resources have negatively affected floras and faunas in maintaining fair balance. In this research study, selected heavy metals (Al, As, Cd, Cr, Cu, Fe, Hg, Pb, Ni, Zn) concentration in three fish species (Clarias gariepinus, Heterotis niloticus and Anguilla labiate), surface water and sediment samples in Ogbaru axis of River Niger, Anambra State, Nigeria. We evaluated the samples using atomic absorption spectrophotometer (AAS). The result of heavy metals (Cu, Fe, Zn, Ni, Pb, Cd, Al, Cd) analysis in fish samples showed that Cr was detected in Clarias garipinus and Anguilla labiate with a concentration of 0.001mg/kg in both species but was not detected in Heterotis niloticus. Hg and Al were not detected in Anguilla labiate but both metals were detected in the other fish species with a mean concentration of 0.311mg/kg and 0.019mg/kg respectively for Clarias garipinus and 0.001mg/kg and 0.005mg/kg respectively for Heterotis niloticus. In decreasing order, the heavy metal concentration in Clarias garipinus in increasing order of Cu >Fe > Ni > Hg > Pb > Zn > As > Cd > Al > Cr, while Heterotis niloticus followed the order Cu > Zn > Fe > Ni > Pb > Cd > Al > As > Hg > Cr, and  Anguilla labiate followed the pattern of Cu > Fe > Zn > Ni > Pb > Cd > Cr > As > Hg > Al. For surface water, As (0.005mg/l), Cd (0.032 mg/l), Cr (0.099 mg/l), Cu (0.186 mg/l), Fe (2.308 mg/l), Hg (1.501 mg/l) and Pb (0.724 mg/l) showed high concentration for the raining season compared to dry season, as Al (0.246 mg/l), Ni (0.773 mg/l) and Zn (2.903 mg/l) were dominant during dry season, while sediment samples of Cr (0.112 mg/kg), Cu (0.029 mg/kg), Ni (0.945 mg/kg) and Pb (0.039 mg/kg) concentration in raining season were higher than dry season and vice versa for other As, Cd, Fe, Hg, Zn. Correlation matrices showed positive value showing that heavy metals were from a similar source with migration route and vice versa for negative correlation. Health and exposure risk assessment was conducted for carcinogenic and non-carcinogenic exposure in adults and children, where the cumulative cancer risk was within USEPA regulatory standard (1.0E-6 – 1.0E-04) and cumulative hazard index were above 1 for adults (2.02) and children (4.93), implying that children are at risk of having adverse health issues compared to adults. Therefore, there is a need for regulatory advocacy and special care to mitigate anthropogenic release and safeguard the environment.

scholarly journals DISTRIBUTION OF HEAVY METALS IN NATUNA COASTAL WATERS

2015 ◽  
Vol 6 (2) ◽  
Author(s):  
Sophia L Sagala ◽  
Rikha Bramawanto ◽  
Anastasia R.T.D Kuswardani ◽  
Widodo S Pranowo
Keyword(s):  
Heavy Metals ◽  
Surface Water ◽  
Coastal Waters ◽  
Sampling Method ◽  
Sediment Samples ◽  
Iron Metal ◽  
Water And Sediment ◽  
Standard Level ◽  
Instrument Detection Limit ◽  
Water And Sediment Samples

ABSTRACTThe study of Pb, Cd, Cu, Hg, and As and Fe in Natuna coastal waters, Riau Islands was conducted in November 2012. Water and sediment samples were collected from 35 stations by purposive sampling method and those heavy metals were analysed using Atomic Absorption Spectrophotometer, flame type (FAAS). The results showed that concentrations of total Pb, Cd, Cu, Hg, and As in surface water were below instrument detection limit (2 µg/L for Pb, Cd, and Cu; 0.02 µg/L for Hg and As). Moreover, the concentration of metal Fe in surface water was 0.021-0.054 mg/L. Concentrations of Pb and Cu in sediment were 0.05-22.67 mg/kg and 3.77-11.00 mg/kg, respectively, at which the highest concentrations were found near Binjai Estuary. Those concentrations were significantly below the standard levels set by CCME (2002) and ANZECC/ARMCANZ (2000). Concentration of Fe in sediment varied from 751.13-2309.12 mg/kg and showed similar spatial distribution to Cu-in-sediment. No standard level for Fe in waters was available. Generally, it can be concluded that Natuna coastal water was still uncontaminated.  Keywords: heavy metals, iron metal, Natuna coastal waters.

scholarly journals DISTRIBUTION OF HEAVY METALS IN NATUNA COASTAL WATERS

2015 ◽  
Vol 6 (2) ◽  
Author(s):  
Sophia L Sagala ◽  
Rikha Bramawanto ◽  
Anastasia R.T.D Kuswardani ◽  
Widodo S Pranowo
Keyword(s):  
Heavy Metals ◽  
Detection Limit ◽  
Surface Water ◽  
Coastal Waters ◽  
Sampling Method ◽  
Sediment Samples ◽  
Iron Metal ◽  
Water And Sediment ◽  
Standard Level ◽  
Water And Sediment Samples

<p><strong><em>ABSTRACT</em></strong></p><p><em>The</em><em> study of Pb, Cd, Cu, Hg, and As and Fe in Natuna coastal waters, Riau Islands was conducted in November 2012. Water and sediment samples were collected from 35 stations by purposive sampling method</em><em> and those heavy metals were</em><em> analysed using Atomic Absorption Spectrophotometer, flame type (FAAS). The results showed that concentrations of total Pb, Cd, Cu, Hg, and As in surface water were below instrument</em><em> </em><em>detection limit</em><em> </em><em>(</em><em>2 µg/L for Pb</em><em>,</em><em> Cd</em><em>, and Cu;</em><em> 0.02 µg/L for Hg and As</em><em>)</em><em>.</em><em> </em><em>Moreover</em><em>, the concentration of metal Fe in surface water was 0.021-0.054 mg/L. Concentrations of Pb and Cu in sediment were 0.05-22.67 mg/kg and 3.77-11.00 mg/kg, respectively, at which the highest concentrations were found near Binjai Estuary.</em><em> </em><em>T</em><em>hose concentrations were significantly below the standard levels set by CCME (2002) and ANZECC/ARMCANZ (2000).</em><em> </em><em>C</em><em>oncentration of Fe in sediment </em><em>varied from</em><em> 751.13-2309.12 mg/kg and showed similar </em><em>spatial </em><em>distribution to Cu-in-sediment. No standard level for Fe in waters was </em><em>available</em><em>. Generally, it can be concluded that Natuna coastal water was still</em><em> uncontaminated</em><em>. </em></p><p> </p><strong><em>Keywords</em></strong><em>: heavy metals, iron metal, Natuna coastal waters.</em>

Taking the pulse of Mother Ganga - Revealing the visible and invisible water pollution crisis along the Ganges River

2021 ◽  
Author(s):  
Stefan Krause ◽  
Keyword(s):  
Water Pollution ◽  
Water Quality ◽  
Land Use ◽  
Surface Water ◽  
River Network ◽  
Ganges River ◽  
Sediment Samples ◽  
Water And Sediment ◽  
The Ganges ◽  
Water And Sediment Samples

&lt;p&gt;It is probably hard to overestimate the significance of the River Ganges for its spiritual, cultural and religious importance. As the worlds&amp;#8217; most populated river basin and a major water resource for the 400 million people inhabiting its catchment, the Ganges represents one of the most complex and stressed river systems globally. This makes the understanding and management of its water quality an act of humanitarian and geopolitical relevance. Water quality along the Ganges is critically impacted by multiple stressors, including agricultural, industrial and domestic pollution inputs, a lack and failure of water and sanitation infrastructure, increasing water demands in areas of intense population growth and migration, as well as the severe implications of land use and climate change. Some aspects of water pollution are readily visualised as the river network evolves, whilst others contribute to an invisible water crisis (Worldbank, 2019) that affects the life and health of hundreds of millions of people.&lt;/p&gt;&lt;p&gt;We report the findings of a large collaborative study to monitor the evolution of water pollution along the 2500 km length of the Ganges river and its major tributaries that was carried out over a six-week period in Nov/Dec 2019 by three teams of more than 30 international researchers from 10 institutions. Surface water and sediment were sampled from more than 80 locations along the river and analysed for organic contaminants, nutrients, metals, pathogen indicators, microbial activity and diversity as well as microplastics, integrating in-situ fluorescence and UV absorbance optical sensor technologies with laboratory sample preparation and analyses. Water and sediment samples were analysed to identify the co-existence of pollution hotspots, quantify their spatial footprint and identify potential source areas, dilution, connectivity and thus, derive understanding of the interactions between proximal and distal of sources solute and particulate pollutants.&lt;/p&gt;&lt;p&gt;Our results reveal the co-existence of distinct pollution hotspots for several contaminants that can be linked to population density and land use in the proximity of sampling sites as well as the contributing catchment area. While some pollution hotspots were characterised by increased concentrations of most contaminant groups, several hotspots of specific pollutants (e.g., microplastics) were identified that could be linked to specific cultural and religious activities. Interestingly, the downstream footprint of specific pollution hotspots from contamination sources along the main stem of the Ganges or through major tributaries varied between contaminants, with generally no significant downstream accumulation emerging in water pollution levels, bearing significant implications for the spatial reach and legacy of pollution hotspots. Furthermore, the comparison of the downstream evolution of multi-pollution profiles between surface water and sediment samples support interpretations of the role of in-stream fate and transport processes in comparison to patterns of pollution source zone activations across the channel. In reporting the development of this multi-dimensional pollution dataset, we intend to stimulate a discussion on the usefulness of large river network surveys to better understand the relative contributions, footprints and impacts of variable pollution sources and how this information can be used for integrated approaches in water resources and pollution management.&lt;/p&gt;

scholarly journals Seasonal study of contamination by metal in water and sediment in a sub-basin in the southeast of Brazil

2011 ◽  
Vol 71 (4) ◽  
pp. 833-843 ◽  
Author(s):  
WAC. Chiba ◽  
MD. Passerini ◽  
JAF. Baio ◽  
JC. Torres ◽  
JG. Tundisi
Keyword(s):  
Rainy Season ◽  
Principal Component ◽  
Dry Season ◽  
Seasonal Differences ◽  
Sediment Samples ◽  
Fluorescent Lamps ◽  
Water And Sediment ◽  
Temporal Occurrence ◽  
Bodies Of Water ◽  
Water And Sediment Samples

The spatial and temporal occurrence of heavy metals (Al, Cd, Pb, Zn, Cr, Co, Cu, Fe, Mn and Ni) in water and sediment samples was investigated in a sub-basin in the southeast of Brazil (São Carlos, SP). All samples were analysed using the USEPA adapted metal method and processed in an atomic absorption spectrophotometer. The discriminant analysis demonstrated that there are significant seasonal differences of metal distribution in the water data, but there are no differences to sediment. The basin studied has high levels of contamination by toxic metals in superficial water and sediment. The superficial water, in the rainy season, presented high levels of Cr, Ni, Pb and Cd, while in the dry season it presented high levels of Zn and Ni. The Principal Component Analysis demonstrated that the season has a huge influence on the levels, types and distribution of metals found in water. The source of contamination was probably diffuse, due to products such as batteries and fluorescent lamps, whose dump discharge can contaminate the bodies of water in the region in the rainy season. Due to fires from the harvest of sugar cane, high levels of Zn were found into the environment, in the dry season.

Risk Assessment for Niclosamide Residues in Water and Sediments from Nan Ji Shan Island within Poyang Lake Region, China

2013 ◽  
Vol 721 ◽  
pp. 608-612 ◽  
Author(s):  
Dong Gen Huang ◽  
Jian Hui Zhen ◽  
Shui Qing Quan ◽  
Miao Liu ◽  
Lei Liu
Keyword(s):  
Risk Assessment ◽  
Environmental Protection Agency ◽  
High Performance ◽  
Poyang Lake ◽  
Sediment Samples ◽  
Poyang Lake Region ◽  
Lake Region ◽  
Water And Sediment ◽  
The Us ◽  
Water And Sediment Samples

The objective of this study was to determine and assess niclosamide residue levels in the Nan Ji Shan island within Poyang Lake Region, from March to June, September, October and December of 2012. Water and sediment samples from the Nan Ji Shan island were extracted with alkaline ethylacetate,and were detected by high performance liquid chromatography (HPLC). Niclosamide residues were detected in all water and sediment samples in varying concentrations during the two periods using molluscicide, niclosamide residues concentration water samples ranged from 0.01 to 0.038 mg/L, and from 0.1 to 0.473 mg/kg in sediments. According to the guidelines for potential risk assessment drawn up by the US Environmental Protection Agency, the risk of niclosamide residue was assessed. The results indicated that it would cause greater effect on fish, invertebrates and aquatic plants, but the influence on human and avian was relatively smaller.

scholarly journals Biokonsentrasi Timbal (Pb) pada Hepatopankreas, Insang dan Daging Penaeus merguiensis di Teluk Kelabat Bagian Luar

2019 ◽  
Vol 22 (2) ◽  
pp. 109
Author(s):  
Derra Alianie Tawa ◽  
Budi Afriyansyah ◽  
Muhammad Ihsan ◽  
Mohammad Agung Nugraha
Keyword(s):  
Heavy Metals ◽  
Daily Intake ◽  
The Body ◽  
Mining Activities ◽  
Sediment Samples ◽  
Water And Sediment ◽  
Safe Limit ◽  
Penaeus Merguiensis ◽  
Pb Concentration ◽  
Water And Sediment Samples

Illegal tin mining or unconventional mining activities produce tailings. Tailings contain dangerous heavy metals one of which is Lead (Pb). The increasing concentration of Pb in the waters will also increase its concentration in the body of the biota, one of which is shrimp. The purpose of this study was to analyse the Pb content in gills, hepatopancreas and muscle in Penaeus merguiensis, analyse the Pb content in water and sediments, measure the ability of Penaeus merguiensis in accumulating Pb in water and sediments, and determine the safe limit for consumption. Shrimp, water and sediment samples were analysed using AAS. The results showed that the highest Pb concentration in Penaeus merguiensis was hepatopancreas> gill> meat, with an average range of 0,1897–0,4064 mg/kg, gills 0,2424-0,4770 mg/kg, and meat 0,1348-0,1636 mg/kg. The average Pb concentration in water ranged from 0,2624 to 0,5713 mg/L, while the sediment ranged from 0,2783 to 0,9760 mg/kg. The ability of Penaeus merguensis to accumulate Pb included in the low category. The value of daily intake is around 9,760-11,128 kg/week. Aktivitas penambangan timah illegal atau tambang inkonvensional menghasilkan sisa limbah buangan (Tailing). Tailing mengandung logam berat berbahaya salah satunya Timbal (Pb). Meningkatnya konsentrasi Pb di perairan akan meningkat pula konsentrasinya dalam tubuh biota, salah satunya udang. Tujuan dilakukannya penelitian ini adalah menganalisis kandungan Pb pada insang, hepatopankreas dan daging pada Penaeus merguiensis, menganalisis kandungan Pb pada air dan sedimen, mengukur kemampuan Penaeus merguiensis dalam mengakumulasikan Pb di air dan sedimen, dan menentukan nilai batas aman konsumsi. Sampel udang, air dan sedimen dianalisis menggunakan AAS. Hasil penelitian menunjukkan bahwa konsentrasi Pb tertinggi pada Penaeus merguiensis adalah hepatopankreas>insang>daging, dengan kisaran rata-rata 0,1897–0,4064 mg/kg, insang 0,2424-0,4770 mg/kg, dan daging 0,1348-0,1636 mg/kg. Konsentrasi Pb rata-rata dalam air berkisar antara 0,2624-0,5713 mg/L, sementara sedimen berkisar dari 0,2783-0,9760 mg/kg. Kemampuan Penaeus merguensis untuk mengakumulasi Pb termasuk dalam kategori rendah. Nilai asupan harian sekitar 9,760-11,128 kg/minggu.

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