The Ionic State of Molybdenum in Sulfuric Uterine Solutions of Rhenium Sorption and its Extraction

results of studies of the forms of finding and methods of extracting molybdenum from acidic solutions with a high concentration of sulfuric acid are presented. Ion-exchange resins of various modifications were tested to determine the most effective for molybdenum during its sorption from a sulfuric acid solution.

Production Techniques of Metallic Foams in Lightweight Materials

Lightweight materials were needed in many different areas, especially in order to reduce the required energy in areas such as automotive and aerospace industries. Metallic foams attract attention in lightweight material applications due to their unique properties. The pores in its structure provide advantages in many applications, both structural and functional by promising both ultra-lightweight construction, energy absorption, and damping insulation. Production techniques of metallic foams can generally be classified as liquid, solid, gas, and ionic state production according to the physical state of the metal at the beginning of the process. The production technique should be chosen according to the usage area and desired properties of the metallic foam and the suitability in terms of cost and sustainability of production. For this reason, the details of the production techniques should be known and the products that can be obtained and their properties should be understood. In this respect, this chapter emphasizes the production methods from past to present.

Ionic State of Molybdenum in Sulfuric Uterine Solutions of Rhenium Sorption and its Extraction

The results of studies of the forms of finding and methods of extracting molybdenum from acidic solutions with a high concentration of sulfuric acid are presented. Ion-exchange resins of various modifications were tested to determine the most effective for molybdenum during its sorption from a sulfuric acid solution.

Mechanisms of 1s Double-Core-Hole Excitation and Decay in Neon

The formation and decay of double-core-hole (DCH) states of the neon ion irradiated by an intense electromagnetic x-ray field are studied theoretically. In the present research DCH formation is the result of sequential absorption of two photons with the creation of an intermediate ion. Detailed calculations of the partial decays and probabilities of shake-ups at the atomic and ionic ionization stages are presented. The angular distribution of photoelectrons corresponding to various residual ionic states are calculated. Specifically, we predict the lack of any photoelectrons corresponding to the residual ionic state 1s12s22pnmpn′2Sf+1D in the direction of the electric field polarization. Dynamical competition between single-core-hole state decay and excitation is analyzed and pulse parameters corresponding to various dynamical regimes are found.

Features of the Ionic State of Indium in Perchlorate Solutions and the Physicochemical Properties of Indium Perchlorate

The possibility of the formation of India perchlorate and mixed ligand complexes has been studied. It is assumed that during the extraction of indium in aqueous solutions of hydrochloric acid at various concentrations and constant ionic strength maintained by the addition of perchloric acid, indium is present in the organic phase in the form of ionic aggregates HClO4 · HInCl4. To study the hydration of Ions, the method of electrical conductivity was carried out in the “In(ClO4)3 - HClO4 - H2O” system. The structure of aqueous solutions of India perchlorates was determined by IR spectroscopy. The structures of trivalent perchlorate India have been established.

The Catalytic Mechanisms of the Reactions between Tryptophan Indole-Lyase and Nonstandard Substrates: The Role of the Ionic State of the Catalytic Group Accepting the Cα Proton of the Substrate

In the reaction between tryptophan indole-lyase (TIL) and a substrate containing a bad leaving group (L-serine), general acid catalysis is required for the group's elimination. During this stage, the proton originally bound to the C atom of the substrate is transferred to the leaving group, which is eliminated as a water molecule. As a result, the basic group that had accepted the C proton at the previous stage has to be involved in the catalytic stage following the elimination in its basic form. On the other hand, when the substrate contains a good leaving group (-chloro-L-alanine), general acid catalysis is not needed at the elimination stage and cannot be implemented, because there are no functional groups in enzymes whose acidity is strong enough to protonate the elimination of a base as weak as Cl- anion. Consequently, the group that had accepted the C proton does not lose its additional proton during the elimination stage and should take part in the subsequent stage in its acidic (not basic) form. To shed light on the mechanistic consequences of the changes in the ionic state of this group, we have considered the pH dependencies of the main kinetic parameters for the reactions of TIL with L-serine and -chloro-L-alanine and the kinetic isotope effects brought about by replacement of the ordinary water used as a solvent with 2H2O. We have found that in the reaction between TIL and -chloro-L-alanine, the aminoacrylate hydrolysis stage is sensitive to the solvent isotope effect, while in the reaction with L-serine it is not. We have concluded that in the first reaction, the functional group containing an additional proton fulfills a definite catalytic function, whereas in the reaction with L-serine, when the additional proton is absent, the mechanism of hydrolysis of the aminoacrylate intermediate should be fundamentally different. Possible mechanisms were considered.