Second-Generation Phosphorus: Recovery from Wastes towards the Sustainability of Production Chains

Phosphorus (P) is essential for life and has a fundamental role in industry and the world food production system. The present work describes different technologies adopted for what is called the second-generation P recovery framework, that encompass the P obtained from residues and wastes. The second-generation P has a high potential to substitute the first-generation P comprising that originally mined from rock phosphates for agricultural production. Several physical, chemical, and biological processes are available for use in second-generation P recovery. They include both concentrating and recovery technologies: (1) chemical extraction using magnesium and calcium precipitating compounds yielding struvite, newberyite and calcium phosphates; (2) thermal treatments like combustion, hydrothermal carbonization, and pyrolysis; (3) nanofiltration and ion exchange methods; (4) electrochemical processes; and (5) biological processes such as composting, algae uptake, and phosphate accumulating microorganisms (PAOs). However, the best technology to use depends on the characteristic of the waste, the purpose of the process, the cost, and the availability of land. The exhaustion of deposits (economic problem) and the accumulation of P (environmental problem) are the main drivers to incentivize the P’s recovery from various wastes. Besides promoting the resource’s safety, the recovery of P introduces the residues as raw materials, closing the productive systems loop and reducing their environmental damage.

Solubility and Efficiency of Rock Phosphate Fertilizers Partially Acidulated with Zeolite and Pillared Clay as Additives

Soluble phosphates are the most common sources currently used in crop production in tropical soils; however, they present low efficiency and are more expensive than natural rock phosphates. The objective was to develop new phosphate fertilizers with slow solubility through the partial acidification of rock phosphates (RPs), incorporating materials with adsorption characteristics to favor slow dissolution and prevent phosphorus (P) fixation in the soil. Three rock phosphates, Araxá (ARP), Bayovar (BRP) and Morocco (MRP), were evaluated at two acidulation levels (25 and 50% Ac.) and two additives; pillared clays (PILC) and zeolites (Zeo), plus triple superphosphate (TSP) and a control (nil-P). The soil diffusion was evaluated in concentric rings in Petri dishes. Solubility was evaluated in leaching columns and sampled in layers from surface for P forms in the soil profile. The relative agronomic efficiency (RAE) was evaluated in maize. Greater diffusion was provided by TSP, followed by BRP and MRP both with 50% Ac. + Zeo, and MRP with 50% Ac. + PILC. Percolated P was more pronounced under TSP, followed by RPs (BRP and MRP) with 50% Ac. + Zeo. BRP and MRP + 50% Ac. were the most promising sources with RAE above 74% compared to TSP.

The Effect of Microbe Plus and Phosphorus Fertilizers on the Vegetative Growth of Oil Palm (Elaesis guineensis, Jacq.) Seedlings

The main objective of this study was to improve the growth of oil palm seedlings by using microbe plus to enhance phosphorous availability from rock phosphate under oil palm nursery was evaluated at Oil Palm Research Institute of Ghana, Kade-Kumasi. The study consisted of 16 treatments replicated 3 times in a 4 × 4 factorial experiment arranged in Randomize Complete Block Design. The factors tested were: Phosphate fertilizers (Phosphate only, triple superphosphate, super rock phosphate and Togo rock phosphate) and microbe plus rates (0, 50, 100 and 150%). Data was collected on leaf area, leaf area index and dry matter production. All data obtained were subjected to analysis of variance (ANOVA) using GENSTAT Version 11.1 (2008). The results showed that the P fertilizers and microbe plus applied alone or their interactions had no significant (P=.05) effect on leaf area and leaf area index values, however, dry matter produced was significantly (P=.05) different from each other. TSPMP150 treated seedlings produced significantly (P=.05) the highest dry weight; 42% increase over the control (No phosphate and microbe plus). The complementary use of microbe plus with triple superphosphate or Senegal rock phosphate proved to be the best options in terms of the parameters measured than the triple superphosphate. Microbe plus can therefore be used in combination with rock phosphate to improve phosphate availability. Field experiment is suggested to validate the effect of microbe plus and these rock phosphates on the performance of oil palm, whereas, additional studies with different application rates, both at nursery and at the field, are recommended.

Phosphorus sources residual effects on Tifton 85 production and nutritive value cultivated in a tropical weathered soil1

Acid reactions and low available phosphorus in tropical soils limit forage yield. The aim was to evaluate soil chemical characteristics pH, P and Mg, forage nutritive values, critical soil and plant P levels and the residual effect of each source. The experiment was in a greenhouse with a Rhodic Haplustox, loam texture. Experimental design was a 5 x 4 factorial with five replicates which phosphate fertilizers were triple superphosphate, reactive rock phosphates Gafsa and Arad, and fused magnesium phosphate powder and coarse, applied at rates of 30, 60, 90 and 120 mg kg-1 P and a control treatment without P. The effectiveness of rock phosphates increased due to their residual effect. The coarse fused magnesium phosphate resulted in the lowest efficiency. The P critical level in soil and plant were 18 mg kg-1 and 2.4 g kg-1, respectively. The increase of phosphorus rates provided an increase in crude protein content.

MECHANISM OF VARIOUS ROCK PHOSPHATES DISSOLUTION BY TRICHODERMA ASPERELLUM GJS 03-35

The process of dissolution of mineral phosphorus raw materials under the influence of Trichoderma asperellum has a complex mechanism, due to both the participation of organic acids and other factors, the main of which is the emission of protons upon absorption of ammonium ion by cells.