Relationships among the Geordie Lake Cu-Pd deposit, alkaline basalt, and syenites in the Coldwell Complex, Midcontinent Rift, Canada

ABSTRACT The Geordie Lake Cu-Pd deposit is associated with troctolite at the base of the Geordie Lake intrusion, located near the center of the Coldwell Complex (1106.5 + 1.2 Ma). It is the only platinum group element deposit in the Midcontinent Rift associated with alkaline rocks. This study focuses on the long-standing questions regarding genetic relationships among the Geordie Lake gabbros, the Wolfcamp basalt, and the various syenites that make up the east-central portion of the Coldwell Complex. Primitive mantle-normalized trace-element patterns for the Geordie Lake intrusion are nearly flat from Th to Ce and show negative Sr, Eu, and Zr anomalies. Characteristic ratios for the Geordie Lake gabbro and troctolite include Th/Nb (0.12), La/Nb (1.1), La/Lu (150), La/Sm (6.9), Zr/Sm (18), and Gd/Yb (2.8). Trace-element patterns that are useful for determining petrogenesis for gabbros are similar to the Wolfcamp basalt and augite syenite with some key exceptions, notably the middle rare earth element and Zr abundances. Affects due to metasomatism or crustal contamination in Wolfcamp basalt and Geordie Lake gabbros and syenites are negligible. Results of Rayleigh fractionation modeling show (1) the Geordie Lake intrusion and Wolfcamp basalt are very similar but not directly related by crystallization, (2) the gabbros and basalt are not related to the syenites, (3) the lower augite syenite can be related to the upper augite syenite and amphibole quartz syenite by fractionation of a hypothetical crystal cumulate composed of orthoclase (78%), clinopyroxene (15%), olivine (1%), and titanomagnetite (6%). We conclude that the Geordie Lake intrusion, Wolfcamp basalt, and saturated syenites in the Coldwell were derived by separate partial melting events in a common mantle source. The origin of the sulfide mineralization is enigmatic because it exhibits characteristics of both magmatic and hydrothermal processes. The sulfide assemblage changes from disseminated bornite and chalcopyrite in the basal zone to pyrrhotite plus chalcopyrite in the upper zones. Sulfides occur as coarse blebs interstitial to fresh or partly altered silicates, or as very fine grains intergrown with clusters of biotite and actinolite. Primitive mantle-normalized platinum group element patterns exhibit a W-shape for Pd-Pt-Rh-Ir-Ni, indicating a relative depletion of Pt and Ir. The Cu/Pd ratios in the mineralized zones are within the range of mantle values (1000–10,000), Pd/Pt is 14–19, Pd/Rh is 91 + 37, and Pd/Ir >16,000. The Pd/Pt, Pd/Rh, and Pd/Ir are considerably higher than in the Wolfcamp basalt (<1, 17, and 75, respectively). If the sulfides are magmatic in origin, then either the Geordie Lake magma was, unlike the Wolfcamp basalt magma, depleted in Pt, Rh, and Ir, or these elements were selectively removed from the sulfide assemblage. Alternatively, Pd was enriched by late-stage hydrothermal processes. Additional work is recommended to constrain petrogenesis of the sulfides by detailed base-metal and TABS (Te, As, Bi, Sb, and Sn) element analysis.

Geology of the Mesoproterozoic Pillar Lake Volcanics and Inspiration Sill, Armstrong, Ontario: Evidence of Early Midcontinent Rift Magmatism in the Northwestern Nipigon Embayment

The Midcontinent Rift System of North America is a ~1.1 Ga large igneous province comprising mainly flood basalts and intrusive rocks. We present new data for the Pillar Lake Volcanics and Inspiration Sill from the northern edge of the Midcontinent Rift in the northwestern Nipigon Embayment. The Pillar Lake Volcanics comprise a ~20-40 m-thick, flat-lying sequence of mafic pillowed and massive flows, pillowed flow breccia, and hyaloclastite breccia. They are characterized by SiO2 of 52-54 wt%, TiO2 of 1.2 to 1.3 wt% and K2O of 0.9 to 1.1 wt%. They are LREE-enriched, with La/Smn of 3.0 to 4.4 with fractionated HREE (Gd/Ybn = 1.4 to 1.7). The Inspiration diabase sill is < 50 m thick and is in direct contact with the underlying Pillar Lake Volcanics. Baddeleyite and zircon data from the Inspiration Sill yield a combined U-Pb upper intercept age of 1105.6 ± 1.6 Ma. The Inspiration Sill is characterized by uniform SiO2 of 52 to 53 wt%, TiO2 of 1.1 to 1.2 and K2O of 0.9 to 1.2 wt%. Inspiration Sill samples are LREE enriched with La/Smn of 3.2 to 3.3 and fractionated HREE of (Gd/Ybn = 1.6). The Pillar Lake Volcanics are at least 1120 Ma, and perhaps as old as 1130 Ma and represent an early, thin, and restricted mafic volcanic sequence, largely preserved below the younger Inspiration Sill. The Pillar Lake Volcanics and Inspiration Sill display a marked geochemical similarity, suggesting that they may represent magmatism associated with the earliest stages of Midcontinent rifting.

Re-Os geochronology highlights widespread latest Mesoproterozoic (ca. 1090–1050 Ma) cratonic basin development on northern Laurentia

The terminal Mesoproterozoic was a period of widespread tectonic convergence globally, culminating in the amalgamation of the Rodinia supercontinent. However, in Laurentia, long-lived orogenesis on its eastern margin was punctuated by short-lived extension that generated the Midcontinent Rift ca. 1110–1090 Ma. Whereas this cratonic rift basin is typically considered an isolated occurrence, a series of new depositional ages demonstrate that multiple cratonic basins in northern Laurentia originated around this time. We present a Re-Os isochron date of 1087.1 ± 5.9 Ma from organic-rich shales of the Agu Bay Formation of the Fury and Hecla Basin, which is one of four closely spaced cratonic basins spanning from northeastern Canada to northwestern Greenland known as the Bylot basins. This age is identical, within uncertainty, to ages from the Midcontinent Rift and the Amundsen Basin in northwestern Canada. These ages imply that the late Mesoproterozoic extensional episode in Laurentia was widespread and likely linked to a common origin. We propose that significant thermal anomalies and mantle upwelling related to supercontinent assembly centered around the Midcontinent Rift influenced the reactivation of crustal weaknesses in Arctic Laurentia beginning ca. 1090 Ma, triggering the formation of a series of cratonic basins.

Exploring rift magmatism and evolution through gravity analysis of North America's failed rifts

&lt;p&gt;Comparative study of North America&amp;#8217;s failed continental rifts allows investigation of the effects of extension, magmatism, magmatic underplating and rift inversion in the evolution of rifting. We explore this issue by examining the gravity signatures of the Midcontinent Rift (MCR), Reelfoot Rift (RR), and Southern Oklahoman Aulacogen (SOA). The ~1.1 Ga MCR records aspects of the complex assembly of Rodina, while the structures related to the ~560 Ma RR and SOA formed during the later breakup of Rodinia and subsequent assembly of Pangea. Combining average gravity anomalies along each rift with seismic data, we examine whether these data support the existence of high-density residual melt underplates (&amp;#8220;rift pillows&amp;#8221;), reflect the possible amounts of inversion, and whether these rifts should be considered analogs of one another at different stages in rift evolution. The MCR and SOA have strong gravity highs along much of their length. Furthermore, the west and east arms of the MCR have different gravity signatures. The west arm of the MCR has a positive gravity anomaly of 80-100 mgals, while the east arm and SOA have positive anomalies of only 40-50 mgals. The RR does not exhibit a high positive anomaly along much of its length. The positive anomalies of both arms of the MCR and SOA reflect 10-20 km thick underplates at the base of the crust. These gravity anomalies also reflect greater amounts of inversion, during which the rift-bounding normal faults are reactivated by later compression, bringing the high-density igneous rocks closer to the surface. By averaging gravity data along the length of each failed rift, we can more easily distinguish between the history of individual rifts and general features of rifting that apply to other failed or active rifts around the world.&lt;/p&gt;

Posteruptive Thermal History of the Proterozoic Basaltic North Shore Volcanic Group of the Midcontinent Rift: Evidence from K/Ar Data of Celadonite

This study reports three K/Ar ages on celadonite, a dioctahedral K-Fe mica, in the Proterozoic North Shore Volcanic Group (NSVG) of the Midcontinent Rift in northeastern Minnesota. Celadonite formed during beginning posteruptive, low-temperature conditions at temperatures&lt;100°C and with input of meteoric water. K/Ar ages between 1062±16 Ma and 955.0±12 Ma document a remarkably long posteruptive thermal history of &gt;100 myrs in a thick continental basaltic sequence. In the stratigraphically lower part of the NSVG, celadonite formation occurred at 1062±16 Ma in an amygdule or a vesicle filled with celadonite, while another celadonite amygdule in a stratigraphically higher flow was dated at 1039.4±14 Ma. Both flows are overprinted by a later multistage lower zeolite-phyllosilicate facies assemblage (laumontite-albite-corrensite±chlorite±smectite±prehnite±pumpellyite). In the stratigraphically higher part of the sequence, celadonite crystallization at an amygdule rim is followed by upper zeolite facies conditions (stilbite-heulandite-smectite assemblage) and was dated at 955.0±12.4 Ma. The constrained time frame of 107 myrs indicates a long-lived, probably not continuous and locally occurring, posteruptive thermal alteration process. The data suggest that alteration was depth-controlled and temporally and spatially inhomogeneous and implies the progression of the sequence from a close-to-the-surface alteration mode with input of meteoric water to a burial metamorphic mode and with locally occurring hydrothermal activity due to continuous magmatic activity. Volcanism in the Midcontinent Rift system is supposed to have lasted between 1109 Ma and 1083 Ma based on U/Pb zircon ages. The first crystallization of celadonite is recorded in the lower part of the NSVG and occurred ca. 30 myrs after the emplacement of the Silver Bay aplite intrusion in the upper part of the NSVG. Burial rates are determined to be 0.04 km·Ma-1and 0.10 km·Ma-1. The hydrothermal alteration under low-temperature burial conditions clearly postdates the rift-related alkaline and tholeiitic magmatism of the Midcontinent Rift and overlaps with the depositional window of the sedimentary rocks that overlie the Midcontinent Rift volcanics, as well as crustal-scale fault systems that were active during Grenvillian tectonic uplift after the cessation of magmatic activity.

Integrated geophysical analysis provides an alternate interpretation of the northern margin of the North American Midcontinent Rift System, Central Lake Superior

The Midcontinent Rift System (MRS) is a 1.1 Ga sequence of voluminous basaltic eruptions and multiple intrusions followed by widespread sedimentation that extends across the Midcontinent and northern Great Lakes region of North America. Previous workers have commonly used seismic-reflection data (Great Lakes International Multidisciplinary Program on Crustal Evolution [GLIMPCE] line A) to demonstrate that the northern rift margin in central Lake Superior developed as a normal growth fault that was structurally inverted to a reverse fault during a compressional event after rifting had ended. A prominent, curvilinear aeromagnetic anomaly that extends from Isle Royale, Michigan, to Superior Shoal in central Lake Superior, Ontario (the IR-SS anomaly), is commonly presented as a manifestation of this reverse fault. We have integrated multidisciplinary geophysical analyses (seismic-reflection, seismic-refraction, aeromagnetic, and gravity), physical-property information (density, magnetic susceptibility and remanence, and compressional-wave velocity), and geologic concepts to develop an alternate interpretation of the rift margin along GLIMPCE line A, where it intersects the IR-SS anomaly. Our new model indicates that a normal fault is the dominant structure at the northern rift margin along line A, contrary to the original rift-margin paradigm, which asserts that compressional structures are the dominant features preserved today. Integral to this alternate model is a newly interpreted, prerift sedimentary basin intruded by sills in northern Lake Superior. Our alternate model of the northern rift margin has implications for interpreting the style, scale, and timing of extension, rift-related intrusion, and compression during development of the MRS.

Rapid emplacement of massive Duluth Complex intrusions within the North American Midcontinent Rift

The Duluth Complex (Minnesota, USA) is one of the largest mafic intrusive complexes on Earth. It was emplaced as the Midcontinent Rift developed in Laurentia’s interior during an interval of magmatism and extension from ca. 1109 to 1084 Ma. This duration of magmatic activity is more protracted than is typical for large igneous provinces interpreted to have formed from decompression melting of upwelling mantle plumes. While the overall duration was protracted, there were intervals of more voluminous magmatism. New 206Pb/238U zircon dates for the anorthositic and layered series of the Duluth Complex constrain these units to have been emplaced ca. 1096 Ma in &lt;1 m.y. (duration of 500 ± 260 k.y.). Comparison of paleomagnetic data from these units with Laurentia’s apparent polar wander path supports this interpretation. This rapid emplacement bears similarities to the geologically short duration of well-dated large igneous provinces. These data support hypotheses that call upon the co-location of lithospheric extension and anomalously hot upwelling mantle. This rapid magmatic pulse occurred &gt;10 m.y. after initial magmatism following &gt;20° of latitudinal plate motion. A likely scenario is one in which upwelling mantle encountered the base of Laurentian lithosphere and flowed via “upside-down drainage” to locally thinned lithosphere of the Midcontinent Rift.