Experimental analysis of the impact protection properties for Kevlar® fabrics under different orientation layers and non-Newtonian fluid compositions

Use of colloidal silica suspensions impregnated in Kevlar® fabrics is new avant-garde of protection equipment for stab wounds and piercing objects. Kevlar® fabrics impregnated with non-Newtonian fluids have been used for protection against sharp blows, mainly due to their lightweight, good flexibility, and superior resistance properties. The aims of this investigation are to demonstrate that Kevlar® fabric impregnated with shear thickening fluids could be improved its performance through the use Aminopropyltrimethoxysilane, as well as by increasing the concentration of silica nanoparticles in its composition. Friction tests on yarns showed that Kevlar® yarns with shear thickening fluids (sample C3—25% Silica and 75%polyethylene glycol with 38% aminopropyltrimethoxysilane), presented higher strength values (10.5 N) when compared with other samples. Impact resistance tests showed that Kevlar® samples with highest concentration shear thickening fluids nanoparticles and oriented fabric layers (C3 OR) presented better performance regarding to penetration depth of stabs P1 (17 mm), S1 (18 mm) and as well as residual energy dissipation, when compared with the standard and other samples. Addition of shear thickening fluids cause reduction in the flexibility of the Kevlar® fabrics, producing sample with 42.74% less flexibility than the standard sample (C3). Adhesion tests for C3 samples exhibited more stable wettability and spreading rate, i.e., a greater adhesion of shear thickening fluids in Kevlar® fabrics than other samples due to its composition (higher concentration of nanoparticles and superior amount of silane agent). Finally, results showed that the shear thickening fluids composition as well as Kevlar® layers orientation should be used to improve the performance of Kevlar® fabrics under impact tests.

Density waves in shear-thickening suspensions

Shear thickening corresponds to an increase of the viscosity as a function of the shear rate. It is observed in many concentrated suspensions in nature and industry: water or oil saturated sediments, crystal-bearing magma, fresh concrete, silica suspensions, and cornstarch mixtures. Here, we reveal how shear-thickening suspensions flow, shedding light onto as yet non-understood complex dynamics reported in the literature. When shear thickening is important, we show the existence of density fluctuations that appear as periodic waves moving in the direction of flow and breaking azimuthal symmetry. They come with strong normal stress fluctuations of the same periodicity. The flow includes small areas of normal stresses of the order of tens of kilopascals and areas of normal stresses of the order of hundreds of pascals. These stress inhomogeneities could play an important role in the damage caused by thickening fluids in the industry.

Rotational Rheometry of a Fumed Silica Lubricating Grease

The rheological properties of lubricating greases are the governing properties for performance assessment in lubrication applications. These properties can be determined under both controlled stress and strain rheometry. Moreover, studying the effect of temperature on these properties is of great importance. This study investigates the differences between rheological characterizations performed under both controlled stress and strain modes on fumed silica greases. The results of steady-state viscometry under controlled strain mode revealed a non-monotonic temperature-dependent behavior. This non-monotonic behavior, attributed to the shear banding, was also observed in up and down stress ramp data. The results of the controlled stress and controlled strain rheometry modes coincided well at high values of stress and shear rates due to the reduced effect of stick-slip phenomenon and elastic deformation. A two-step yielding flow curve observed in the steady flow curves was justified by bond and cage breakage mechanisms in fumed silica suspensions.

Microfiltration of Submicron-Sized and Nano-Sized Suspensions for Particle Size Determination by Dynamic Light Scattering

Dynamic light scattering (DLS) is commonly used for the determination of average particle diameters and suspension stability and popular in academics and industry. However, DLS is not considered suitable for polydisperse samples. The presence of little quantities of micrometre particles in nano and submicrometre suspensions especially affect the reliability of DLS results. Microfiltration might be a suitable method for the removal of unwanted large particles. This study investigates the effect of microfiltration on the diameter distributions as measured by DLS. Polystyrene standards (40–900 nm diameter), and monomodal silica suspensions were filtered with polytetrafluoroethylene (PTFE) membranes (0.1–1.0 µm pore size) to investigate retention properties and grade efficiency. Non-ideal materials were used to prove the results. Experiments showed that a mono-exponential decay can be achieved by filtration. A size safety factor of at least three between labeled pore size and average diameter was found to keep separation as low as possible. Filtration in order to enhance DLS for particulate submicrometre materials was considered suitable for narrowly distributed coated titania and kaolin powder. In a regulatory context, this might have an impact on considering a substance false positive or false negative according to the European Commission (EC) recommendation of a definition of the term nanomaterial.