Topological phase transition in cavity optomechanical system with periodical modulation

We investigate the topological phase transition and the enhanced topological effect in cavity optomechanical system with periodical modulation. By calculating the steady-state equations of the system, the steady-state conditions of cavity fields and the restricted conditions of effective optomechanical couplings are demonstrated. It is found that the cavity optomechanical system can be modulated to different topological Su-Schrieffer-Heeger (SSH) phases via designing the optomechanical couplings legitimately. Meanwhile, combining the effective optomechanical couplings and the probability distributions of gap states, we reveal the topological phase transition between trivial SSH phase and nontrivial SSH phase via adjusting the decay rates of cavity fields. Moreover, we find that the enhanced topological effect of gap states can be achieved by enlarging the size of system and adjusting the decay rates of cavity fields.

Majorana zero modes induced by superconducting phase bias

Majorana zero modes in condensed matter systems have been the subject of much interest in recent years. Their non-Abelian exchange statistics, making them a unique state of matter, and their potential applications in topological quantum computation, earned them attention from both theorists and experimentalists. It is generally understood that in order to form Majorana zero modes in quasi-one-dimensional topological insulators, time-reversal symmetry must be broken. The straightforward mechanisms for doing so—applying magnetic fields or coupling to ferromagnets—turned out to have many unwanted side effects, such as degradation of superconductivity and the formation of sub-gap states, which is part of the reason Majorana zero modes have been eluding direct experimental detection for a long time. Here we review several proposal that rely on controlling the phase of the superconducting order parameter, either as the sole mechanism for time-reversal-symmetry breaking, or as an additional handy knob used to reduce the applied magnetic field. These proposals hold practical promise to improve Majorana detection, and they shed light on the physics underlying the formation of the topological superconducting state.

An Experimental and Theoretical Study on the Effect of Silver Nanoparticles Concentration on the Structural, Morphological, Optical, and Electronic Properties of TiO2 Nanocrystals

In this work, pure and silver (Ag)-loaded TiO2 nanocrystals (NCs) with various concentrations of Ag were prepared by soft chemical route and the effect of Ag nanoparticles (NPs) on the functional properties of TiO2 was studied. X-ray diffraction (XRD) and Raman studies confirmed that the synthesized product had single-phase nature and high crystalline quality. The crystallite size was decreased from 18.3 nm to 13.9 nm with the increasing in concentration of Ag in TiO2 NCs. FESEM micrographs showed that the pure and AgNPs-loaded TiO2 have spherical morphology and uniform size distribution with the size ranging from 20 to 10 nm. Raman spectroscopy performed on pure and AgNPs-loaded TiO2 confirms the presence of anatase phase and AgNPs. Optical properties show the characteristics peaks of TiO2 and the shifting of the peaks position was observed by changing the concentration of Ag. The tuning of bandgap was found to be observed with the increase in Ag, which could be ascribed to the synergistic effect between silver and TiO2 NCs. Density functional theory calculations are carried out for different Ag series of doped TiO2 lattices to simulate the structural and electronic properties. The analysis of the electronic structures show that Ag loading induces new localized gap states around the Fermi level. Moreover, the introduction of dopant states in the gap region owing to Ag doping can be convenient to shift the absorption edge of pristine TiO2 through visible light.

A Metastable p-Type Semiconductor as a Defect-Tolerant Photoelectrode

A p-type Cu3Ta7O19 semiconductor was synthesized using a CuCl flux-based approach and investigated for its crystalline structure and photoelectrochemical properties. The semiconductor was found to be metastable, i.e., thermodynamically unstable, and to slowly oxidize at its surfaces upon heating in air, yielding CuO as nano-sized islands. However, the bulk crystalline structure was maintained, with up to 50% Cu(I)-vacancies and a concomitant oxidation of the Cu(I) to Cu(II) cations within the structure. Thermogravimetric and magnetic susceptibility measurements showed the formation of increasing amounts of Cu(II) cations, according to the following reaction: Cu3Ta7O19 + x/2 O2 → Cu(3−x)Ta7O19 + x CuO (surface) (x = 0 to ~0.8). With minor amounts of surface oxidation, the cathodic photocurrents of the polycrystalline films increase significantly, from <0.1 mA cm−2 up to >0.5 mA cm−2, under visible-light irradiation (pH = 6.3; irradiant powder density of ~500 mW cm−2) at an applied bias of −0.6 V vs. SCE. Electronic structure calculations revealed that its defect tolerance arises from the antibonding nature of its valence band edge, with the formation of defect states in resonance with the valence band, rather than as mid-gap states that function as recombination centers. Thus, the metastable Cu(I)-containing semiconductor was demonstrated to possess a high defect tolerance, which facilitates its high cathodic photocurrents.

Synergetic modulation of surface alkali and oxygen vacancy over SrTiO3 for the CO2 photodissociation

Photochemical conversion of CO2 into solar fuels is one of the promising strategies to reducing the CO2 emission and developing a sustainable carbon economy. For the more efficient utilization of solar spectrum, several approaches were adopted to pursue the visible-light-driven SrTiO3. Herein, oxygen vacancy was introduced over the commercial SrTiO3 (SrTiO3-x) via the NaBH4 thermal treatment, to extend the light absorption and promote the CO2 adsorption over SrTiO3. Due to the mid-gap states resulted from the oxygen deficiency, combined with the intrinsic energy level of SrTiO3, the SrTiO3-x catalyst exhibited excellent CO productivity (4.1 molˑg-1ˑh-1) and stability from the CO2 photodissociation under the visible-light irradiation (λ > 400 nm). Then, surface alkalization over SrTiO3-x (OH-SrTiO3−x) was carried out to further enhance the CO2 adsorption/activation over the surface base sites and provide the OH ions as hole acceptor, the surface alkali OH connected with Sr site of SrTiO3 could also weaken the Sr-O bonding thus facilitate the regeneration of surface oxygen vacancy under the light illumination, thus resulting in 1.5 times higher CO productivity additionally. This study demonstrates that the synergetic modulation of alkali OH and oxygen vacancy over SrTiO3 could largely promote the CO2 photodissociation activity.