Performance of any sensor in a nuclear reactor involves reliable operation under a harsh environment
(i.e., high temperature, neutron irradiation, and a high dose of ionizing radiation). In this environment,
accurate and continuous monitoring of temperature is critical for the reactor's stability and proper functionality.
Furthermore, during the development and testing stages of new materials and structural components for these systems,
it is imperative to collect in-situ measurement data about the exact test conditions for real-time analysis of their
performance. To meet the compelling need of such sensing devices, we propose radiation-hard temperature sensors based
on the phase change phenomenon of chalcogenide glasses. The primary goal is to resolve the monitoring of the cladding
temperature of light water and metallic or ceramic sodium-cooled fast reactors within a temperature range of 400°C to
600°C. This work is focused on studies of Ge-Se(S) chalcogenide glasses that have crystallization temperatures in this
range. Each chalcogenide glass transforms and becomes crystalline at a specific heating rate at a definite temperature.
As a result of this, both the electrical resistance and optical properties of the materials change. As this is the first
time such devices have been fabricated, this work submits new data regarding materials research, various device
structures, fabrication, performance, and testing under irradiation. The application of these materials in devices
usually involves the formation of a thin film that works as an active layer. Traditionally, thin films are prepared by
thermal evaporation, sputtering or chemical vapor deposition and they require high vacuum machinery and patterning
applying photolithography. To avoid using such heavy machinery and costly fabrication processes, we investigate the
formulation of nanoparticle inks of chalcogenide glasses, the formation of printed thin films using the inks, low-cost
sintering and demonstrate their application in electronic and photonic sensors utilizing their phase transition effects.
The printed chalcogenide glass films showed similar structural, electronic and optical properties as the thermally
evaporated films. The newly developed process steps reported in this work describe chalcogenide glasses nanoparticle
inks formulation, their application by inkjet printing and dip-coating methods and sintering to fabricate phase change
temperature sensors. To interpret and predict the printed films' performance, Raman spectroscopy, X-ray Diffraction
Spectroscopy, Energy Dispersion Spectroscopy, Atom Force Microscopy, temperature dependent Ellipsometry, and other
methods are used. An essential part of materials' behavior is related to the materials' and devices' response to ion
beam irradiation. Both experimental data and simulation are analyzed to study the effect of irradiation. Based on the
different working principles, electrical, optical and plasmonic temperature sensors are investigated. An array of
optical fiber devices fabricated with different chalcogenide glasses is shown to perform a real-time temperature reading.
This work could be used as a paradigm for sensor fabrication and testing for high radiation environments and nanoparticle
inks of chalcogenide glasses formulation and their application by inkjet printing and dip-coating. The most novel outcome
of this work adds chalcogenide glasses to the list of inkjet printable materials, thus opening up an opportunity to
achieve arbitrary structures for optical and electronic applications without photolithography.
Phase Change Temperature Sensor for High Radiation Environment
