Comparison of Total Column and Surface Mixing Ratio of Carbon Monoxide Derived from the TROPOMI/Sentinel-5 Precursor with In-Situ Measurements from Extensive Ground-Based Network over South Korea

Atmospheric carbon monoxide (CO) significantly impacts climate change and human health, and has become the focus of increased air quality and climate research. Since 2018, the Troposphere Monitoring Instrument (TROPOMI) has provided total column amounts of CO (CTROPOMI) with a high spatial resolution to monitor atmospheric CO. This study compared and assessed the accuracy of CTROPOMI measurements using surface in-situ measurements (SKME) obtained from an extensive ground-based network over South Korea, where CO level is persistently affected by both local emissions and trans-boundary transport. Our analysis reveals that the TROPOMI effectively detected major emission sources of CO over South Korea and efficiently complemented the spatial coverage of the ground-based network. In general, the correlations between CTROPOMI and SKME were lower than those for NO2 reported in a previous study, and this discrepancy was partly attributed to the lower spatiotemporal variability. Moreover, vertical CO profiles were sampled from the ECMWF CAMS reanalysis data (EAC4) to convert CTROPOMI to surface mixing ratios (STROPOMI). STROPOMI showed a significant underestimation compared with SKME by approximately 40%, with a moderate correlation of approximately 0.51. The low biases of STROPOMI were more significant during the winter season, which was mainly attributed to the underestimation of the EAC4 CO at the surface. This study can contribute to the assessment of satellite and model data for monitoring surface air quality and greenhouse gas emissions.

Assessment of Tropospheric Concentrations of NO2 from the TROPOMI/Sentinel-5 Precursor for the Estimation of Long-Term Exposure to Surface NO2 over South Korea

Since April 2018, the TROPOspheric Monitoring Instrument (TROPOMI) has provided data on tropospheric NO2 column concentrations (CTROPOMI) with unprecedented spatial resolution. This study aims to assess the capability of TROPOMI to acquire high spatial resolution data regarding surface NO2 mixing ratios. In general, the instrument effectively detected major and moderate sources of NO2 over South Korea with a clear weekday–weekend distinction. We compared the CTROPOMI with surface NO2 mixing ratio measurements from an extensive ground-based network over South Korea operated by the Korean Ministry of Environment (SKME; more than 570 sites), for 2019. Spatiotemporally collocated CTROPOMI and SKME showed a moderate correlation (correlation coefficient, r = 0.67), whereas their annual mean values at each site showed a higher correlation (r = 0.84). The CTROPOMI and SKME were well correlated around the Seoul metropolitan area, where significant amounts of NO2 prevailed throughout the year, whereas they showed lower correlation at rural sites. We converted the tropospheric NO2 from TROPOMI to the surface mixing ratio (STROPOMI) using the EAC4 (ECMWF Atmospheric Composition Reanalysis 4) profile shape, for quantitative comparison with the SKME. The estimated STROPOMI generally underestimated the in-situ value obtained, SKME (slope = 0.64), as reported in previous studies.

Off-Equatorial Deep-Cycle Turbulence Forced by Tropical Instability Waves in the Equatorial Pacific

The equatorial Pacific cold tongue is a site of large heat absorption by the ocean. This heat uptake is enhanced by a daily cycle of shear turbulence beneath the mixed layer—“deep-cycle turbulence”—that removes heat from the sea surface and deposits it in the upper flank of the Equatorial Undercurrent. Deep-cycle turbulence results when turbulence is triggered daily in sheared and stratified flow that is marginally stable (gradient Richardson number Ri ≈ 0.25). Deep-cycle turbulence has been observed on numerous occasions in the cold tongue at 0°, 140°W, and may be modulated by tropical instability waves (TIWs). Here we use a primitive equation regional simulation of the cold tongue to show that deep-cycle turbulence may also occur off the equator within TIW cold cusps where the flow is marginally stable. In the cold cusp, preexisting equatorial zonal shear uz is enhanced by horizontal vortex stretching near the equator, and subsequently modified by horizontal vortex tilting terms to generate meridional shear υz off of the equator. Parameterized turbulence in the sheared flow of the cold cusp is triggered daily by the descent of the surface mixing layer associated with the weakening of the stabilizing surface buoyancy flux in the afternoon. Observational evidence for off-equatorial deep-cycle turbulence is restricted to a few CTD casts, which, when combined with shear from shipboard ADCP data, suggest the presence of marginally stable flow in TIW cold cusps. This study motivates further observational campaigns to characterize the modulation of deep-cycle turbulence by TIWs both on and off the equator.

Detectability of biosignatures on LHS 1140 b

<p>Rocky extrasolar planets orbiting M dwarfs are prime targets in the search for habitable surface conditions and biosignatures with near-future telescopes like the James Webb Space Telescope (JWST) and the Extremely Large Telescope (ELT). Even for the closest known targets the capabilities to characterize Earth-like or CO<sub>2</sub>-dominated atmospheres with JWST or ELT might still be limited to a few molecules such as CO<sub>2</sub> or CH<sub>4</sub>. Hence it would be difficult to draw conclusions on the surface conditions and potential habitability of these planets. In clear H<sub>2</sub>-He atmospheres the molecular features in transmission spectra could be much larger and hence potential biosignatures might be detectable.</p><p>In this study, we investigate the detectability of the potential biosignatures NH<sub>3</sub>, PH<sub>3</sub>, CH<sub>3</sub>Cl, and N<sub>2</sub>O, assuming different H<sub>2</sub>-He atmospheres for the habitable zone super-Earth LHS 1140 b. Recent observations of the atmosphere of LHS 1140 b suggest that the planet might hold a clear H<sub>2</sub>-dominated atmosphere and might show an absorption feature around 1.4 µm due to H<sub>2</sub>O or CH<sub>4</sub> absorption. Here we use the coupled convective-climate-photochemistry model 1D-TERRA to simulate H<sub>2</sub> atmospheres of LHS 1140 b with different amounts of CH<sub>4</sub> and assuming that the planet has an ocean and a biosphere.</p><p>The destruction of the potential biosignatures NH<sub>3</sub>, PH<sub>3</sub>, CH<sub>3</sub>Cl, and N<sub>2</sub>O shows a weak dependence on the concentrations of CH<sub>4</sub>. For weak abundances of CH<sub>4</sub> only 5 to 10 transits are required to detect these molecules with JWST or ELT. However, for CH<sub>4</sub> surface mixing ratios of a few percent only NH<sub>3</sub> and N<sub>2</sub>O might be detectable with less than 10 transits. A scenario with large abundances of CH<sub>4</sub> is consistent with the spectral feature at 1.4 µm and such an atmosphere might allow habitable surface temperatures. If this spectral feature at 1.4 µm originates from H<sub>2</sub>O absorption, the planet is likely not habitable at the surface.</p>

Incorporation and evaluation of the CRI v2.2 chemical mechanism in UKESM1: An alternative mechanism with updated isoprene chemistry for investigating the influence of BVOCs on atmospheric composition and climate.

<p>We present the first incorporation and evaluation of the Common Representative Intermediates version 2.2 chemistry mechanism, CRI v2.2, for use in the United Kingdom Earth System Model (UKESM1). Tuned against the MCM v3.3.1, the CRI v2.2 mechanism builds on the previous CRI version, CRI v2.1, in UKESM1 (Archer-Nicholls et al., 2020) by updating isoprene chemistry and offers a more comprehensive description of tropospheric chemistry than the standard chemistry mechanism STRAT-TROP (ST).</p><p><span>CRI v2.2 adds state-of-the-art isoprene chemistry with the introduction of HO</span><sub><span>x</span></sub><span>-recycling via the isoprene peroxy radical isomerisation pathway, </span><span>making UKESM1 one of the first CMIP6 models to include this important chemistry. </span><span>HO</span><sub><span>x</span></sub><span>-recycling has noticeable effects on oxidants in regions with large emissions of biogenic volatile organic compounds (BVOCs). Low altitude OH in tropical forested regions increases by 75-150% relative to ST, reducing the existing model low bias compared to observations. Consequently, isoprene surface mixing ratios decrease considerably (25-40%), significantly improving the model high bias relative to ST. Methane lifetime decreases by 2% and tropospheric ozone burden increases by 4%. </span></p><p>Aerosol processes also differ between CRI v2.2 and ST, resulting in changes to the size and number distributions. Relative to ST, CRI v2.2 simulates an 8% decrease in the sulphate aerosol burden with 20% decreases in the nucleation and Aitken modes. By contrast, the secondary organic aerosol (SOA) nucleation mode burden increases by 11%. Globally, the average nucleation and Aitken mode aerosol number concentrations decrease by 20%.</p><p>The differences in aerosol and gas phase chemistry between CRI v2.2 and ST are likely to have impacts on the radiation budget. We plan to use CRI v2.2 and ST to investigate the influence that the chemical mechanism has on the simulated chemistry-climate feedbacks from BVOCs. In addition, CRI v2.2 will serve as the basis for the addition of a scheme describing the formation of highly oxygenated organic molecules (HOMs) from BVOCs, facilitating a semi-explicit mechanism for new particle formation from organic species.</p>

Effect of Breaking Waves on Near-Surface Mixing in an Ocean-Wave Coupling System under Calm Wind Conditions

Estimating wave effects on vertical mixing is a necessary step toward improving the accuracy and reliability of upper-ocean forecasts. In this study, we evaluate the wave effects on upper-ocean mixing in the northern East China Sea in summer by analyzing the results of comparative experiments: a stand-alone ocean model as a control run and two ocean–wave coupled models that include the effect of the breaking waves (BW) and of the wave–current interaction (WCI) with a vortex-force formalism. The comparison exhibits that under weak wind conditions, the BW effect prescribed by wave dissipation energy significantly enhances near-surface mixing because of increased downward turbulent kinetic energy (TKE), whereas the WCI has little effect on vertical mixing. Increased TKE results in a mixed-layer depth deepened by ~46% relative to the control run, which provides better agreement with the observed surface thermal structure. An additional experiment with local wind–based BW parameterization confirms the importance of nonlocally generated waves that propagated into the study area upon near-surface mixing. This suggests that under calm wind conditions, waves propagated over distances can largely affect surface vertical mixing; thus, ocean–wave coupling is capable of improving the surface thermal structure.

Discrete Element Simulation and Validation of a Mixing Process of Granular Materials

The mixing processes of granular materials have gained wide interest among various fields of science and engineering. In this study, our focus is a mixing process for offshore mining. We conducted numerical simulations using the discrete element method (DEM) in comparison with experimental works on mixing color sand. Careful calibration of initial packing densities has been performed for the simulations. For validation, the steady-state torques on the mixer head, the maximal increase of surface height after mixing, and the surface mixing patterns have been compared. The effect of particle size on the simulation results has been clarified. With the particle size approaching the actual particle size, consistent torques and mixing patterns indicate the capability of the DEM code for studying the particular mixing process, while the results for the maximal increase of surface height should be interpreted with more caution.

Observations of Near-Surface Mixing Behind a Headland

Field observations were collected near the mouth of the Bagaduce River, Maine, in order to understand how complex features affect the intratidal and lateral variability of turbulence and vertical mixing. The Bagaduce River is a low-inflow, macrotidal estuary that features tidal islands, tidal flats and sharp channel bends. Profiles of salinity, temperature, and turbulent kinetic energy dissipation (ε) were collected for a tidal cycle across the estuary with a microstructure profiler. Lateral distributions of current velocities were obtained with an acoustic doppler current profiler. Results showed intratidal asymmetries in bottom-generated vertical eddy diffusivity and viscosity, with larger values occurring on ebb (Kz: 10−2 m2; Az: 10−2 m2/s) compared to flood (Kz: 10−5 m2/s; Az: 10−4 m2/s). Bottom-generated mixing was moderated by the intrusion of stratified water on flood, which suppressed mixing. Elevated mixing (Kz: 10−3 m2; Az: 10−2.5 m2/s) occurred in the upper water column in the lee of a small island and was decoupled from the bottom layer. The near-surface mixing was a product of an eddy formed downstream of a headland, which tended to reinforce vertical shear by laterally straining streamwise velocities. These results are the first to show near-surface mixing caused by vertical vorticity induced by an eddy, rather than previously reported streamwise vorticity associated with lateral circulation.