Effect of Vulcanization and CO2 Plasticization on Cell Morphology of Silicone Rubber in Temperature Rise Foaming Process

Both vulcanization reaction and CO2 plasticization play key roles in the temperature rise foaming process of silicone rubber. The chosen methyl-vinyl silicone rubber system with a pre-vulcanization degree of 36% had proper crosslinked networks, which not only could ensure enough polymer matrix strength to avoid bubble rupture but also had enough dissolved CO2 content in silicone rubber for induced bubble nucleation. The CO2 diffusion and further vulcanization reaction occur simultaneously in the CO2 plasticized polymer during bubble nucleation and growth. The dissolved CO2 in the pre-vulcanized silicone rubber caused a temperature delay to start while accelerating further vulcanization reactions, but the lower viscoelasticity caused by either CO2 plasticization or fewer crosslinking networks was still the dominating factor for larger cell formation. There was a sudden increase in elastic modulus and complex viscosity for pre-vulcanized silicone rubbers at higher temperature because of the occurrence of further vulcanization, but CO2 plasticization reduced the scope of change of rheological properties, and the loss factor was close to 1 around 170 °C, which is corresponding to the optimum foaming temperature. The foamed silicone rubber had a higher cell density and smaller cell size at a higher temperature rising rate, which is due to higher CO2 supersaturation and faster vulcanization reaction. These results provide some insight into the coupling mode and effect of CO2 plasticization and vulcanization for regulating cell structure in foaming silicone rubber process.

What Antarctic Plants Can Tell Us about Climate Changes: Temperature as a Driver for Metabolic Reprogramming

Global warming is strongly affecting the maritime Antarctica climate and the consequent melting of perennial snow and ice covers resulted in increased colonization by plants. Colobanthus quitensis is a vascular plant highly adapted to the harsh environmental conditions of Antarctic Peninsula and understanding how the plant is responding to global warming is a new challenging target for modern cell physiology. To this aim, we performed differential proteomic analysis on C. quitensis plants grown in natural conditions compared to plants grown for one year inside open top chambers (OTCs) which determine an increase of about 4 °C at midday, mimicking the effect of global warming. A thorough analysis of the up- and downregulated proteins highlighted an extensive metabolism reprogramming leading to enhanced photoprotection and oxidative stress control as well as reduced content of cell wall components. Overall, OTCs growth seems to be advantageous for C. quitensis plants which could benefit from a better CO2 diffusion into the mesophyll and a reduced ROS-mediated photodamage.