Halogen Enrichment of Siberian Traps Magmas During Interaction With Evaporites

Volatile emissions to the atmosphere associated with the Siberian Traps eruptions at the Permian-Triassic boundary were sourced from the outgassing of primary magmas and the sedimentary host rocks into which they were intruded. Halogens in volcanic gases may have played an important role in environmental degradation and in stratospheric ozone destruction. Here we investigate how halogens behave during the interaction between salts and basalt magma emplaced as sills and erupted as lava. We present whole-rock, trace, and halogen concentrations for a suite of samples from three locations in the Siberian Traps Large Igneous Province, including basalt lavas erupted, and dolerites intruded into both organic-bearing shales and evaporites. Dolerites are enriched in Cl, Br, and I; their enrichment in Cl is similar to MORB and OIB that have been inferred to have assimilated seawater. The dolerites exhibit halogen compositional systematics, which extend towards both evaporites and crustal brines. Furthermore, all analyzed samples show enrichment in Rb/Nb; with the dolerites also showing enrichment in Cl/K similar to MORB and OIB that have been inferred to have assimilated seawater. We infer that samples from all three locations have assimilated fluids derived from evaporites, which are components of crustal sedimentary rocks. We show that up to 89% of the chlorine in the dolerites may have been assimilated as a consequence of the contact metamorphism of evaporites. We show, by thermal modeling, that halogen transfer may occur via assimilation of a brine phase derived from heating evaporites. Halogen assimilation from subcropping evaporites may be pervasive in the Siberian Traps Large Igneous Province and is expected to have enhanced emissions of Cl and Br into the atmosphere from both intrusive and extrusive magmatism.

Petrogenesis and dynamic implications of the Cenozoic alkali basalts from Jingpohu volcanic field, Northeast China.

The Cenozoic alkali basalts are widely exposed in the Jingpohu volcanic field, Northeast China. Previous volcanology and geochronology researches have revealed that they were formed in three periods of Miocene (∼29.23-13.59 Ma), Pleistocene (∼83.7 Ka), and Holocene (∼5500-5200 a BP). The Miocene and Pleistocene basalts consist of alkali olivine basalts, while the Holocene basalts are composed of alkali olivine basalts and leucite tephrites. Petrogenetic studies reveal that the primary magmas of the Miocene and Pleistocene alkali olivine basalts originated from partial melting of EM2-like garnet peridotites, and those of the Holocene alkali olivine basalts were derived from melting of EM1- and EM2-like garnet peridotites with higher garnet proportions. In contrast, the primary magmas of Holocene leucite tephrites were derived from melting of eclogites and peridotites. Combined with previous researches, we suggest that melting of the mantle source region to generate Jingpohu alkali basalts was triggered by decarbonization and dehydration of the slabs stagnated in the mantle transition zone.Supplementary material at https://doi.org/10.6084/m9.figshare.c.5227666

Superhydrous Arc Magmas in the Alpine Context

Magmatic rocks in the Alps are scarce. What little arc magmatism there was pre-dates the Eurasia–Adria collision at 43–34 Ma but ends at 30–29 Ma. Conversely, geochemical data for magmatic rocks from the Alps resemble that of subduction-related magmatic arcs. A characteristic of Alpine magmatism is the occurrence of relatively deep (80–100 km) super-hydrous (>8 wt% H2O) low-K primary magmas in the east and shoshonitic K-rich magmas in the west. These features are likely related to the absence of vigorous mantle wedge convection. Superhydrous primary magmas undergo extensive crystallization and fluid saturation at depth, producing high ratios of plutonic to volcanic rocks. We speculate that superhydrous primary arc magmas are a consequence of slow convergence and the initial architecture of subducting crust.

Petrogeochemical characteristics of mafite-ultramafite rocks of the southern part of the Marunkeu block (Polar Urals)

In the Polar Urals, in the Central and Western tectonic zones, small bodies of mafic-ultramafic rocks are widespread. Their age, petrographic and geochemical features are poorly studied. The paper presents the results of petrographic and petro-geochemical study of muscovite-albite-epidote-amphibole and pyroxene-amphibole-chlorite rocks of the southern part of the Marunkeu block of the Polar Urals, localized in the Middle Riphean sediments of the Nyarovey series and presumably belonging to the Ampelshor complex (O1-2). The primary composition of metamorphites corresponded to high-magnesian, low-titanic, low-alumina, and potassium-sodium tholeiitic hornblende gabbro-dolerites (dolerites) and peridotites formed either from primary magmas melted at the level of the spinel facies from the depleted mantle under the influence of an aqueous fluid, or by intra-chamber differentiation. In terms of the contents of rare and rare-earth elements, they differ from continental riftogenic formations (in particular, dolerites of the Orangyugan-Lemva complex) and are close to the tholeiites of the ensimatic island arcs.

Partition of Ni, Ca and Mn between olivine and carbonated silicate melt

<p>Phenocrysts of olivine with high Ni, low Mn and Ca relative to global MORBs are usually attributed to a stronger role of the pyroxenite melting (Soblev et al., 2005). The Hawaiian shield stage lavas (high Si group) with high bulk-rock and olivine Ni have usually been attributed to the role recycled oceanic crust. However, the Hawaiian plume also produces lavas with Si-undersaturated alkali basalt (low Si group) and relatively low Ni, whose origin has not been well understood. In this study, we examine the role of deep carbon on the magma compositions and their influences on olivine geochemistry. Here by comparing the whole rock and olivine geochemistry data of Hawaiian high Si group basalts with Hawaiian low Si group basalts, we find that the primary magmas of the latter have relatively lower Ni but comparable concentrations of Mn and Ca. However, the high Si group basalt olivines have indistinctive partition coefficient of Ni but significantly lower Mn and Ca than those of the high Si group basalts.</p><p>The deep Earth is a large reservoir of carbon, which when participates in mantle melting would significantly influence the mantle residual minerals and melt compositions. For example, mantle melting with CO<sub>2</sub> is commonly shown to reduce SiO<sub>2</sub> in the melts. Thus, the genesis of the Si-undersaturated alkali basalts has usually been attributed to the role of CO2 (Zhang et al., 2017). The role of CO2 in the genesis of Hawaiian alkali lavas have also been predicted in previous studies. Based on the observations from Hawaiian lavas, we suggest that CO2 played a key role in lowering the partition coefficients of Mn and Ca. We have conducted high pressure-temperature melting experiments on mantle rocks with CO2, and find that CO2 has a potential influence on the partition of Ni, Mn and Ca between olivine and silicate melts, more experiments remain to be further conducted. This work was financially supported by the National Natural Science Foundation of China (91858206, 41876040).</p>

Concentrations of Te, As, Bi, Sb (TABS) and Se in the Marginal Zone of the Bushveld Complex: evidence for crustal contamination and the nature of the magma that formed the Merensky Reef

<p>The association of platinum-group elements (PGE) and the chalcophile elements Te, As, Bi, Sb and Sn (TABS) has been documented in several magmatic sulfide deposits. These groups of elements are either hosted within sulfide minerals, or combine to form discrete platinum-group minerals (PGM) associated with sulfide minerals. However, the concentration of TABS in parental magmas from which magmatic sulfide deposits formed was still missing. This study presents the distribution of TABS and Se in B-1, B-2 and B-3 rocks of the Marginal Zone of the Bushveld Complex. These rocks have been proposed as representative of the parental liquids from which the Bushveld Complex crystallized, thus allowing us to assess the concentration of Se and TABS in the liquids from which some of the largest PGE deposits in the world have formed. Concentrations of As and Sb in the initial Bushveld liquid (B-1) are significantly higher than in primary magmas, whereas the Se and TABS of later magmas (B-2 and B-3) are similar to primary magmas. We attribute the difference due upper crustal contamination of the B-1 magma, whereas the B-2 and B-3 magmas were most likely contaminated with a plagioclase-rich residuum formed upon the partial melting of the upper crust. Moreover, we modeled the concentrations of the TABS in the Merensky Reef using a mixture of two of the magma types present in the Marginal Zone (the B-1 and B-2) as the initial silicate liquid. The modeled concentrations closely resemble the measured values obtained for a section across the Merensky Reef at the Impala mine. This supports the B-1 and B-2 mixture as an appropriate initial liquid for the crystallization of the Merensky Reef. The modeling also shows that the distributions of Se, Te and Bi across the Merensky Reef are controlled by the sulfide liquid component. In contrast, As and Sb distributions are influenced both by the amount of silicate melt component in the cumulates and the sulfide liquid component. This is because Se, Te and Bi are moderately to strongly chalcophile elements, but As and Sb are only slightly chalcophile elements. Consequently, the effect of crustal contamination for elements with high partition coefficients between sulfide and silicate liquid (Te, Bi and Se) is obscured by the interaction of sulfides with a large volume of silicate magma. Therefore, the concentrations of these elements are higher in samples with greater proportions of sulfide minerals. In contrast, for elements with lower partition coefficients (As and Sb), the whole-rock concentrations are not upgraded by the presence of sulfide minerals, and thus the effect of crustal contamination can be more readily assessed.</p>

Mantle Melting and Magmatic Processes Under La Picada Stratovolcano (CSVZ, Chile)

Where and how arc magmas are generated and differentiated are still debated and these questions are investigated in the context of part of the Andean arc (Chilean Southern Volcanic Zone) where the continental crust is thin. Results are presented for the La Picada stratovolcano (41°S) that belongs to the Central Southern Volcanic Zone (CSVZ) (38°S–41·5°S, Chile) which results from the subduction of the Nazca plate beneath the western margin of the South American continent. Forty-seven representative samples collected from different units of the volcano define a differentiation trend from basalt to basaltic andesite and dacite (50·9 to 65·6 wt % SiO2). This trend straddles the tholeiitic and calc-alkaline fields and displays a conspicuous compositional Daly Gap between 57·0 and 62·7 wt % SiO2. Interstitial, mostly dacitic, glass pockets extend the trend to 76·0 wt % SiO2. Mineral compositions and geochemical data indicate that differentiation from the basaltic parent magmas to the dacites occurred in the upper crust (∼0·2 GPa) with no sign of an intermediate fractionation stage in the lower crust. However, we have currently no precise constraint on the depth of differentiation from the primary magmas to the basaltic parent magmas. Stalling of the basaltic parent magmas in the upper crust could have been controlled by the occurrence of a major crustal discontinuity, by vapor saturation that induced volatile exsolution resulting in an increase of melt viscosity, or by both processes acting concomitantly. The observed Daly Gap thus results from upper crustal magmatic processes. Samples from both sides of the Daly Gap show contrasting textures: basalts and basaltic andesites, found as lavas, are rich in macrocrysts, whereas dacites, only observed in crosscutting dykes, are very poor in macrocrysts. Moreover, modelling of the fractional crystallization process indicates a total fractionation of 43% to reach the most evolved basaltic andesites. The Daly Gap is thus interpreted as resulting from critical crystallinity that was reached in the basaltic andesites within the main storage region, precluding eruption of more evolved lavas. Some interstitial dacitic melt was extracted from the crystal mush and emplaced as dykes, possibly connected to small dacitic domes, now eroded away. In addition to the overall differentiation trend, the basalts to basaltic andesites display variable MgO, Cr and Ni contents at a given SiO2. Crystal accumulation and high pressure fractionation fail to predict this geochemical variability which is interpreted as resulting from variable extents of fractional crystallization. Geothermobarometry using recalculated primary magmas indicates last equilibration at about 1·3–1·5 GPa and at a temperature higher than the anhydrous peridotite solidus, pointing to a potential role of decompression melting. However, because the basalts are enriched in slab components and H2O compared to N-MORB, wet melting is highly likely.

Petrogenesis and Geochemical Properties of Dome-shaped Subvolcanic Complexes in Southwest of Shahrab (Northeast of Isfahan)

<p>The studied area is located in southwest of Shahrab village near Ardestan city. This zone is part of Uremia- Dokhtar magmatic belt. Outcrops composed of rhyolite and rhyodacite dome-shaped volcanic complexes are scattered in the studied area; some of which are exploited as ornamental stone. The main rhyolite minerals include quartz, plagioclase and alkali feldspar. Minor minerals include Apatite, Sphene and opaque minerals and of the secondary minerals in these rocks Christie, Chlorite, Epidote and calcite could be mentioned. Calcite exists in rocks in form of filler of micro-fissures. The ignimbrite presence in this group of rocks in form of xenolith is one of the features of this rock group. The main primary texture in rhyolite and rhyodacite is porphyritic and the secondary texture includes pull-apart, snow flake and spherulitic textures. Geochemical evidences indicate that these rocks are sub-alkaline, Calc-alkaline compositions with high potassium and meta-alumina. These rocks have negative EU anomaly that is the feature of acidic igneous rocks. The studied rocks show high enrichment of LREE and LILE elements. The primary magmas constituting these rocks have mantel origin raised under extreme compressional conditions on continental crust in a tectonic environment of volcanic arc. It seems that these rocks are formed in connection with continuance of volcanic activities associated with subduction of Neolithic oceanic plate beneath continental plate of Iran. </p>