Timing and Mechanisms of Silicate Differentiation and Basalt Magma Generation on the Howardite-Eucrite-Diogenite Asteroid Parent Body

<p>Meteorites provide the only direct record of the chronology and nature of the processes that occurred in the early solar system. In this study, meteorites were examined in order to gain insight into the timing and nature of magmatism and silicate differentiation on asteroidal bodies in the first few million years of the solar system. These bodies are considered the precursors to terrestrial planets, and as such they provide information about conditions in the solar system at the time of planet formation. This study focuses on eucrites, which are basaltic meteorites that are believed to represent the crust of the Howardite-Eucrite-Diogenite (HED) parent body. The processes of silicate differentiation and the relationship between eucrites and the diogenitic mafic cumulate of the HED parent body are poorly understood. The major and trace element chemistry of the minerals in the eucrite suite was measured. There is little variability in mineral major element concentrations in eucrites, however considerable variability was observed in mineral trace element concentrations, particularly with respect to incompatible elements in the mineral phases. Magnesium was separated from digested eucrite samples, and the Mg isotope composition of the eucrites was measured to high precision in order to date the samples using the short-lived ²⁶Al–²⁶Mg chronometer and examine magmatic evolution on the HED parent body. Correlations between incompatible elements in pyroxene and ²⁶Mg anomalies, produced by the decay of ²⁶Al, indicate that the eucrite suite was formed from a single, evolving magma body. Large trace element and Mg isotopic differences between eucrites and diogenites indicate that the two meteorite groups did not, as previously suggested, originate from the same magma body. Instead they may have formed from two large magma bodies, which were spatially or temporally separated on the HED parent body. The application of the short-lived ²⁶Al–²⁶Mg chronometer to this suite of eucrites constrains the onset of eucrite formation to ~3 Myr after the formation of the solar system’s first solids, as a result of rapid accretion and melting of planetesimals due to heating from the decay of ²⁶Al.</p>

Timing and Mechanisms of Silicate Differentiation and Basalt Magma Generation on the Howardite-Eucrite-Diogenite Asteroid Parent Body

<p>Meteorites provide the only direct record of the chronology and nature of the processes that occurred in the early solar system. In this study, meteorites were examined in order to gain insight into the timing and nature of magmatism and silicate differentiation on asteroidal bodies in the first few million years of the solar system. These bodies are considered the precursors to terrestrial planets, and as such they provide information about conditions in the solar system at the time of planet formation. This study focuses on eucrites, which are basaltic meteorites that are believed to represent the crust of the Howardite-Eucrite-Diogenite (HED) parent body. The processes of silicate differentiation and the relationship between eucrites and the diogenitic mafic cumulate of the HED parent body are poorly understood. The major and trace element chemistry of the minerals in the eucrite suite was measured. There is little variability in mineral major element concentrations in eucrites, however considerable variability was observed in mineral trace element concentrations, particularly with respect to incompatible elements in the mineral phases. Magnesium was separated from digested eucrite samples, and the Mg isotope composition of the eucrites was measured to high precision in order to date the samples using the short-lived ²⁶Al–²⁶Mg chronometer and examine magmatic evolution on the HED parent body. Correlations between incompatible elements in pyroxene and ²⁶Mg anomalies, produced by the decay of ²⁶Al, indicate that the eucrite suite was formed from a single, evolving magma body. Large trace element and Mg isotopic differences between eucrites and diogenites indicate that the two meteorite groups did not, as previously suggested, originate from the same magma body. Instead they may have formed from two large magma bodies, which were spatially or temporally separated on the HED parent body. The application of the short-lived ²⁶Al–²⁶Mg chronometer to this suite of eucrites constrains the onset of eucrite formation to ~3 Myr after the formation of the solar system’s first solids, as a result of rapid accretion and melting of planetesimals due to heating from the decay of ²⁶Al.</p>

Relationships among the Geordie Lake Cu-Pd deposit, alkaline basalt, and syenites in the Coldwell Complex, Midcontinent Rift, Canada

ABSTRACT The Geordie Lake Cu-Pd deposit is associated with troctolite at the base of the Geordie Lake intrusion, located near the center of the Coldwell Complex (1106.5 + 1.2 Ma). It is the only platinum group element deposit in the Midcontinent Rift associated with alkaline rocks. This study focuses on the long-standing questions regarding genetic relationships among the Geordie Lake gabbros, the Wolfcamp basalt, and the various syenites that make up the east-central portion of the Coldwell Complex. Primitive mantle-normalized trace-element patterns for the Geordie Lake intrusion are nearly flat from Th to Ce and show negative Sr, Eu, and Zr anomalies. Characteristic ratios for the Geordie Lake gabbro and troctolite include Th/Nb (0.12), La/Nb (1.1), La/Lu (150), La/Sm (6.9), Zr/Sm (18), and Gd/Yb (2.8). Trace-element patterns that are useful for determining petrogenesis for gabbros are similar to the Wolfcamp basalt and augite syenite with some key exceptions, notably the middle rare earth element and Zr abundances. Affects due to metasomatism or crustal contamination in Wolfcamp basalt and Geordie Lake gabbros and syenites are negligible. Results of Rayleigh fractionation modeling show (1) the Geordie Lake intrusion and Wolfcamp basalt are very similar but not directly related by crystallization, (2) the gabbros and basalt are not related to the syenites, (3) the lower augite syenite can be related to the upper augite syenite and amphibole quartz syenite by fractionation of a hypothetical crystal cumulate composed of orthoclase (78%), clinopyroxene (15%), olivine (1%), and titanomagnetite (6%). We conclude that the Geordie Lake intrusion, Wolfcamp basalt, and saturated syenites in the Coldwell were derived by separate partial melting events in a common mantle source. The origin of the sulfide mineralization is enigmatic because it exhibits characteristics of both magmatic and hydrothermal processes. The sulfide assemblage changes from disseminated bornite and chalcopyrite in the basal zone to pyrrhotite plus chalcopyrite in the upper zones. Sulfides occur as coarse blebs interstitial to fresh or partly altered silicates, or as very fine grains intergrown with clusters of biotite and actinolite. Primitive mantle-normalized platinum group element patterns exhibit a W-shape for Pd-Pt-Rh-Ir-Ni, indicating a relative depletion of Pt and Ir. The Cu/Pd ratios in the mineralized zones are within the range of mantle values (1000–10,000), Pd/Pt is 14–19, Pd/Rh is 91 + 37, and Pd/Ir &gt;16,000. The Pd/Pt, Pd/Rh, and Pd/Ir are considerably higher than in the Wolfcamp basalt (&lt;1, 17, and 75, respectively). If the sulfides are magmatic in origin, then either the Geordie Lake magma was, unlike the Wolfcamp basalt magma, depleted in Pt, Rh, and Ir, or these elements were selectively removed from the sulfide assemblage. Alternatively, Pd was enriched by late-stage hydrothermal processes. Additional work is recommended to constrain petrogenesis of the sulfides by detailed base-metal and TABS (Te, As, Bi, Sb, and Sn) element analysis.

Halogen Enrichment of Siberian Traps Magmas During Interaction With Evaporites

Volatile emissions to the atmosphere associated with the Siberian Traps eruptions at the Permian-Triassic boundary were sourced from the outgassing of primary magmas and the sedimentary host rocks into which they were intruded. Halogens in volcanic gases may have played an important role in environmental degradation and in stratospheric ozone destruction. Here we investigate how halogens behave during the interaction between salts and basalt magma emplaced as sills and erupted as lava. We present whole-rock, trace, and halogen concentrations for a suite of samples from three locations in the Siberian Traps Large Igneous Province, including basalt lavas erupted, and dolerites intruded into both organic-bearing shales and evaporites. Dolerites are enriched in Cl, Br, and I; their enrichment in Cl is similar to MORB and OIB that have been inferred to have assimilated seawater. The dolerites exhibit halogen compositional systematics, which extend towards both evaporites and crustal brines. Furthermore, all analyzed samples show enrichment in Rb/Nb; with the dolerites also showing enrichment in Cl/K similar to MORB and OIB that have been inferred to have assimilated seawater. We infer that samples from all three locations have assimilated fluids derived from evaporites, which are components of crustal sedimentary rocks. We show that up to 89% of the chlorine in the dolerites may have been assimilated as a consequence of the contact metamorphism of evaporites. We show, by thermal modeling, that halogen transfer may occur via assimilation of a brine phase derived from heating evaporites. Halogen assimilation from subcropping evaporites may be pervasive in the Siberian Traps Large Igneous Province and is expected to have enhanced emissions of Cl and Br into the atmosphere from both intrusive and extrusive magmatism.

Chemical-physical constraints of the 2015 eruptive activity of Mt. Etna: new insights from thermo-barometry and geochemistry of olivine-hosted melt inclusions

&lt;p&gt;The concomitant activation off all four summit craters of Mt. Etna during the December 2015 eruptive event allow us to investigate the chemical-physical crystallization conditions and magma dynamics in the shallower portion of the open-conduit feeding system. In this study, we discuss new petrological, geochemical and thermo-barometric data as well as the composition of major element and volatile content (H&lt;sub&gt;2&lt;/sub&gt;O, CO&lt;sub&gt;2&lt;/sub&gt;, F, Cl and S) of olivine-hosted melt inclusions from the explosive and effusive products emitted during the December 2015 eruptive event.&lt;/p&gt;&lt;p&gt;Results and rhyolite-MELTS thermodynamic modelling of mineral phase stability highlight the relatively shallow crystal equilibrium depth prior to the eruption ranging from 400-500 MPa for Central Crater and North East Crater, up to 200 MPa below the New South East Crater. The study of high-pressure and high-temperature homogenized olivine-hosted melt inclusions allowed us to identify the composition of the almost primary alkali-basalt magma (11.8 wt% MgO) containing up to 4.9 wt% and 8151 ppm of H&lt;sub&gt;2&lt;/sub&gt;O and CO&lt;sub&gt;2 &lt;/sub&gt;respectively. The results, together with those already reported for the previous paroxystic events of the 2011-2012 (Giacomoni et al., 2018), reinforce the model of a vertically extended feeding system and highlight that the activity at the New South East Crater was fed by a magma residing at significant shallower depth with respect to Central Craters and North East Crater, although all conduits are fed by a common deep (P = 530-440 MPa) basic magmatic refilling. Plagioclase stability model and dissolution and resorption textures confirm its dependence on H&lt;sub&gt;2&lt;/sub&gt;O content, thus suggesting that further studies on the effect that flushing from fluids with different H&lt;sub&gt;2&lt;/sub&gt;O/CO&lt;sub&gt;2&lt;/sub&gt; ratio are needed in order to understand the eruption triggering mechanisms of paroxystic fountaining.&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;&lt;p&gt;&lt;strong&gt;References&lt;/strong&gt;&lt;/p&gt;&lt;p&gt;Giacomoni P., Coltorti M., Mollo S., Ferlito C., Braiato M., Scarlato P. 2018. The 2011-2012 paroxysmal eruptions at Mt. Etna volcano: Insights on the vertically zoned plumbing system. JVGR 349, 370-391.&lt;/p&gt;

Geochemistry of Karoo basalts and dolerites in the northeastern Orange Free State: Recognition and origin of new Karoo basalt magma types. NE Free State.xls

One of the most significant results emerging from the Karoo Volcanics Project of the NGP ls the recognition of a number of geochemically distinct basalt magma types occurring within the lower part of the Karoo volcanic pile in the Northeastern Cape and Southern Lesotho.<div>NE Free State<br></div>

Geochemistry of Karoo basalts and dolerites in the northeastern Orange Free State: Recognition and origin of new Karoo basalt magma types. NE Free State.xls

One of the most significant results emerging from the Karoo Volcanics Project of the NGP ls the recognition of a number of geochemically distinct basalt magma types occurring within the lower part of the Karoo volcanic pile in the Northeastern Cape and Southern Lesotho.<div>NE Free State<br></div>