Importance of Infiltration Rates for Fate and Transport of Benzene in High-Tiered Risk-Based Assessment Considering Korean Site-Specific Factors at Contaminated Sites

Widely used conservative approaches for risk-based assessments of the subsurface transport processes have been calculated using simple analytical equations or general default values. Higher-tier risk assessment of contaminated sites requires the numerical models or additional site-specific values for input parameters. Previous studies have focused on the development of sophisticated models fit into risk-based frameworks. Our study mainly aims to explore the applicability of site-specific parameters and to modify the risk-based fate and transport model according to the types of the site-specific parameters. To apply the modified fate and transport equation and the site-specific default infiltration range, this study assessed the source depletion, leachate concentrations, and exposure concentration of benzene, which is a representative organic contaminant. The numerical models consist of two continuous processes, the fate and transport of contaminants from (1) the soil to the groundwater table in the vadose zone and subsequently (2) from the groundwater table to exposure wells in the saturated zone. Spatially varied Korean domestic recharge data were successfully incorporated into site-specific infiltration parameters in the models. The numerical simulation results were expressed as transient time series of concentrations over time. Results presented the narrow range of predicted concentrations at the groundwater table when site-specific infiltration was applied, and the dilution–attenuation factors for the unsaturated zone (DAFunsat) were derived based on the prediction. When a contaminant travels to the longest path length of 10 m with a source depth of 1 m in the vadoze zone, the simulated DAFunsat ranged from 3 to 4. The highest DAFunsat simulation results are close to 1 when contaminants travel to a source depth of 5 m and the shortest path length of 1 m. In the saturated aquifer below the contaminated sites, the variation in exposure concentration with time at monitoring wells is detected differently depending on the depth of the saturated zone.

Macroseismic intensity attenuation equations for Central Asia earthquakes

Based on macroseismic survey data for strong earthquakes in Central Asia, the coefficients of attenuation of seismic intensities with distance in the Blake-Shebalin- and Kovesligethy -type equations were refined. A new generalized dependence of macroseismic intensity attenuation on distance, taking into account the depth of the earthquake hypocentre, were obtained. Relations between the minor and major axes of the ellipse approximating real isoseists depending on the shaking strength, source depth and earthquake magnitude were found. With the example of the territory of eastern Uzbekistan, the influence of the choice of the law of seismic intensity attenuation with distance on the obtained seismic hazard assessments is investigated.

Observations of PKKPab Diffraction Waves Well Beyond Cutoff Distance

The core mantle boundary (CMB) features the most dramatic contrast in the physical properties within the Earth and plays a fundamental role in the understanding of the dynamic evolution of the Earth’s interior. Seismic core phases such as PKKP sample large area of the lowermost mantle and the uppermost core, thus providing valuable information of the velocity structures on both sides of the CMB. Diffraction Waves Well Beyond Cutoff Distance (PKKPab) is one branch of the triplicated PKKP that can be observed beyond its ray theoretical cutoff distance as a result of diffraction along the CMB. The travel time and slowness of the diffracted PKKPab (denoted as PKKPabdiff) can be used to constrain the P-wave velocities at the lowermost mantle, thus have been investigated in numerous studies. Previous results (Rost and Garnero, 2006) suggest that most of the observations of the PKKPabdiff waves are in the epicentral distance range of 95°–105° (minor arc convention) (PKKPabdiff diffraction length less than 10°). However, high-frequency (∼1 Hz) synthetic seismograms show that the PKKPabdiff waveforms could be observable at distance down to 65°, which indicates that the PKKPabdiff signals could be detected at distances less than 95° in observations. To explore the distance ranges in which PKKPabdiff is observable, we collected global three-component broadband waveforms from 246 events with source depth deeper than 100 km and magnitude above M 6 from 2007 to 2017 available at the Incorporated Research Institutions for Seismology Data Management Center. We analyzed the slowness, polarization, and amplitude of the candidate PKKPabdiff signals, and found 95 events with clear PKKPabdiffsignals, with nearly 60% of the events show PKKPabdiff diffraction lengths greater than 10°, and the longest diffraction distance is beyond 20°. These newly identified PKKPabdiff waves would substantially augment the dataset of core phases for improvements of the CMB velocity models.

Continental-scale analysis of shallow and deep groundwater contributions to streams

Groundwater discharge generates streamflow and influences stream thermal regimes. However, the water quality and thermal buffering capacity of groundwater depends on the aquifer source-depth. Here, we pair multi-year air and stream temperature signals to categorize 1729 sites across the continental United States as having major dam influence, shallow or deep groundwater signatures, or lack of pronounced groundwater (atmospheric) signatures. Approximately 40% of non-dam stream sites have substantial groundwater contributions as indicated by characteristic paired air and stream temperature signal metrics. Streams with shallow groundwater signatures account for half of all groundwater signature sites and show reduced baseflow and a higher proportion of warming trends compared to sites with deep groundwater signatures. These findings align with theory that shallow groundwater is more vulnerable to temperature increase and depletion. Streams with atmospheric signatures tend to drain watersheds with low slope and greater human disturbance, indicating reduced stream-groundwater connectivity in populated valley settings.

Prediction of Size and Shape of Wetting Patterns Created by Inverted Open Plastic Bottles (IOPB)

<p>Plastic bottles can be used in irrigation fields which introduces a sustainable low-cost alternative for irrigation methods. Until now, plastic bottles were used in small irrigation fields since there are limited scientific measurements of it is performance. The aim of this study is to predict the size and shape of the wetting patterns generated by inverted opened plastic bottles. Hydraulic simulations for 48 design cases of 12 different soil types and 4 sizes of subsurface source were accomplished using 2D-Hydrus. The simulation outputs were validated using experimental results. Multi regression analysis was used to identify the general formulae of the dependent variables of hydraulic conductivity, area of subsurface source, depth of the source, head of application, and time of application. The statistical analysis was formulated by the R-studio program. Results show that the maximum width and depth of wetting patterns occurred in sandy soil which were 34.1 and 96.8 cm, respectively. The minimum values were in silty clay with the width and depth of wetting patterns of 4.3 and 19 cm, respectively. The standard deviation of the width and depth were 9.02 and 22.58, respectively.  In conclusion, the soil type is a vital factor that impacts the flow in the soil profile and the size and shape of the wetting patterns. In addition, the size and depth of the subsurface source impact the size and location of the wetting patterns. The Head of the water in IOPB can be used to specify the size of the wetting patterns. The statistical model can be used to predict the size of the wetting patterns created by IOPBs accurately.</p>