scholarly journals Status and Speciation of Silicon and Its Interaction with Physico-Chemical Properties

Author(s):  
Isaiah Ufuoma Efenudu ◽  
Ehi Robert Orhue ◽  
Ogochukwu Jennifer Ikeh ◽  
Michael Aimiesomon Erhayimwen ◽  
Blessing James

The effectiveness of three different extractants soil mixtures—HCl, HCl + H2S04, and DTPA-TEA, in order to determine Si from soil and the forms of Silicon as influenced by different parent materials under acidic medium. Seven forms of Silicon; namely water soluble, specifically adsorbed, oxides bound, organic matter bound, exchangeable, residual, total viz sequential fractionation. Extractable Si value established in this study was (50.0 mg kg-1), indicating negative effect on plant physiology. The physico-chemical properties decreased significantly with increase in soil depth vs soil parent materials. In addition, the forms of Si in the parent materials decreased in the pattern RES, bound residual fractions > EXC, soluble & exchangeable fractions > OM, organic matter fraction. Among the properties the silt fraction, pH & OM significantly and positively correlated with the forms of silicon, with negative correlation vs clay which maybe due to silicon adsorption by clayey fraction of the soil (redox). Therefore the soil maybe be maintained and conserved for farming activities.

2017 ◽  
Vol 23 (3) ◽  
pp. 350-361 ◽  
Author(s):  
Hisham Al-Obaidi ◽  
Mridul Majumder ◽  
Fiza Bari

Crystalline and amorphous dispersions have been the focus of academic and industrial research due to their potential role in formulating poorly water-soluble drugs. This review looks at the progress made starting with crystalline carriers in the form of eutectics moving towards more complex crystalline mixtures. It also covers using glassy polymers to maintain the drug as amorphous exhibiting higher energy and entropy. However, the amorphous form tends to recrystallize on storage, which limits the benefits of this approach. Specific interactions between the drug and the polymer may retard this spontaneous conversion of the amorphous drug. Some studies have shown that it is possible to maintain the drug in the amorphous form for extended periods of time. For the drug and the polymer to form a stable mixture they have to be miscible on a molecular basis. Another form of solid dispersions is pharmaceutical co-crystals, for which research has focused on understanding the chemistry, crystal engineering and physico-chemical properties. USFDA has issued a guidance in April 2013 suggesting that the co-crystals as a pharmaceutical product may be a reality; but just not yet! While some of the research is still oriented towards application of these carriers, understanding the mechanism by which drug-carrier miscibility occurs is also covered. Within this context is the use of thermodynamic models such as Flory-Huggins model with some examples of studies used to predict miscibility.


2016 ◽  
Author(s):  
Zhaolian Ye ◽  
Jiashu Liu ◽  
Aijun Gu ◽  
Feifei Feng ◽  
Yuhai Liu ◽  
...  

Abstract. Knowledge on aerosol chemistry in densely populated regions is critical for reduction of air pollution, while such studies haven't been conducted in Changzhou, an important manufacturing base and polluted city in the Yangtze River Delta (YRD), China. This work, for the first time, performed a thorough chemical characterization on the fine particular matter (PM2.5) samples, collected during July 2015 to April 2016 across four seasons in Changzhou city. A suite of analytical techniques were employed to characterize organic carbon / elemental carbon (OC / EC), water-soluble organic carbon (WSOC), water-soluble inorganic ions (WSIIs), trace elements, and polycyclic aromatic hydrocarbons (PAHs) in PM2.5; in particular, an Aerodyne soot particle aerosol mass spectrometer (SP-AMS) was deployed to probe the chemical properties of water-soluble organic aerosols (WSOA). The average PM2.5 concentrations were found to be 108.3 μg m−3, and all identified species were able to reconstruct ~ 80 % of the PM2.5 mass. The WSIIs occupied about half of the PM2.5 mass (~ 52.1 %), with SO42−, NO3− and NH4+ as the major ions. On average, nitrate concentrations dominated over sulfate (mass ratio of 1.21), indicating influences from traffic emissions. OC and EC correlated well with each other and the highest OC / EC ratio (5.16) occurred in winter, suggesting complex OC sources likely including both secondarily formed and primarily emitted OA. Concentrations of eight trace elements (Mn, Zn, Al, B, Cr, Cu, Fe, Pb) can contribute up to 6.0 % of PM2.5 during winter. PAHs concentrations were also high in winter (140.25 ng m−3), which were predominated by median/high molecular weight PAHs with 5- and 6-rings. The organic matter including both water-soluble and water-insoluble species occupied ~ 20 % PM2.5 mass. SP-AMS determined that the WSOA had an average atomic oxygen-to-carbon (O / C), hydrogen-to-carbon (H / C), nitrogen-to-carbon (N / C) and organic matter-to-organic carbon (OM / OC) ratios of 0.36, 1.54, 0.11, and 1.74, respectively. Source apportionment of WSOA further identified two secondary OA (SOA) factors (a less oxidized and a more oxidized OA) and two primary OA (POA) factors (a nitrogen enriched hydrocarbon-like traffic OA and a cooking-related OA). On average, the POA contribution overweighed SOA (55 % vs. 45 %), indicating the important role of local anthropogenic emissions to the aerosol pollution in Changzhou. Our measurement also shows the abundance of organic nitrogen species in WSOA, and the source analyses suggest these species likely associated with traffic emissions, which warrants more investigations on PM samples from other locations.


Author(s):  
Gebeyaw Tilahun Yeshaneh

The study was conducted at the Abuhoy Gara Catchment, which is located in the Gidan District of North Wello Zone. The aim of the study was to study farmers’ perceptions about the effect of farm land management practices and soil depth on the distribution of major soil physico-chemical properties in eroded soils of Aboy Gara watershed. To address this issue, semi-structured interviews were conducted in 64 households to gain insight into soil fertility management practices, local methods were used to assess the fertility status of a field, and perceived trends in soil fertility. Thirty-three farmers were then asked to identify fertile and infertile fields. According to farmers response, farmers’ fields were characterized as fertile where it comprise black color, cracks during dry season, good crop performance, vigorous growth of certain plants and presence of plants in a dry environment whereas the infertile is where it shows yellow/white and red colors, compacted soils, stunted plant growth, presence of rocks and stones and wilting or dying of crops in a hot environment. A total of eight indicators (soil color, texture, soil depth, topography, soil drainage, and distance from home, type of weeds grown and cultivation intensity) were found to be used by farmers to evaluate and monitor soil fertility. The results of administered questions showed that the principal indicators mentioned by farmers as very important were soil colour (82.8%), continuous cropping land (72.2%), soil texture (62.8%), distance from home (61%), type of weeds grown (56%), soil depth (55.6%), topography (51.1%), and soil drainage (28.7%) as very important. So, among sixty four interviewed farmers: deep soil (60 farmers), soils near to home (60 farmers), forest soil (59 farmers), smooth fine soil (59 farmers), black color soil (58 farmers) and gentle slope soil (57farmers) are categorized as fertile whereas 59, 57, 56, 55, and 44farmers said that Sandy/coarse soil, shallow soil depth, steep slope soils and yellow/white, red soils and continuously cultivated soils are infertile, respectively. The overall result showed that there was good agreement between farmers’ assessment of the soil fertility status of a field and a number of these indicators. The soil laboratory analysis also corresponded well with farmers’ assessment of soil fertility. Therefore, to design more appropriate research and to facilitate clear communication with farmers, researchers need to recognize farmers’ knowledge, perceptions about assessments of soil fertility. Because, as they included all soil factors affecting plant growth, farmers’ perceptions of soil fertility were found to be more long term day-to-day close practical experience finding than those of researchers.


2020 ◽  
pp. 6-12
Author(s):  
Tahsina Sharmin Hoque ◽  
Shafia Afrin ◽  
Israt Jahan ◽  
Md. Joinul Abedin Mian ◽  
Mohammad Anwar Hossain

Soil depth can significantly influence the availability of nutrients in soil. An experiment was conducted with seven soil samples from seven land use types to observe the effect of soil depth on soil properties under various land use systems. Soil pH, electrical conductivity (EC), organic matter, available phosphorus (P), available sulphur (S) and different forms of potassium (K) such as water soluble, exchangeable and non-exchangeable were determined from the soil samples collected from four soil depths (viz. 0-10, 10-20, 20-30 and 30-40 cm). Soil pH varied from 6.30-7.39 irrespective of depths and land uses and it increased with increasing soil depth. Electrical conductivity of the soils ranged from 42-310 µS cm-1 and organic matter status of most of the soils was very low to medium in level. Both EC and organic matter content decreased with the increase of soil depth. Available P concentration showed no specific changing trend with soil depth whereas available S concentration under different land use systems decreased with increasing soil depth. The concentrations of water soluble, exchangeable and non-exchangeable K in soils varied from 12.30-39.60, 20.90-53.16 and 163.30-684.30 mg kg-1, respectively and showed no specific changing pattern with soil depth. Water soluble K content was higher in rice growing fertilizer and manure-treated soil but higher exchangeable and non-exchangeable K contents were observed in banana growing soil. In rice growing soils, nutrient concentration is mostly higher in nitrogen (N), P and K + farm yard manure (FYM) - treated plots compared to rice growing control plots.


2020 ◽  
Vol 150 ◽  
pp. 03010
Author(s):  
Hassnae Maher ◽  
Rachid Moussadek ◽  
Abdelmjid Zouahri ◽  
Ahmed Douaik ◽  
Houria Dakak ◽  
...  

In Morocco, agriculture is an important sector of the economy, accounting for 15 to 20% of Gross Domestic Product. However, it has faced several challenges: intensive tillage of land that has accelerated water erosion, seriously threatening water and soil potential, low plant cover density and misuse of traditional agricultural practices, causing a decrease in organic matter levels and destroying aggregate stability. Climate change is making water and soil management in agriculture more and more complicated. The major challenge for Moroccan agriculture is to increase agricultural production while preserving natural resources. The objective of our study is to evaluate the effect of no tillage (NT) on the physico- chemical properties of soil in the El Koudia experimental station, Rabat, Morocco. The crop is durum wheat, Arrehane variety. Soil samples are pre-dried, ground and screened to 0.2mm for organic matter (OM) analysis and 2mm for the remainder of the analyses. Plugs, canned, are then sintered, screened and dried for structural stability tests. The results show that no tillage (NT) favours the accumulation of surface OM, particularly at the 0-5cm horizon unlike conventional tillage (CT). The NT promotes structural stability, with a mean weight diameter (MWD) = 0.94mm for the NT compared to 0.83mm for the CT. These results show that soils ploughed in CT are more exposed to erosion degradation than soils not ploughed (NT). In addition, NT preserves soil moisture and promotes additional water retention of 5 to 10%.


2019 ◽  
Vol 9 (13) ◽  
pp. 2598 ◽  
Author(s):  
M. J. Hernández-Rodríguez ◽  
R. Santana Rodríguez ◽  
R. Darias ◽  
O. González Díaz ◽  
J. M. Pérez Luzardo ◽  
...  

In this study, mortar specimens were prepared with a cement:sand:water ratio of 1:3:0.5, in accordance with standard EN196-1. Portland CEM I 52.5 R grey (G) and white (W) cements were used, together with normalised sand and distilled water. Different amounts of TiO2 photocatalyst were incorporated in the preparation of the mortar samples. The effect of the addition of TiO2 was studied on mechanical properties of the mortar and cement including compressive and flexural strength, consistency (the flow table test), setting time and carbonation. Characterization techniques, including thermogravimetry, mercury porosimetry and X-ray diffraction spectroscopy (XRD), were applied to study the physico-chemical properties of the mortars. It was shown that adding the photocatalyst to the mortar had no negative effect on its properties and could be used to accelerate the setting process. Specimen photoactivity with the incorporated photocatalyst was tested for NOx oxidation in different conditions of humidity (0% RH and 65% RH) and illumination (Vis or Vis/UV), with the results showing an important activity even under Vis radiation.


2015 ◽  
Vol 211 ◽  
pp. 487-493 ◽  
Author(s):  
Olga S. Manyakina ◽  
Konstantin N. Semenov ◽  
Nikolay A. Charykov ◽  
Natalia M. Ivanova ◽  
Viktor A. Keskinov ◽  
...  

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