Deciphering the Palaeocene–Eocene thermal maximum by Granger causality test

The Palaeocene–Eocene thermal maximum is a global warming period (~ 56 Ma), which is marked by a sharp negative carbon isotope excursion (CIE) that caused by the injection of massive isotopically-light carbon into the ocean-atmosphere. It is often considered that the carbon injection caused global warming. However, several studies have suggested that warming and environmental perturbations precede the onset of the CIE. Here we present Granger test to investigate the detailed mechanisms of this event. We show a shift from climate-warming driving carbon-emission scenario to a scheme in which carbon-injection causing global-warming during the CIE. The initial carbon emission might be from methane hydrates dissociation and/or permafrost thawing, possibly linked with astronomical paced warming. This change of causal direction may result from the warming feedback of the emitted carbon and additional carbon from other sources, such as volcanism, bolide impact, oxidation of marine organic matter, and wildfires burning peatlands.

Effect of FeO Content on Foaming and Viscosity Properties in FeO-CaO-SiO2-MgO-Al2O3 Slag System

The foaming process is an important part of the electric arc furnace (EAF) steelmaking process. It can promote thermal efficiency and reduce refractory consumption. FeO is a key material used during the foaming process. Unlike with other components used in forming foaming slag, the amount of FeO can be controlled by oxygen or carbon injection. Therefore, adjusting the content of FeO is the most economical foaming mode adopted for the EAFs steelmaking process. In this study, the influence of FeO content on the physical properties of slag was discussed. The melting temperature of the slag was evaluated using three methods: viscosity experiment, using Thermo-Calc simulation software, and high-temperature optical method. The experimental results revealed that the viscosity of slag increases as FeO content decreases. The results also revealed that foam height ratio exhibited a positive correlation with the viscosity of slag.

Hydrate Plugging and Flow Remediation during CO2 Injection in Sediments

Successful geological sequestration of carbon depends strongly on reservoir seal integrity and storage capacity, including CO2 injection efficiency. Formation of solid hydrates in the near-wellbore area during CO2 injection can cause permeability impairment and, eventually, injectivity loss. In this study, flow remediation in hydrate-plugged sandstone was assessed as function of hydrate morphology and saturation. CO2 and CH4 hydrates formed consistently at elevated pressures and low temperatures, reflecting gas-invaded zones containing residual brine near the injection well. Flow remediation by methanol injection benefited from miscibility with water; the methanol solution contacted and dissociated CO2 hydrates via liquid water channels. Injection of N2 gas did not result in flow remediation of non-porous CO2 and CH4 hydrates, likely due to insufficient gas permeability. In contrast, N2 as a thermodynamic inhibitor dissociated porous CH4 hydrates at lower hydrate saturations (<0.48 frac.). Core-scale thermal stimulation proved to be the most efficient remediation method for near-zero permeability conditions. However, once thermal stimulation ended and pure CO2 injection recommenced at hydrate-forming conditions, secondary hydrate formation occurred aggressively due to the memory effect. Field-specific remediation methods must be included in the well design to avoid key operational challenges during carbon injection and storage.

Marine nitrogen fixers mediate a low latitude pathway for atmospheric CO2 drawdown

Roughly a third (~30 ppm) of the carbon dioxide (CO2) that entered the ocean during ice ages is attributed to biological mechanisms. A leading hypothesis for the biological drawdown of CO2 is iron (Fe) fertilisation of the high latitudes, but modelling efforts attribute at most 10 ppm to this mechanism, leaving ~20 ppm unexplained. We show that an Fe-induced stimulation of dinitrogen (N2) fixation can induce a low latitude drawdown of 7–16 ppm CO2. This mechanism involves a closer coupling between N2 fixers and denitrifiers that alleviates widespread nitrate limitation. Consequently, phosphate utilisation and carbon export increase near upwelling zones, causing deoxygenation and deeper carbon injection. Furthermore, this low latitude mechanism reproduces the regional patterns of organic δ15N deposited in glacial sediments. The positive response of marine N2 fixation to dusty ice age conditions, first proposed twenty years ago, therefore compliments high latitude changes to amplify CO2 drawdown.