Novel U-Pb isotopic zircon data on the rhyolite of the Saf’yanovskoe Cu-Zn deposit (Middle Urals)

Research subject. Zircons from the Saf’yanovskoe Cu-Zn deposit rhyolite (Middle Urals). For the first time, zircon U-Pb dating for the rhyolite of the ore-bearing volcanic-sedimentary rocks of the Saf’yanovskoe deposit was performed. The volcanites are characterized by an andesite-rhyodacite composition and are localized at the southern edge of the Rezhevskaya structural-formation zone (SFZ) of the Eastern Ural megazone. A number of publications assign these rocks either to the basalt-rhyolite formation of the Middle Devonian, or to the basalt-andesite-dacite-rhyolite formation of the Lower-Middle Devonian.Aim. To estimate the age of the ore-bearing volcanic rocks under study using the U-Pb SHRIMP-II isotop ic system of zircon from the rhyolite of the eastern side of the Saf’yanovskoe deposit. By its chemical composition, the rhyolite belongs to the silicic varieties of subvolcanic rocks. Methods and results. The U-Pb isotopic system of zircon was studied by 5-collector mass-spectrometer of high precision and emission of the secondary ions SHRIMP-II (ASI, Australia) in the VSЕGEI Institute. U-Pb relations were investigated by a procedure developed by I.S. Williams. The U-Pb data obtained based on 13 zircon grains showed the age of 422.8 ± 3.7 Ma. Conclusions. The U-Pb dating of zircon obtained previously from the lens-shaped andesite bodies of the western side of the Safyanovskoe deposit gave the age of 422.8 Ma, which corresponds to the Przydoli series epoch of the Upper Silurian. We established that, among the volcanic rocks of the Saf’yanovskoe deposit, the effusive formations of the Upper Silurian are present.

Petrogenesis and tectonic setting of Late Devonian high-Mg andesites in the Beishan orogen, NW China

High-Mg andesites (HMAs) are crucial for the reconstruction of plate tectonics, continental margin formation and lithospheric evolution. In this study, we present new fossil age, whole-rock geochemical and Sr–Nd isotope data on the newly discovered Dundunshan Group HMAs in the Dundunshan area of the Beishan orogen (central-southern Central Asian Orogenic Belt). The Dundunshan HMA samples are characterized by high MgO (6.47–7.02 wt%) contents and high Mg# values (67.27–68.77), with SiO2 (58.57–62.13 wt%), Al2O3 (14.49–16.07 wt%) and CaO (5.05–6.24 wt%) resembling typical HMAs. The Dundunshan HMA samples are calc-alkaline and strongly enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs), with slightly negative Eu anomaly and high-field-strength element (HFSE) depletions. Their (87Sr/86Sr)i ratios (0.7041–0.7057) and ϵNd(t) (3.73–5.59) indicate that the Dundunshan HMAs were mainly formed by the interactions between subducted oceanic sediment-derived melts and mantle peridotites. Fossil evidence and published radiometric age data constrain the formation of the Dundunshan HMAs to early Late Devonian time. Sedimentological features of the Middle Devonian Sangejing Formation and regional tectonic correlation suggest that the Hongliuhe–Niujuanzi–Xichangjing Ocean in the Dundunshan area was likely closed during late Middle Devonian time, and that the Dundunshan HMAs were formed in a post-collision extensional setting.

Morphology and Nomenclature of Barsassia (Lycopsida) from the Middle Devonian of West Junggar, Xinjiang, China

Morphology and nomenclature are essential issues of botany, in which both extant and fossil plant taxa follow the same nomenclature code. Devonian (419.2–358.9 Ma) herbaceous lycopsid Barsassia, one of the earliest coal-forming plants in geological history, possesses a characteristic, easily recognized, step-like stem and has been thought to be an index fossil for dating and correlating the Middle Devonian strata, especially those in the paleoblocks of Siberia, Kazakhstan, Xinjiang, and North China. Here, we systematically study the Devonian lycopsid Barsassia in terms of its morphology and nomenclature, based on the new materials from the Middle Devonian Hujiersite Formation of West Junggar, Xinjiang, China, and the International Code of Nomenclature for algae, fungi, and plants (Shenzhen Code). Barsassia ornata is determined as the type species of the genus, and a neotype is designated for that name. Barsassia ornata consists of fan- or rectangular-shaped leaves with awl-shaped or finger-like distal tips. Its leaves are pseudo-whorls and imbricately arranged on the stem surface forming distinct step-like structure.

Los mármoles cálcicos de El Escorial (Complejo Metamórfico Cushamen, Macizo Norpatagónico): caracterización isotópica de 87Sr-86Sr y edad de sedimentación

The El Escorial marbles (Cushamen Metamorphic Complex) along with amphibolites form metamorphic septa within the permian granitoids of the Mamil Choique Formation (261-286 Ma). The metamorphism, determined in granulite facies migmatic gneisses septa cropping out 120 km southwest of El Escorial, occurs at 311 ± 27 Ma (CHIME method in monazite). The marbles are calcitic (calcite > 95%, R.I.: 0.5 to 2.5%) and show 87Sr/86Sr values between 0.70768 and 0.70825 (n = 10). The data provided in this work, added to previous contributions, allow to constraints the sedimentation age of the silicic-carbonate successions of the Cushamen Metamorphic Complex between ca. 385 and 335 Ma. This suggests the existence of a mixed carbonate-siliciclastic platform at least in the southernmost portion of southwestern Gondwana between Middle Devonian and early Carboniferous (Middle Mississippian).

Early Devonian Arc-Related Volcanic Rocks in the Haerdaban, North Margin of the Yili Block: Constraint on the Southward Subduction of the Junggar Ocean

The origin and tectonic implication of Early–Middle Devonian magmatism in the northern margin of YB (Yili Block) remain enigmatic and are important for understanding Late Paleozoic evolution of the Junggar Ocean and southern Kazakhstan Orocline. Here, we present the systematic study of whole-rock geochemical and Sr–Nd isotope features as well as U–Pb–Hf isotope characteristics of zircon crystals for newly identified Early Devonian volcanic rocks from the northern margin of YB. The volcanic rocks are composed of rhyolite, rhyolite porphyry, and rhyolitic tuff. Zircon U-Pb age dating indicates they were formed at ca. 407~418 Ma. They have high SiO2 (70.16–77.52 wt.%) and alkali (5.10–9.56 wt.%) contents, and high Zr + Nb + Ce + Y content (~456 ppm), indicative of A-type magma. Their relative depletion of Nb, Ta, and Ti, and enrichment of LILEs show arc affinity. Their low initial 87Sr/86Sr ratios (0.699708–0.709822) and negative εNd(t) values (−1.8 to −4.0) indicate a mainly continental magma source and their positive εHf(t)values (+6.13 to +14.81) are possibly due to the garnet effect. All these above reveal that volcanic rocks were generated by re-melting of lower crust under a high temperature condition, which was induced by long-lived heat accumulation with no or minimal basalt flux. Combined with active continental margin inference evidenced by contemporaneous sedimentary rocks, we attribute the generation of the volcanic rocks to a continental arc setting related to the southward subduction of Junggar oceanic crust. Thus, we infer the Early–Middle Devonian arc-related magmatic rocks in the northern margin of YB are eastward counterparts of the southern limb of the Devonian Volcanic Belt, which resulted from a relatively steady-state southward subduction.

Ulungarat Basin: Record of a major Middle Devonian to Mississippian syn-rift to post-rift tectonic transition, eastern Brooks Range, Arctic Alaska

The Ulungarat Basin of Arctic Alaska is a unique exposed stratigraphic record of the mid-Paleozoic transition from the Romanzof orogeny to post-orogenic rifting and Ellesmerian passive margin subsidence. The Ulungarat Basin succession is composed of both syn-rift and post-rift deposits recording this mid-Paleozoic transition. The syn-rift deposits unconformably overlie highly deformed Romanzof orogenic basement on the mid-Paleozoic regional angular unconformity and are unconformably overlain by post-rift Endicott Group deposits of the Ellesmerian passive margin. Shallow marine strata of Eifelian age at the base of the Ulungarat Formation record onset of rifting and limit age of the Romanzof orogeny to late Early Devonian. Abrupt thickness and facies changes within the Ulungarat Formation and disconformably overlying syn-rift Mangaqtaaq Formation suggest active normal faulting during deposition. The Mangaqtaaq Formation records lacustrine deposition in a restricted down-faulted structural low. The unconformity between syn-rift deposits and overlying post-rift Endicott Group is interpreted to be the result of sediment bypass during deposition of the outboard allochthonous Endicott Group. Within Ulungarat Basin, transgressive post-rift Lower Mississippian Kekiktuk Conglomerate and Kayak Shale (Endicott Group) are older and thicker than equivalents to the north. North of Ulungarat Basin, deformed pre-Middle Devonian rocks were exposed to erosion at the mid-Paleozoic regional uncon­formity for ~50 m.y., supplying sediments to the rift basin and broader Arctic Alaska rifted margin beyond. Although Middle Devonian to Lower Mississip­pian chert- and quartz-pebble conglomerates and sandstones across Arctic Alaska share a common provenance from the eroding ancestral Romanzof highlands, they were deposited in different tectonic settings.

BIOSTRATIGRAPHY AND CORRELATION OF DEVONIAN DEPOSITS IN THE SOUTH-WEST SEGMENT OF THE EAST-EUROPEAN PLATFORM BY BRACHIOPODS

The main aim of the paper is to study the detailed distribution of the brachiopod fauna throughout the entire Devonian section from the Silurian-Devonian boundary at the Podilla region to the Devonian-Carboniferous boundary at the SW slope of the Dnipro-Donets Depression (DDD). The Devonian brachiopods (mainly Productids, Spiriferids and Rhynchonellids) of the south-west segment of the East-European Platform (EEP) are reviewed from the DDD, Volhyn-Podilla monocline (VPM) including the L’viv Paleozoic Trough, and Fore-Dobrogea Paleozoic Depression (FDPD). The faunas of these regions are mutually related and compared to the Devonian faunas of the EEP (Russia) and Pripyat’ Depression (Belarus). In recent years several paleontological investigations have broadened and deepened our knowledge of the Devonian biostratigraphy of Ukraine. Based on systematic studies of brachiopods from the SW segment of the EEP we recognize four successive faunas corresponding to four great marine transgressions — Early Devonian (Tiwer Series, the Monograptus uniformis Zone), Middle Devonian (Givetian Stage, the conodont varcus Zone), Late Frasnian (the conodont Upper rhenana — linguiformis Zone), and Early Famennian (the conodont triangularis-crepida Zone). The Early Devonian association includes Howellella angustiplicata, Plectodonta maria, and Daiya navicula and others which are similar to late Silurian brachiopods by their generic features (represented the genus common with the Upper Silurian). The Middle Devonian assemblages contain: Emanuella volhynica, Atrypa (Desquamatia) ventricosa, Chonetes sarcinulata, and Poloniproductus productoides at VPM sections (Givetian Stage, the varcus Zone), as well as Variatrypa sokolovae (Eifelian Stage), but in the DDD sections the impoverished association with Stringocephalus cf. burtini (Eifelian Stage) and Atrypa uralica (Givetian Stage) occur. The Late Frasnian association is represented by dominance of Theodossia tanaica, T. evlanensis, T. livnensis at all regions — VPM, DDD and FDPD (the Upper rhenana — linguiformis zones). The Early Famennian association is represented by ex Cyrtospirifer archiaci = Cyrtospirifer asiaticus and Cyrtospirifer ljachovichensis, Cyrtiopsis sp., Ptychomaletoechia zadonica, Iloerhynchus tichomirovi, Ardiviscus ex gr.herminae, Steinhagella annae etc. at DDD and by the same association plus Dmitria angustirostris at VPM (the triangularis-crepida zones). Brachiopods near the D-C boundary have been recorded so far from the black shales fossiliferous deeper water facies only in DDD: Spinocarinifera nigra, S. fallax, Sphenospira julii, Parallelora sp. (the Siphonodella praesulcata Zone). The result of our systematic study of productids, spiriferids, rhynchonellids, atrypids, and athyrids from Ukrainian sections are in perfect agreement with, and supplement to the previous investigations of Middle and Upper Devonian deposits at VPM and DDD, suggesting their important role for precising boundaries between the Devonian stages and horizons in SW segment of EEP. The essential role of brachiopods for the Devonian biostratigraphy and correlations with the East-European biozonation is confirmed.

Supplemental Material: Ulungarat Basin: Record of a major Middle Devonian to Mississippian syn-rift to post-rift tectonic transition, eastern Brooks Range, Arctic Alaska

<div>Describes the organization, sedimentology, and depositional environments of the Ulungarat Basin succession including description of type sections of the Ulungarat and Mangaqtaaq formations. Table S1 documents published fossil and radiometric age constraints used to construct the mid-Paleozoic tectonostratigraphic chart (Fig. 12), including basis for age assignment and list of source references. A reference list of all sources cited in Table S1 is included.<br></div>