Novel Structures and Applications of Graphene-Based Semiconductor Photocatalysts: Faceted Particles, Photonic Crystals, Antimicrobial and Magnetic Properties

Graphene, graphene oxide, reduced graphene oxide and their composites with various compounds/materials have high potential for substantial impact as cheap photocatalysts, which is essential to meet the demands of global activity, offering the advantage of utilizing “green” solar energy. Accordingly, graphene-based materials might help to reduce reliance on fossil fuel supplies and facile remediation routes to achieve clean environment and pure water. This review presents recent developments of graphene-based semiconductor photocatalysts, including novel composites with faceted particles, photonic crystals, and nanotubes/nanowires, where the enhancement of activity mechanism is associated with a synergistic effect resulting from the presence of graphene structure. Moreover, antimicrobial potential (highly needed these days), and facile recovery/reuse of photocatalysts by magnetic field have been addresses as very important issue for future commercialization. It is believed that graphene materials should be available soon in the market, especially because of constantly decreasing prices of graphene, vis response, excellent charge transfer ability, and thus high and broad photocatalytic activity against both organic pollutants and microorganisms.

Spectral measurements of surface hoar crystals

ABSTRACTSurface hoar crystals are common on the surface of mountain snow covers. Once buried, layers of large plate-shaped surface hoar crystals are prone to releasing dangerous snow-slab avalanches. Since snow microstructure influences the optical properties of snow, remote sensors could potentially detect the formation of surface hoar and other snow types associated with avalanche release. The spectral reflectance of 377 snow samples was measured with a field spectrometer between 750 and 2500 nm, including 161 samples of surface hoar. Morphological snow shapes associated with critical avalanche layers (surface hoar, near-surface faceted particles and depth hoar) had lower average reflectance factors than non-critical snow shapes at infrared wavelengths. Needle-shaped surface hoar was more reflective than plate-shaped surface hoar, but there were no significant differences between different sizes of surface hoar. Normalized difference indices calculated with reflectance from two wavelength bands is presented as a potential method to classify critical snow surfaces remotely, although melt-freeze crusts near the surface complicated the classification. Accordingly, further studying on the effect of melt-freeze crusts and quantification of the bidirectional reflective properties of critical snow types is needed.

Preparation and Characterization of Si3N4-BN Ceramic Composites by Gelcasting

In this work, a novel method for the preparation of colloids has been studied for the fabrication of silicon nitride –Boron nitride composites. In the present work, the dispersion of mixed silicon nitride –Boron nitride powders in aqueous media was studied with the changes dispersant concentration, solution pH etc. Polyethylenimine (PEI) additive as a dispersant were used for Si3N4 and BN powders in aqueous media. Well-dispersed Si3N4 and BN powders in aqueous media were attained atthe 1 wt% PEI and pH 9. 40 vol% covered Si3N4/BN slurries with varying BN content was adapted for gel casting. The gel casted material waspreheated at normal room temperature, debindered at 6000C and sintered at 17000C. The sintered composite material composed mainly of alpha-Si3N4, beta-Si3N4, and h-BN. The prepared composite material shows uniform microstructure with faceted particles, α-Si3N4 and abundant pores.

Nanopatterning Gold by Templated Solid State Dewetting on the Silica Warp and Weft of Diatoms

The diatom,Nitzschia palea, exhibits complex silica shell (frustule) topography that resembles the warp and weft pattern of woven glass. The surface is perforated with a rhombic lattice of roughly oblong pores between periodically undulating transverse weft costae. Exfoliated frustules can be used to template gold nanoparticles by thermally induced dewetting of thin gold films. Acting as templates for the process, the frustules give rise to two coexisting hierarchies of particle sizes and patterned distributions of nanoparticles. By examining temperature dependent dewetting of 5, 10, and 15 nm Au films for various annealing times, we establish conditions for particle formation and patterning. The 5 nm film gives distributions of small particles randomly distributed over the surface and multiple particles at the rhombic lattice points in the pores. Thicker films yield larger faceted particles on the surface and particles that exhibit shapes that are roughly conformal with the shape of the pore container. The pores and costae are sources of curvature instabilities in the film that lead to mass transport of gold and selective accumulation in the weft valleys and pores. We suggest that, with respect to dewetting, the frustule comprises 2-dimensional sublattices of trapping sites. The pattern of dewetting is radically altered by interposing a self-assembled molecular adhesive of mercaptopropyltrimethoxysilane between the Au film overlayer and the frustule. By adjusting the interfacial energy in this manner, a fractal-like overlay of Au islands coexists with a periodic distribution of nanoparticles in the pores.