Monitoring the effectiveness of selected sorption materials in removing diclofenac from water

One of the contemporary problems is the widespread use of medicaments, which leads to an increased occurrence of these substances in the environment. The efficiency of conventional treatment processes for removing drugs from water is in most cases very little, if not zero. Treatment processes for removal of drugs include adsorption on activated carbon, membrane processes, and advanced oxidation processes. Within a specific university research project, a laboratory test was performed at the Institute of Municipal Water Management of the Faculty of Civil Engineering, Brno University of Technology, to monitor the effectiveness of diclofenac removal by selected sorption materials. Diclofenac was chosen for this experiment as a representative of one of the most widespread groups of drugs - non-steroidal anti-inflammatory drugs. The removal of diclofenac from water was performed using columns filled with sorption materials Filtrasorb F100, GEH and Bayoxide E33. The aim of the test was to compare the selected sorption materials in terms of their effectiveness in removing diclofenac from water. From analyses of water taken at predetermined time intervals after filtration through said materials, it was found that the most suitable material for removing diclofenac from water is Filtrasorb F100.

Simple Fabrication of Solid-State Nanopores on a Carbon Film

Solid-state nanopores are widely used as a platform for stochastic nanopore sensing because they can provide better robustness, controllable pore size, and higher integrability than biological nanopores. However, the fabrication procedures, including thin film preparation and nanopore formation, require advanced micro-and nano-fabrication techniques. Here, we describe the simple fabrication of solid-state nanopores in a commercially available material: a flat thin carbon film-coated micro-grid for a transmission electron microscope (TEM). We attempted two general methods for nanopore fabrication in the carbon film. The first method was a scanning TEM (STEM) electron beam method. Nanopores were fabricated by irradiating a focused electron beam on the carbon membrane on micro-grids, resulting in the production of nanopores with pore diameters ranging from 2 to 135 nm. The second attempt was a dielectric breakdown method. In this method, nanopores were fabricated by applying a transmembrane voltage of 10 or 30 V through the carbon film on micro-grids. As a result, nanopores with pore diameters ranging from 3.7 to 1345 nm were obtained. Since these nanopores were successfully fabricated in the commercially available carbon thin film using readily available devices, we believe that these solid-state nanopores offer great utility in the field of nanopore research.

Unidirectional ion transport in nanoporous carbon membranes with a hierarchical pore architecture

The transport of fluids in channels with diameter of 1-2 nm exhibits many anomalous features due to the interplay of several genuinely interfacial effects. Quasi-unidirectional ion transport, reminiscent of the behavior of membrane pores in biological cells, is one phenomenon that has attracted a lot of attention in recent years, e.g., for realizing diodes for ion-conduction based electronics. Although ion rectification has been demonstrated in many asymmetric artificial nanopores, it always fails in the high-concentration range, and operates in either acidic or alkaline electrolytes but never over the whole pH range. Here we report a hierarchical pore architecture carbon membrane with a pore size gradient from 60 nm to 1.4 nm, which enables high ionic rectification ratios up to 104 in different environments including high concentration neutral (3 M KCl), acidic (1 M HCl), and alkaline (1 M NaOH) electrolytes, resulting from the asymmetric energy barriers for ions transport in two directions. Additionally, light irradiation as an external energy source can reduce the energy barriers to promote ions transport bidirectionally. The anomalous ion transport together with the robust nanoporous carbon structure may find applications in membrane filtration, water desalination, and fuel cell membranes.