Post-Ore Processes of Uranium Migration in the Sandstone-Hosted Type Deposits: 234U/238U, 238U/235U and U–Pb Systematics of Ores of the Namaru Deposit, Vitim District, Northern Transbaikalia

To assess the nature of the post-ore behaviour of uranium in the Namaru deposit (Khiagda ore field), U–Pb isotope systems and the isotopic composition of uranium (234U/238U and 238U/235U) were studied. The studied samples represent different ore zones of the deposit and were collected along cross-sections both vertically and horizontally. Wide variations in the isotopic composition of uranium and U–Pb isotopic age have been established. Deviations of the 234U/238U ratio from equilibrium values, which for some samples exceed 50%, along with significant variations in the isotopic age, indicate that permafrost layer, which covered the catchment areas of paleovalleys with meteoric oxygen-containing waters ca. 2.5 Ma ago, did not lead to preserving uranium ores at the deposit. Uranium migration took place during the Quaternary period. The effective combining the U–Pb dating and 234U/238U data in assessing the post-ore redistribution of uranium made it possible to recognize: removal of uranium from some zones of the ore body and its accompanying redeposition in others. Wide variations in the 238U/235U (137.484–137.851) ratios throughout the entire studied cross-sections can be explained by the different locations of samples relatively to the ore deposition front and change in redox conditions as this front advanced. Depletion of the light isotope 235U in the lower zone of the ore body may be associated with the influence of ascending carbonic waters established in the regional basement. The effect of such waters on uranium-bearing rocks causes predominant leaching of light 235U.

Isotopic age and paleogeodynamic position of ultrapotassic magmatism of Central Chukotka

The 40Ar/39Ar dating of ultrapotassic rocks from Central Chukotka shows that these rocks are Early Cretaceous, and yields a narrow range of age variations (109 to 107 Ma), which correlates fairly well with the range of age variations of granitoids typical of the study area (117–105 Ma). There are thus grounds to suggest that the ultrapotassic magmas and granitoids resulted from the same geological process that can be identified from the material characteristics of the ultrapotassic magmas.In the modern concepts of the regional geological development, the formation of the granitoid and ultrapotassic magmas can be related to the continental lithosphere extension due to the collision of Eurasian plate and the Chukotka – Arctic Alaska continental block.Using modern genetic models based on the interpretations of the material characteristics of ultrapotassic magmas, it is possible to limit the number of genetic hypotheses and to relate the continental lithosphere extension to the processes that took place in the upper mantle of the study area.

Geological features and the first isotopic data of volcanic rocks in the Iset river basin, East-Urals megazone

Relevance of the work. The Iset river basin contains the most extensive outcrops of volcanogenic formations of the Beklenishchevsky complex of the East Ural megazone, the age of which is determined as Early Carboniferous by the ratio of volcanic rocks with faunistically characterized sedimentary deposits. Volcanics here compose flows of andesite-basaltic and andesitic lavas and lava breccias. There are no geochronological dates specifying the age of the rocks, which makes it difficult to assess their role in the formation of the megazone. Therefore, isotopic dating of these formations is very important. Methods. The U – Pb age and data on the geochemistry of zircons were obtained by laser ablation (LA – ICP – MS). Purpose of the research is to study the features of the geological structure, the material composition of volcanic rocks in the Iset river basin, the geochemistry of zircons from andesites and the determination of their isotopic age. Results of the work and the scope of their application. Lava flows of andesites and basaltic andesites with minor amounts of basalts and dacites have tectonic contact with sedimentary rocks of the Early Carboniferous age. The distribution of rare elements in volcanics is typical of supra-subduction formations. Zircons in andesites are represented by prismatic and isometric crystals. Prismatic differences in the nature of the distribution of REE and the content of Li, Ti, Sr, Th, U refer to zircons of magmatic genesis, isometric – to “hydrothermal”. According to the U / Yb – Y ratios, the former correspond to the zircons of the ocean floor, while the latter are related to the continental ones. Isotopic dating of zircons from andesites was carried out for the first time. Their age was 311 million years. The data can be used in geological mapping, as well as in the compilation of large-scale geodynamic maps and diagrams. Conclusions. Volcanic rocks in the Iset river basin were formed in supra-subduction continental-marginal geodynamic conditions that took place in the Urals in the Carboniferous. The obtained value of the age of zircons from andesites, possibly, fixes the stage of their transformation. Keywords: East-Ural megazone, volcanic rocks, zircon, isotopic age.

Benchmarking source specific isotopic ratios of levoglucosan to better constrain the contribution of domestic heating to the air pollution

<p>Due to the potential to fingerprint emissions, carbon stable isotopes are considered a powerful tool to get insight into sources of air pollutants and to study their atmospheric life cycle. Including the independent isotopic knowledge into chemical models, not only concentration but also isotope ratios can be predicted. This provides the possibility to differentiate the impact of source strength from that of chemical reactions in the atmosphere. In a recent study comparing Lagrangian-particle-dispersion-simulations with ambient observations, Betancourt et al. [1] (ACPD2020) found that the observed isotopic age of levoglucosan, a biomass burning tracer, agrees well with the isotopic age derived from back-plumes analyses. This showed that the wintertime aerosol burden from domestic heating observed in residential areas of North-Rheine-Westphalia, Germany, is of local or regional origin. Error analyses though indicated that the largest source of uncertainty was the limited information on emission isotope ratios.</p><p>In this work, the stable isotope ratios of levoglucosan in aerosol particles emitted from the combustion of 18 different biomass fuels typically used for domestic heating in Western and Eastern Europe (soft and hard woods, brown coals and corn cobs, respectively) were measured by Thermal Desorption- Two-Dimensional Gas Chromatographie- Isotope Ratio Mass Spectrometry (TD-2DGC-IRMS). Additionally to the compound specific measurements, isotopic ratios of total carbon in the fuel parent material, in the precursor cellulose, as well as in sampled aerosol particles were determined.</p><p>Levoglucosan δ<sup>13</sup>C was found to vary between -23.6 and -21.7‰ for the C3 plant samples, showing good agreement with Sang et al [2] (EST2012). The brown coal and the C4 plant samples were isotopically heavier, showing isotopic ratios in the range of -21,1 to -18.6‰ and -12.9‰, respectively. In this presentation, the observed levoglucosan δ<sup>13</sup>C will be discussed with respect to the carbon isotopic composition of the parent materials. The potential of using compound specific δ<sup>13</sup>C measurements of levoglucosan for improved source apportionment will be addressed.</p><p>References:</p>

Age of the lower Cambrian Vanadium deposit, East Guizhou, South China: Evidences from age of tuff and carbon isotope analysis along the Bagong section

The early Cambrian is a critical interval of dramatic oceanic and biochemical changes in geological history. The black shale deposits, which are rich in Mo, Ni, V, and platinum group elements (PGE), are a reflection of that interval. Among all known Cambrian black shale deposits in South China, the vanadium deposits are poorly constrained by geochronology. The newly discovered tuff layer in the Sansui Bagong vanadium deposit in Guizhou Province can provide excellent constraints on the age of vanadium deposits. In this study, we obtain a new zircon U–Pb isotopic age, which can constrain the age of the vanadium deposit. This tuff occurs in the middle part of the ore bed, and the age of the tuff layer can reflect the mineralization age of the V deposit. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) is used in this study to obtain the zircon U–Pb age of the tuff and indicates that the event of volcanic activity took place at 520.9 ± 1 Ma. This age is close to the boundary between the Cambrian Terreneuvian and Series 2. This result provides a good constraint on the age of the vanadium deposits in South China and makes the vanadium deposits to be comparable with other Mo–Ni–PGE deposits. The alteration of organic carbon isotope (δ 13Corg) values can reflect changes in the marine environment and is widely used in stratigraphic correlation. The analysis of the δ 13Corg values of the ore bed in the present study reveals a positive excursion at the bottom of the deposit and a negative excursion in the V-enriched layer. The δ 13Corg values in the Bagong section are comparable to those in the Xiaotan and Longbizui sections. The ages of the Sansui vanadium deposit constrained by the U–Pb isotopic age of the tuff and the δ 13Corg values are consistent. All of the data lead us to infer that the vanadium deposit formed at approximately 521 Ma.

Genesis of Early Precambrian crystalline complexes

The obtained evidence of hot heterogeneous accretion of the Earth leads to a fundamentally new solution of the problem of the genesis of Early Precambrian crystal complexes. According to this approach, a powerful impact heat release during accretion resulted in the formation of a layered global magmatic ocean. Its upper acidic layer arose from low-pressure residual melts of the bottom parts of the still shallow early ocean, fractionated under the influence of an increase in the load pressure of the forming upper layers. The solidification of the uppermost parts of the acidic layer led to the formation of the most ancient tonalite-trondyemite complexes. Gneiss-crystalshale complexes were formed from its deeper parts by lowering the crystallized near-surface areas together with sediments accumulated on them and lifting the underlying magmas of often more mafic composition in their place. Leaching of the near-surface parts of the solidified rocks under the influence of acidic emanations of the magmatic ocean caused the predominance of quartzites and high-alumina gneisses among the oldest pararocks. Due to the solidification of the magmatic ocean from top to bottom, the isotopic age of gneiss decreases on average with depth. The surfacing of residual melts of its various layers led to the evolution of magmatism of ancient platforms from acidic to alkaline-ultrabasic and kimberlite. The separation of ore-bearing emanations of the magmatic ocean caused the formation of numerous often unique deposits.

Uranium-Lead by Monacite Geochronology of Granites Distributed in the Middle Current of ihe River Ros (Ros-Tikich Megablock Ukrainian Shield)

Granitoids play a leading role in the geological structure of the Ros-Tikich megablock. The rocks of the Ros-Tikich series, which form the supercrystalline base here, have survived among the granitoids only in the form of some remnants of different sizes. In the coastal outcrops of the middle course of the river Ros (east of Bila Tserkva) and in the quarries located near the river, the most common are two-feldspar granitoids, isolated as part of two complexes – Uman and Stavyshche. Plagiogranitoids and supercrustal rocks have survived among them in the form of separate fragments. Of the accessory uranium-containing minerals, zircon and titanite are present in two-field spar granites, and monazite was found in single samples of granites in which titanite was absent. The age of obscure porphyry-like granite discovered by the Ostrivsk quarry – 2063.5 ± 1.2 million years and uniformgrained granite, distributed in the quarry of the village of Bovkun – 2042.5 ± 8.6 million years. The obtained values of the isotopic age of these granites are in good agreement with the results of uranium-lead isotopic dating of zircons from twofeldspar granites of the Ros-Tikich megablock (1990-2080 million years). This allows us to propose to combine the granites of the Stavyshche and Uman complexes into one Paleoproterozoic complex.