Photo-controlled self-assembly behavior of novel amphiphilic polymers with rosin-based azobenzene group

Novel ‘bola’ rosin-based photo-responsive amphiphilic polymers PMPn (n=17, 34, 69) were synthesized using polyethyleneglycol (PEG) as a double hydrophilic head and N-azobenzenemaleimidepimaric (AZOMPA) as a hydrophobic tail. The relatively fixed...

Influence of Chromophoric Electron-Donating Groups on Photoinduced Solid-to-Liquid Transitions of Azopolymers

The photoinduced solid-to-liquid transitions property of azobenzene-containing polymers (azopolymers) enables azopolymers with various promising applications. However, a general lack of knowledge regarding the influence of structure of the azobenzene derivatives on the photoinduced liquefaction hinders the design of novel azopolymers. In the present study, a series of azopolymers with side chains containing azobenzene unit bearing alkyl electron-donating groups were synthesized. The photoisomerization and photoinduced liquefaction properties of newly synthesized azopolymers were investigated. Alkyl-based electron-donating group significantly facilitate the photoisomerization process of azopolymers in solution, as the electron-donating ability of substituents increased, the time required for photoisomerization of azopolymers continually deceased. Meanwhile, the electron-donating group can drastically accelerate photoinduced solid-to-liquid transitions of azopolymers, the liquefaction rate of obtained azopolymers gradually getting quicker as the electron-donating ability of substituents increased. This study clearly demonstrates that the electron-donating group that bearing in the azobenzene group of polymer side chain play an essential role on the photoinduced solid-to-liquid transitions of azopolymers, and hence, gives an insight into how to design novel azopolymers for practical applications.

Photoswitchable dynasore analogs to control endocytosis with light

We've combined the pharmacological properties of the dynamin inhibitor dynasore and the photochromic properties of an azobenzene group, to obtain the first light-regulated small-molecule inhibitor of endocytosis.

Photoinduced Reversible Bending and Guest Molecule Release of Azobenzene-Containing Polydiacetylene Nanotubes

Creation of hollow, one-dimensional nanomaterials has gained great recent attention in the chemical and material sciences. In a study aimed at discovering new functional materials of this type, we observed that an amphiphilic diacetylene (DA) derivative, containing an azobenzene moiety and an oligo-ethylene group, self-assembles to form nanotubes and undergoes photopolymerization to form hollow polydiacetylene (PDA) nanotubes with a uniform wall thickness and diameter. The azobenzene-PDA nanotubes are photoresponsive in that on-and-off UV-irradiation leads to a reversible morphological change between straight and bent forms in association with E-Z photoisomerization of the azobenzene group. Owing to the UV-induced structural change feature, the new DA and PDA nanotubes serve as a controlled release material. Accordingly, fluorescent rhodamine B encapsulated inside the nanotubes are effectively released by using repeated on-off UV irradiation. Furthermore, photo-release of rhodamine B was shown to occur in an artemia (brine shrimp).

Photo-isomerization and light-modulated aggregation behavior of azobenzene-based ionic liquids in aqueous solutions

ILs with an azobenzene-group at the end of the alkyl chain could form micelles; UV/vis irradiation only changed the size of the aggregates.