ASSESSMENT OF CHANGES IN THE HYDROGEOLOGICAL CONDITIONS CAUSED BY WET-BASED CONSERVATION OF THE STYLSKYI QUARRY OPERATED BY “DOKUCHAEVSK FLUX AND DOLOMITE COMPLEX” PJSC USING MATHEMATICAL MODELLING

Extraction of minerals significantly affects the hydrogeological conditions of the environment. Active development of mining operations in the Donbas region determined the dominant influence of technogenic changes in geological environment on the formation of modern ecological conditions in the region. This applies not only to coal mining but also raw materials extraction (dolomites, limestone) for metallurgical plants mostly by quarrying. Recently, a significant environmental problem in the region has been the mines and quarries closure, envisaged by the program for restructuring the coal industry of Ukraine. Closure of mines or quarries through wet-based conservation is the least financially expensive, although it significantly increases the technogenic load on the natural environment. The object of research involved groundwater and surface water within the area of the Stylskyi and Skhidnyi (Vostochnyi) quarries of the “Dokuchaevsk flux-dolomite complex” PJSC, as well as Kipucha Krynytsa and Shevchenkivskyi water intake structures. The goal of research was to forecast changes in the hydrogeological conditions under the influence of wet-based conservation of the Stylskyi quarry. To achieve this goal, hydrogeological methods, mathematical modelling, and expert assessments were used. Consequently, a hydrogeological model of the research area was created, its functional correspondence to the natural-anthropogenic conditions was confirmed, and calculation hydrogeological parameters were specified. As a result, the forecast of changes in the hydrogeological conditions under the influence of wet-based conservation of the Stylskyi quarry was made. In particular, the following issues were determined: the dynamics of quarry flooding; the influence of this process on changes in water inflows to the Skhidnyi (Vostochnyi) quarry, Kipucha Krynytsa and Shevchenkivskyi water intake structures; possible flooding of settlements and swamping of the research area; changes in chemical composition and groundwater salinity; time of quarry draining at various intensity of water outflow to resume mineral production in case of need. We would like to emphasize that the forecasts made should be used when designing partial or full flooding of the Stylskyi quarry.

TO THE MEMORY OF VOLODYMYR MYKOLAYOVYCH SHOVKOPLYAS (October 15, 1929 — May 4, 2021)

The article is dedicated to Volodymyr Shovkoplyas, the famous scientist and researcher in the field of general geology, geochronology, paleogeography and stratigraphy of the quarter, Doctor of Geological and Mineralogical Sciences, Professor, Leading Researcher of the Department of Anthropogene Geology of the Institute of Geological Sciences of the National Academy of Sciences of Ukraine.

BIOSTRATIGRAPHY AND CORRELATION OF DEVONIAN DEPOSITS IN THE SOUTH-WEST SEGMENT OF THE EAST-EUROPEAN PLATFORM BY BRACHIOPODS

The main aim of the paper is to study the detailed distribution of the brachiopod fauna throughout the entire Devonian section from the Silurian-Devonian boundary at the Podilla region to the Devonian-Carboniferous boundary at the SW slope of the Dnipro-Donets Depression (DDD). The Devonian brachiopods (mainly Productids, Spiriferids and Rhynchonellids) of the south-west segment of the East-European Platform (EEP) are reviewed from the DDD, Volhyn-Podilla monocline (VPM) including the L’viv Paleozoic Trough, and Fore-Dobrogea Paleozoic Depression (FDPD). The faunas of these regions are mutually related and compared to the Devonian faunas of the EEP (Russia) and Pripyat’ Depression (Belarus). In recent years several paleontological investigations have broadened and deepened our knowledge of the Devonian biostratigraphy of Ukraine. Based on systematic studies of brachiopods from the SW segment of the EEP we recognize four successive faunas corresponding to four great marine transgressions — Early Devonian (Tiwer Series, the Monograptus uniformis Zone), Middle Devonian (Givetian Stage, the conodont varcus Zone), Late Frasnian (the conodont Upper rhenana — linguiformis Zone), and Early Famennian (the conodont triangularis-crepida Zone). The Early Devonian association includes Howellella angustiplicata, Plectodonta maria, and Daiya navicula and others which are similar to late Silurian brachiopods by their generic features (represented the genus common with the Upper Silurian). The Middle Devonian assemblages contain: Emanuella volhynica, Atrypa (Desquamatia) ventricosa, Chonetes sarcinulata, and Poloniproductus productoides at VPM sections (Givetian Stage, the varcus Zone), as well as Variatrypa sokolovae (Eifelian Stage), but in the DDD sections the impoverished association with Stringocephalus cf. burtini (Eifelian Stage) and Atrypa uralica (Givetian Stage) occur. The Late Frasnian association is represented by dominance of Theodossia tanaica, T. evlanensis, T. livnensis at all regions — VPM, DDD and FDPD (the Upper rhenana — linguiformis zones). The Early Famennian association is represented by ex Cyrtospirifer archiaci = Cyrtospirifer asiaticus and Cyrtospirifer ljachovichensis, Cyrtiopsis sp., Ptychomaletoechia zadonica, Iloerhynchus tichomirovi, Ardiviscus ex gr.herminae, Steinhagella annae etc. at DDD and by the same association plus Dmitria angustirostris at VPM (the triangularis-crepida zones). Brachiopods near the D-C boundary have been recorded so far from the black shales fossiliferous deeper water facies only in DDD: Spinocarinifera nigra, S. fallax, Sphenospira julii, Parallelora sp. (the Siphonodella praesulcata Zone). The result of our systematic study of productids, spiriferids, rhynchonellids, atrypids, and athyrids from Ukrainian sections are in perfect agreement with, and supplement to the previous investigations of Middle and Upper Devonian deposits at VPM and DDD, suggesting their important role for precising boundaries between the Devonian stages and horizons in SW segment of EEP. The essential role of brachiopods for the Devonian biostratigraphy and correlations with the East-European biozonation is confirmed.

THE PALEOARCHEAN (3.3 Ga) AND MESOARCHEAN (3.0 Ga) TTGs OF THE WESTERN AZOV AREA, THE UKRAINIAN SHIELD

A large anticline structure that includes the West Azov and Remivka blocks occurs in the western part of the Azov Domain of the Ukrainian Shield. These blocks are composed of rocks of the Mesoarchean (3.2-3.0 Ga) granite-greenstone association and relics of an older basement. The anticline is divided into two parts by the Bilotserkivka structure of sub-latitudinal strike; the northern part includes the Huliaipole and Remivka blocks, and the southern part is comprised of the Saltycha anticline. The Archean plagiogranitoids of the West Azov underwent intense dislocation metamorphism during the Paleoproterozoic. In many areas they were transformed into plagioclase gneisses that were attributed to the Paleoarchean “Kainkulak thickness” of the Azov Series. Detailed geological-structural and geochronological studies are required to define the age of these gneisses.We have chosen two areas for our studies: the Lantsevo anticline within the Bilotserkivka structure, and the Ivanivka area in the eastern part of the Saltycha anticline. The Bilotserkivka structure is composed of rocks of the Central Azov Series and highly deformed Archean formations. We have dated plagiogneisses of the Lantsevo anticline. These rocks contain large relics of metamorphic rocks of unknown age, including two-pyroxene and pyroxene crystalline schists, and pyroxenemagnetite quartzites (BIF). In terms of chemical composition, two-pyroxene crystalline schists correspond to tholeiitic basalts and basaltic komatiites. Ferruginous-siliceous rocks belong to the Algoma type typical for the Archean greenstone belts. Biotite gneisses are similar to the medium-pressure tonalite-trondhjemite-granodiorite rocks (TTGs). The U-Pb age of zircon crystallization from biotite gneisses is 3299 ± 11 Ma. At 30 km in the western part of the Bilotserkivka structure, we have previously identified quartz diorites having an age of 3297 ± 22 Ma. In terms of geochemical characteristics, they correspond to low-pressure TTGs. These data show that the Bilotserkivka structure is a block representing an ancient basement. In the Ivanivka area in the eastern part of the Saltycha anticline, the strike of the Archean rocks was reorientated from northwestern to latitudinal. The studied dislocated trondhjemites of the Ivanivka area correspond to TTGs in terms of the geochemical characteristics. They contain numerous relics of highly altered amphibolites. The U-Pb age of zircon crystallization from trondhjemite is 3013 ± 15 Ma. These rocks are of the same age as TTGs of the Shevchenko Complex cutting through the sedimentary-volcanogenic rocks of the greenstone structures of the Azov Domain. They share age and geochemical characteristics with biotite and amphibole-biotite gneisses of the “Kainkulak thickness” in Zrazkove village located at the Mokra Konka river (3.1-3.0 Ga) and with biotite gneisses in the lower reaches of the Kainkulak river (2.92 Ga). Thus, gneisses of the “Kainkulak thickness” in fact represent the Mesoarchean TTGs of the Shevchenko Complex, which were transformed in the Paleoproterozoic time due to the dislocation metamorphism. Late Paleoarchean (3.3 Ga) tonalites are known in the West Azov and the KMA domains; they probably also occur in the basement of the Middle Dnieper domains, where detrital zircons of this age have been reported. These data allow us to conclude the existence of a large Late Paleoarchean (3.3 Ga) protocraton, in which the Mesoarchean (3.2-3.0 Ga) greenstone belts and TTGs of the eastern part of the Ukrainian Shield and the KMA Domain were formed.

90 th АNNIVERSARY OF ACADEMICIAN OF THE NAS OF UKRAINE VADYM IVANOVYCH LYALKO

A brief review of the biography and scientific achievements of Academician of the NAS of Ukraine V.I. Lyalko on the occasion of the 90th Аnniversary.

COMPLEX BIOSTRATIGRAPHIC SCHEME OF THE JURASSIC DEPOSITS OF THE PIENNINE ZONE OF THE UKRAINIAN CARPATHIANS

The article summarizes the results of the study of paleontology and biostratigraphy of the Jurassic of the Piennine Zone of the Ukrainian Carpathians by domestic and foreign researchers. For the first time, a summary paleontological description of these sediments is presented, taking into account numerous published data on identified macro- and mictofossils. A correlation biozonal scale has been created, as well as complex biostratigraphic schemes for each Jurassic series of its region in accordance with the International Stratigraphic Scale (2020). Because the stratigraphic sequence was disturbed by disjunctive dislocations, these schemes were developed by analysis of fragmentary sections. At present, three series of the Jurassic are determined by ammonites, belemnites, pelecypods, brachiopods, the Lower and Upper series are also dated by dinocysts, the Upper also by foraminifera and tintinnids. The stages and standard zones of the modern international scale are determined by ammonites: Liasicus of the Gettangian; Bucklandi, Obtusum, Raricostatum of the Sinemurian; Jamesoni, Emaciatum of the Pliensbachian; Tenuicostatum, Serpentinum, Bifrons, Thouarcense of the Toarcien; Opalinum, Murchisonae, Bradfordensis, Concavum of the Aalenian; Propinquans, Humpriesianum, Parkinsoni of the Bajocian; Zigzag, Aurigerus, Subcontractus, Bremeri, Retrocostatum of the Bathonian; Athletа of the Callovian; Plicatilis і Bifurcates of the Oxfordian; Divisum, Acanticum і Cavouri of the Kimmeridgian. Continuous dinocyst zonation is traced in the Upper Jurassic – Fibrata Аcme (Upper Oxfordian), Parvula Acme, Moluccana і Borzai (Kimmerigian), Pulla, Tithonica, Malmica, Semiradiata (Lower Tithonian) and all standard tintinnide zones of Tithonian — Chitinoidella (підзони Dobeni і Boneti), Praetintinnopsella, Crassicollaria. The boundaries of the stages from the Gettangiean to the Oxfordian are not determined. The boundaries between the Lower and Upper Oxfordian as well as between the Kimmeridgian substages are determined by ammonites as well as the boundary between the Kimmeridgian and Tithonian is determined by dinocysts, and the boundary between the Jurassic and Cretaceous is determined by tintinnids (corresponds to the boundary between the zones Crassicollaria of Tithonian and Calpionella of Berriassian). Stratigraphic unconformities were revealed by the macro- and mictofossils: the regional erosion on the boundary between the Aalenian and Bajocian as well as in Early Callovian, and short gap on the boundary between the Lower and Upper Bajocian.

85 th АNNIVERSARY OF ACADEMICIAN OF THE NAS OF UKRAINE VIACHESLAV MYKHAILOVYCH SHESTOPALOV

A brief review of the biography and scientific achievements of Academician of the NAS of Ukraine V.M. Shestopalov on the occasion of the 85th Аnniversary.

GROUNDWATER RUNOFF IN THE PIVDENNYI BUH RIVER BASIN IN CONDITIONS OF GLOBAL WARMING

This paper analyses changes in the calculated values of the specific runoff of unconfined and confined groundwaters to the rivers Pivdennyi Buh (Khmilnyk town) and Zhar (a tributary of the Pivdennyi Buh; Vinnytsia and Khmelnytsky regions) by seasons and long-term stages, for a total of 38 years (1980-2017). Regularities of seasonal changes in groundwater runoff in areas with different relief and average long-term groundwater levels (0.5-1.5; 0.8-2.5 and 2.7-4.5 m) are revealed. These changes have been shown to be closely related to abnormal air temperature fluctuations. There are four stages of successive changes in the regime of groundwater and in the volume of their runoff to rivers: I. 1980-1989 (1990) — traditionally minimal winter and autumn underground runoff, moderate summer and predominant spring runoff, dominance of runoff from the area with high GWT; ІІ. 1990-1998 — growth and advantages of groundwater runoff from the area with low GWT, reduction to the long-term minimum of groundwater runoff in the area with high GWT (0.8-2.5 m); III. From 1999 to 2014 — the predominant dominance of winter runoff over spring, slow growth of groundwater runoff in a limited area of the catchment with levels of 0.8-2.5 m; high-amplitude fluctuations of runoff and GWT with the achievement of long-term maximums in the area with GWT = 2.5-4.0 m; IV. 2015-2019 — the most intense reduction of GWT, and in the upper reaches of small rivers — of underground runoff to rivers.There is a progressive decrease in the specific flow of groundwater to rivers, and consequently of their resources — primarily for the aquifers in the upper reaches of rivers with GWT 0.5-1.5 m with no pressure recharge. Aquifers of ground water fed by confined aquifers (mainly within floodplains and the first low terraces of rivers) in the studied area of the Ukrainian massif of fracture waters have greater stability of the level regime on the background of rising temperatures and decreasing precipitation (recorded by 2020) than shallow water (0.5-2.0 m) without signs of such recharge.

PECULIARITIES OF FORMATION OF THE LOWER CRETACEOUS TEСTONO-SEDIMENTATION SYSTEM OF THE BLACK SEA MEGADEPRESSION

Based on the analysis of the distribution of structural-material complexes, facial-genetic types and modeling of the history of immersion of the Lower Cretaceous sediments, the spatial-temporal differentiation of the tectonic regime of the Black Sea megadepression in the Early Cretaceous was established. It is shown that the structural and lithologicalfacial features of the Lower Cretaceous tectonic-sedimentation system were determined by the interaction of tectonic and geological-paleooceanographic factors. Thus, the low sea level and the initial phases of activation of sublatitudinal faults in the Hoterivian-Aptian determined the dominant influence of submeridional tectonic faults on the formation of the corresponding structural-facial block zonation. The increase in the area of the basin, the removal of denudation areas in the Late Albian reduced the intensity of terrigenous discharge, and the prolonged activity of sublatitudinal faults led to the formation of sublatitudinal structural-facial zonation. In the subsequent geological history, the tectonic regime was characterized by a complex mosaic-block character, which influenced the heterogeneity of oil and gas lithofluid systems of Cretaceous deposits.

NEW DATA ON PROMISING OIL AND GAS OBJECTS IN THE SANDSTONES OF THE YAMNA SUITE OF THE PALEOCENE IN THE NORTHWEST OF THE SKIBA ZONE OF THE UKRAINIAN CARPATHIANS

More than 6 million tons of the oil have been extracted in the Skybа Zone of the Ukrainian Carpathians. In particular, 4.2 million tons of oil (85.7% of total production) were obtained from the Yamna sandstones of Paleocene, which are characterized by satisfactory physical properties. Most of the areas of fields that exploited them are located in the Boryslav oil and gas production area. Among them are such oil fields as Skhidnytsko-Urytske (more than 3.8 million tons of oil extracted), Violeta, Faustina, MEP, Miriam and Ropne. Outside this area, oil was extracted in Strilbychi and Staraya Sol. At most of these fields, oil horizons are at a depth of only 100-800 m. The gas and condensate are extracted at the field of Tanyavа in the wing of the Vytvytska Luska of the Berehova Skyba, which has been torn off by the thrust. In addition, a very large number of natural oil and gas manifestations - direct signs of oil and gas potential - have been recorded in the Skyba Zone. All this indicates the potential prospects of structures within the Skyba Zone, including shallow ones. The distribution area of Yamna sandstones is much larger than the area of these deposits. The distribution area of sandstones of Yamna is much larger than the area of these deposits. It occupies about half of the area of Skyba Zone. Part of it can be considered promising, removing areas where of Yamna sandstones are present on the day surface, although, even in such conditions, they are in some cases industrially oil-bearing (Strelbychi oil field). Sandstones of Yamna are characterized by satisfactory reservoir properties., The calculated porosity and permeability reach the maximum values at known deposits: 0.182 and 130 ∙ 10–3 microns2 respectively, and the estimated thickness of 13.5 m. In the Folded Carpathians and, especially, within the north-eastern fragments (Beregova, Oriv, Skoliv) in different years performed a large amount of field seismic surveys. On the basis of the obtained materials, for the first time in the Carpathian region structural constructions were made on the reflecting horizons in the Paleocene (Yamna Formation) and in the Stryi Formation of the Upper Cretaceous. This article evaluates the prospects of these research objects. The Khodkiv and Osichnyanska structures of Berehova Skyba are recommended for conducting search works.