chloride flux
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2021 ◽  
Author(s):  
◽  
Ian Alistair Nairn

<p>Okataina Volcanic Centre is the most recently active of the four major rhyolite eruptive centres in the Taupo Volcanic Zone of New Zealand. Within the Centre lies Haroharo Caldera, a complex of overlapping collapse structures resulting from successive voluminous pyroclastic eruptions from the same general source area. At least four main and possibly two minor caldera-forming eruptions have occurred during the last 250,000 years, although poor exposure means that attempts to interpret the early structural history are highly speculative. Although there is no compelling evidence of structural updoming within Haroharo Caldera, magma resurgence has followed the last major caldera-forming eruption of the Rotoiti Breccia at [greater than or equal to] 42,000 years B.P. Eruption of this magma within the caldera has formed the two large rhyolite lava and pyroclastic piles of the Haroharo Volcanic Complex and Tarawera Volcanic Complex, plus two subsidiary adjacent complexes at Okareka and Rotoma. All these intracaldera eruptives are younger than 20,000 years B.P., with the most recent eruptions from Tarawera; of rhyolite at c. 700 years B.P., and of basalt in 1886 A.D. A considerable amount of earlier work carried out at Okataina was directed mainly at petrology and chemistry of the rhyolites forming the Tarawera and Haroharo Volcanic Complexes. The present study has arisen from a 1:50,000 mapping programme at Okataina and has sought to examine structures and volcanic history in greater detail, and to consider the resulting geological implications for geothermal resources. Caldera boundaries have been mapped, and two major vent lineations are defined, apparently related to fundamental basement fractures which have controlled location of the Tarawera and Haroharo Volcanic Complexes. An intracaldera ring fault is also suggested by the sub-circular arrangement of some young volcanic vents. The Haroharo and Tarawera Complexes are mapped, with locations of source vents, and dating of the major lavas and pyroclastic deposits. All the post-20,000 year eruptives are placed in four main emptive episodes at Haroharo, and five at Tarawera. The near-source pyroclastic surge and flow deposits are 14C dated, and with their associated widespread plinian fall deposits they provide time planes for dating the associated lavas. The emptive episodes generally appear to have been of much shorter duration than the intervening quiescent periods which lasted for thousands of years. All the eruptive episodes at Haroharo involved multiple eruptions from vents spread out over several kilometres along the vent lineations. Similar multiple vent eruptions can be demonstrated for some of the Tarawera eruptive episodes. More than 500 km3 of magma has been erupted from Haroharo Caldera during the last 250,000 years, 80 km3 of which was erupted in the Last 20,000 years. This history suggests that a large magmatic heat source should continue to underlie the Okataina Volcanic Centre. However, very little surface hydrothermal activity occurs within Haroharo Caldera. It is suggested that the large external hydrothermal fields at Tikitere, Waimangu-Waiotapu-Waikite, and possibly Kawerau, are related to Haroharo Caldera heat sources. Presently available data are summarized for hydrothermal fields in and adjacent to Haroharo Caldera, and new analyses are presented for some warm springs discovered within the caldera. Estimates and measurements of chloride fluxes in lakes and rivers are reported. The chloride flux values suggest the occurrence of larger hydrothermal heat flows into lakes and rivers than are apparent at the surface. Measurements of chloride flux in the Tarawera River showed that 280 g s-1 of chloride is added to the river within Haroharo Caldera below the Lake Tarawera outlet. Only 80 g s-1 of this chloride comes from known geothermal sources. A total chloride flux of 760 g s-1 in the Tarawera River passing out of the Okataina Volcanic Centre indicates a minimum geothermal heat flow of 600 MW. Estimates of heat flows in other drainage paths from Haroharo Caldera suggest that minimum total heat flow from the caldera may exceed 1500 MW. A large heat flow from the caldera would appear consistent with the volcanic history. Some suggestions are made for further investigation of the geothermal resources</p>


2021 ◽  
Author(s):  
◽  
Ian Alistair Nairn

<p>Okataina Volcanic Centre is the most recently active of the four major rhyolite eruptive centres in the Taupo Volcanic Zone of New Zealand. Within the Centre lies Haroharo Caldera, a complex of overlapping collapse structures resulting from successive voluminous pyroclastic eruptions from the same general source area. At least four main and possibly two minor caldera-forming eruptions have occurred during the last 250,000 years, although poor exposure means that attempts to interpret the early structural history are highly speculative. Although there is no compelling evidence of structural updoming within Haroharo Caldera, magma resurgence has followed the last major caldera-forming eruption of the Rotoiti Breccia at [greater than or equal to] 42,000 years B.P. Eruption of this magma within the caldera has formed the two large rhyolite lava and pyroclastic piles of the Haroharo Volcanic Complex and Tarawera Volcanic Complex, plus two subsidiary adjacent complexes at Okareka and Rotoma. All these intracaldera eruptives are younger than 20,000 years B.P., with the most recent eruptions from Tarawera; of rhyolite at c. 700 years B.P., and of basalt in 1886 A.D. A considerable amount of earlier work carried out at Okataina was directed mainly at petrology and chemistry of the rhyolites forming the Tarawera and Haroharo Volcanic Complexes. The present study has arisen from a 1:50,000 mapping programme at Okataina and has sought to examine structures and volcanic history in greater detail, and to consider the resulting geological implications for geothermal resources. Caldera boundaries have been mapped, and two major vent lineations are defined, apparently related to fundamental basement fractures which have controlled location of the Tarawera and Haroharo Volcanic Complexes. An intracaldera ring fault is also suggested by the sub-circular arrangement of some young volcanic vents. The Haroharo and Tarawera Complexes are mapped, with locations of source vents, and dating of the major lavas and pyroclastic deposits. All the post-20,000 year eruptives are placed in four main emptive episodes at Haroharo, and five at Tarawera. The near-source pyroclastic surge and flow deposits are 14C dated, and with their associated widespread plinian fall deposits they provide time planes for dating the associated lavas. The emptive episodes generally appear to have been of much shorter duration than the intervening quiescent periods which lasted for thousands of years. All the eruptive episodes at Haroharo involved multiple eruptions from vents spread out over several kilometres along the vent lineations. Similar multiple vent eruptions can be demonstrated for some of the Tarawera eruptive episodes. More than 500 km3 of magma has been erupted from Haroharo Caldera during the last 250,000 years, 80 km3 of which was erupted in the Last 20,000 years. This history suggests that a large magmatic heat source should continue to underlie the Okataina Volcanic Centre. However, very little surface hydrothermal activity occurs within Haroharo Caldera. It is suggested that the large external hydrothermal fields at Tikitere, Waimangu-Waiotapu-Waikite, and possibly Kawerau, are related to Haroharo Caldera heat sources. Presently available data are summarized for hydrothermal fields in and adjacent to Haroharo Caldera, and new analyses are presented for some warm springs discovered within the caldera. Estimates and measurements of chloride fluxes in lakes and rivers are reported. The chloride flux values suggest the occurrence of larger hydrothermal heat flows into lakes and rivers than are apparent at the surface. Measurements of chloride flux in the Tarawera River showed that 280 g s-1 of chloride is added to the river within Haroharo Caldera below the Lake Tarawera outlet. Only 80 g s-1 of this chloride comes from known geothermal sources. A total chloride flux of 760 g s-1 in the Tarawera River passing out of the Okataina Volcanic Centre indicates a minimum geothermal heat flow of 600 MW. Estimates of heat flows in other drainage paths from Haroharo Caldera suggest that minimum total heat flow from the caldera may exceed 1500 MW. A large heat flow from the caldera would appear consistent with the volcanic history. Some suggestions are made for further investigation of the geothermal resources</p>


Terra Nova ◽  
2019 ◽  
Vol 31 (6) ◽  
pp. 511-517 ◽  
Author(s):  
Vadim S. Kamenetsky ◽  
Alexander Belousov ◽  
Victor V. Sharygin ◽  
Liudmila M. Zhitova ◽  
Kathy Ehrig ◽  
...  

2019 ◽  
Vol 29 (12) ◽  
pp. 5072-5084 ◽  
Author(s):  
F T Djankpa ◽  
F Lischka ◽  
M Chatterjee ◽  
S L Juliano

Abstract KCC2 is a brain specific chloride–potassium cotransporter affecting neuronal development including migration and cellular maturation. It modulates chloride homeostasis influencing the switch of GABA from depolarizing to hyperpolarizing, which contributes to the cues that influence the termination of neuronal migration. The expression of KCC2 during migration of interneurons, therefore, correlates with the ability of these cells to respond to GABA as a stop signal. Manipulation of KCC2 in development can affect various aspects of migrating neurons, including the speed. We describe the effect of KCC2 downregulation and inhibition on features of migrating interneurons of normal ferret kits and those treated with methylazoxymethanol acetate, which increases KCC2. Treatment of organotypic cultures with Bisphenol A, an environmental toxin that alters gene expression, also downregulates KCC2 protein. In organotypic slices treated with the KCC2 antagonist VU0240551, chloride imaging shows inhibition of KCC2 via blockade of chloride flux. Time-lapse video imaging of organotypic cultures treated with either drug, shows a significant increase in the average speed, step size, and number of turns made by migrating neurons leaving the ganglionic eminence. Our findings demonstrate the harmful effect of environmental toxins on brain development and potential consequences in the pathogenesis of neurodevelopmental disorders.


2019 ◽  
Vol 1 (5) ◽  
pp. 1726-1730
Author(s):  
Minoru Sohmiya ◽  
Shinya Umehara ◽  
Shinpei Enomoto ◽  
Yusuke Ide ◽  
Tomohiko Okada ◽  
...  

“Chloride flux growth in the rigid nanospace of mesoporous silica” was employed to produce lithium niobium oxide anisotropic nanoparticles.


2018 ◽  
Vol 2 (1) ◽  
pp. 913-922 ◽  
Author(s):  
Kenta Kawashima ◽  
Yang Liu ◽  
Jun-Hyuk Kim ◽  
Bryan R. Wygant ◽  
Isabelle Cheng ◽  
...  
Keyword(s):  

2018 ◽  
Vol 18 (9) ◽  
pp. 5301-5310 ◽  
Author(s):  
Kenta Kawashima ◽  
Jun-Hyuk Kim ◽  
Isabelle Cheng ◽  
Kunio Yubuta ◽  
Kihyun Shin ◽  
...  
Keyword(s):  

2017 ◽  
Vol 43 (10) ◽  
pp. 7695-7700 ◽  
Author(s):  
Yue Li ◽  
Feng-Qiang Xiong ◽  
Ruiling Ou ◽  
Lipeng Wan ◽  
Congling Yin ◽  
...  
Keyword(s):  

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