scholarly journals Air Pollution Control by Using Advanced Oxidation Processes (AOPs)

Author(s):  
K. Arun Kumar ◽  
B. S. Shilpa ◽  
S. Sandeep

Among air pollution control strategies, air cleaning with Advanced Oxidation Processes (AOPs) has been drawing more and more attention because of the restraints in the production of secondary pollution. AOPs have a wide range of applications such as air (odour elimination, purification), soil (remediation) and water decontamination. Ideally, the photo catalyst, titanium dioxide, is introduced in the top layer of the concrete pavement for best results. In addition, the combination of TiO2 with cement-based products offers some synergistic advantages, as the reaction products can be adsorbed at the surface and subsequently be washed away by rain. The main aim of this research work is to measure the effect of titanium dioxide as photo catalyst in purifying nitrogen oxide (NOX) and Carbon Oxides (COX) on pavement surface and outdoor environment condition. For that, TiO2 is replaced for cement at different proportions of 5%, 10% & 15% in terms of weight in the cement concrete moulds of 10 mm uniform thickness and curing is done for seven days, then same were exposed to the sunlight at Ijoor circle sampling point Rama Nagar Town for 21 days of observation. From the Energy Dispersive Spectroscopy (EDS) analysis, result it is observed that atom percentage increased maximum of 59.05 for carbon atoms for 10% proportion specimen. Then, check the amount of  percentage for carbon atoms adsorbed by 10% proportion specimen at police/Kandaya Bhavan circle and Railway station circle sampling points of Rama Nagar Town for 21 days of observations and the results shows that, carbon atom percentage increased maximum of 42.99 and 58.69 for carbon atoms respectively at above sampling points. From this work, it is conclude that the  Carbon atoms and Nitrogen atoms present in the atmosphere will be reduce up to some level when replace 10% of Titanium dioxide with cement in the concrete  moulds of 10 mm thickness by Photo catalytic activity.

2019 ◽  
Vol 9 (13) ◽  
pp. 2652 ◽  
Author(s):  
Jéssica Martini ◽  
Carla A. Orge ◽  
Joaquim L. Faria ◽  
M. Fernando R. Pereira ◽  
O. Salomé G. P. Soares

The degradation of sulfamethoxazole (SMX) by several advanced oxidation processes (AOPs) is carried out in the presence of different catalysts. The catalysts used consisted of carbon nanotubes (CNT), titanium dioxide (TiO2), a composite of carbon nanotubes and titanium dioxide (TiO2/CNT), and iron supported on carbon nanotubes (Fe/CNT). SMX removal was evaluated by catalytic ozonation, photocatalysis, catalytic oxidation with hydrogen peroxide, and combinations of these processes. The evolution of the SMX concentration during reaction time, the mineralization degree, the toxicity of the treated solution, and the formation of organic intermediates and ions were monitored. Ozonation catalyzed by Fe/CNT and CNT and photocatalytic ozonation in the presence of CNT presented the fastest degradation of SMX, whereas photocatalytic ozonation with CNT showed the best results in terms of organic matter removal (92% of total organic carbon (TOC) depletion). Total mineralization of the solution and almost complete reduction of toxicity was only achieved in the photocatalytic ozonation with H2O2 and Fe/CNT catalysts. The compound 3-amino-5-methylisoxazole was one of the first intermediates formed during SMX degradation. p-Benzoquinone was only formed in photocatalysis. Oxalic and oxamic acids were also detected and in most of the catalytic processes they appeared in small amounts. Ion concentrations increased with the reaction time.


2018 ◽  
Vol 59 ◽  
pp. 00017
Author(s):  
Kamil Kuźmiński ◽  
Antoni W. Morawski ◽  
Magdalena Janus

In these studies advanced oxidation processes such as: photolysis, ozonation and photocatalysis for anionic and cationic surfactants decomposition were used. Nitrogen modified titanium dioxide and commercial TiO2-P25 were used for photocatalytic tests. UV-C lamp and different dose of ozone: 186, 383, 478 and 563 mg/(dm3·h) were used. The optimal system for anionic and cationic surfactants decomposition was connection of ozonation with UV-C irradiation.


2016 ◽  
Vol 3 (1) ◽  
pp. 141-158 ◽  
Author(s):  
Getachew A. Adnew ◽  
◽  
Carl Meusinger ◽  
Nicolai Bork ◽  
Michael Gallus ◽  
...  

2019 ◽  
Vol 1 (1) ◽  
pp. 11-15
Author(s):  
Mirela Alina Constantin ◽  
Lucian Alexandru Constantin ◽  
Ines Nitoi ◽  
Ionut Cristea ◽  
Ellea Boulac

Degradation experiments on 5-Fluorouracil synthetic solutions were performed using three types of advanced oxidation systems: UV/H2O2, UV/TiO2 and UV/H2O2/TiO2. Optimum parameters for all three systems were established and 5-Fluorouracil degradation efficiencies were calculated, for all systems being more than 97%. The results showed that the combined UV/H2O2/TiO2 system is offering shortest irradiation time, the possibility to recover and reuse the photo catalyst as well as the possibility to use solar radiation. Obtained results proved also that advanced oxidation processes represent a viable option for degradation of hazardous pollutants that cannot be removed properly via conventional wastewater treatment processes.


1992 ◽  
Vol 27 (1) ◽  
pp. 1-22 ◽  
Author(s):  
J. H. Carey

Abstract Various processes that have been suggested for the oxidation of organic compounds in wastewater are summarized. The most widely applicable are based on generation of hydroxyl radicals via the photolysis of hydrogen peroxide, ozone and titanium dioxide. Other methods of generating hydroxyl radicals and other oxidants, as well as other methods of oxidation that have been suggested for organic wastewater treatment are also discussed.


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