scholarly journals Influence of Chromophoric Electron-Donating Groups on Photoinduced Solid-to-Liquid Transitions of Azopolymers

Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 901 ◽  
Author(s):  
Jian Xu ◽  
Bin Niu ◽  
Song Guo ◽  
Xiaolei Zhao ◽  
Xiaoli Li ◽  
...  
Keyword(s):  
Essential Role ◽  
Side Chain ◽  
Practical Applications ◽  
General Lack ◽  
Azobenzene Group ◽  
Time Required ◽  
Electron Donating Groups ◽  
Azobenzene Derivatives ◽  
Insight Into ◽  
Photoisomerization Process

The photoinduced solid-to-liquid transitions property of azobenzene-containing polymers (azopolymers) enables azopolymers with various promising applications. However, a general lack of knowledge regarding the influence of structure of the azobenzene derivatives on the photoinduced liquefaction hinders the design of novel azopolymers. In the present study, a series of azopolymers with side chains containing azobenzene unit bearing alkyl electron-donating groups were synthesized. The photoisomerization and photoinduced liquefaction properties of newly synthesized azopolymers were investigated. Alkyl-based electron-donating group significantly facilitate the photoisomerization process of azopolymers in solution, as the electron-donating ability of substituents increased, the time required for photoisomerization of azopolymers continually deceased. Meanwhile, the electron-donating group can drastically accelerate photoinduced solid-to-liquid transitions of azopolymers, the liquefaction rate of obtained azopolymers gradually getting quicker as the electron-donating ability of substituents increased. This study clearly demonstrates that the electron-donating group that bearing in the azobenzene group of polymer side chain play an essential role on the photoinduced solid-to-liquid transitions of azopolymers, and hence, gives an insight into how to design novel azopolymers for practical applications.

scholarly journals The structure of an archaeal oligosaccharyltransferase provides insight into the strict exclusion of proline from the N-glycosylation sequon

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Yuya Taguchi ◽  
Takahiro Yamasaki ◽  
Marie Ishikawa ◽  
Yuki Kawasaki ◽  
Ryuji Yukimura ◽  
...  
Keyword(s):  
Essential Role ◽  
Ring Structure ◽  
Structural Basis ◽  
Side Chain ◽  
Ramachandran Plot ◽  
Amino Acid Motif ◽  
External Loop ◽  
Backbone Dihedral Angle ◽  
Insight Into

AbstractOligosaccharyltransferase (OST) catalyzes oligosaccharide transfer to the Asn residue in the N-glycosylation sequon, Asn-X-Ser/Thr, where Pro is strictly excluded at position X. Considering the unique structural properties of proline, this exclusion may not be surprising, but the structural basis for the rejection of Pro residues should be explained explicitly. Here we determined the crystal structure of an archaeal OST in a complex with a sequon-containing peptide and dolichol-phosphate to a 2.7 Å resolution. The sequon part in the peptide forms two inter-chain hydrogen bonds with a conserved amino acid motif, TIXE. We confirmed the essential role of the TIXE motif and the adjacent regions by extensive alanine-scanning of the external loop 5. A Ramachandran plot revealed that the ring structure of the Pro side chain is incompatible with the ϕ backbone dihedral angle around −150° in the rigid sequon-TIXE structure. The present structure clearly provides the structural basis for the exclusion of Pro residues from the N-glycosylation sequon.

Insight into the practical models for prediciting the essential role of the cytochrome P450-mediated biotransformation in emodin-associated hepatotoxicity

Toxicology ◽  
2021 ◽  
Vol 462 ◽  
pp. 152930
Author(s):  
Tingting Zhang ◽  
Xiaomei He ◽  
Lanlan Sun ◽  
Dong Wang ◽  
Shuya Zhang ◽  
...  
Keyword(s):  
Cytochrome P450 ◽  
Essential Role ◽  
Insight Into

A computational insight into the relationship between side chain IR line shapes and local environment in fibril-like structures

2021 ◽  
Vol 154 (8) ◽  
pp. 084105
Author(s):  
Sandra M. V. Pinto ◽  
Nicola Tasinato ◽  
Vincenzo Barone ◽  
Laura Zanetti-Polzi ◽  
Isabella Daidone
Keyword(s):  
Local Environment ◽  
Side Chain ◽  
Line Shapes ◽  
The Relationship ◽  
Insight Into

Market Opportunity Analysis in Thailand: Case of Individual Power Sources by Thermoelectric-Generator Technology for Portable Electronics

2019 ◽  
Vol 16 (03) ◽  
pp. 1950027
Author(s):  
Surapree Maolikul ◽  
Thira Chavarnakul ◽  
Somchai Kiatgamolchai
Keyword(s):  
Thermoelectric Generator ◽  
Electrical Power ◽  
Technology Commercialization ◽  
Market Opportunity ◽  
Business Research ◽  
Power Sources ◽  
Practical Applications ◽  
Portable Electronics ◽  
Decision Factors ◽  
Insight Into

Thermoelectrics, an energy-conversion technology, has been developed for its potential to support portable electronics with an innovative power source. Primarily focusing on the metropolitan market in Thailand, the study, thus, aimed at the market insight into portable electronics users’ characteristics and opinions of thermoelectric-generator (TEG) technology commercialization. The business research was conducted to analyze their behaviors for power-supply lacking problems, encountering heat or cold sources, purchasing decision for a TEG-based charger and key decision factors. For practical applications, an innovative TEG-based charger should be more flexible by harnessing various heat or cold sources from ambient situations to generate electrical power.

scholarly journals Corrigendum: Solid-State NMR Measurements of Asymmetric Dipolar Couplings Provide Insight into Protein Side-Chain Motion

2012 ◽  
Vol 51 (40) ◽  
pp. 9959-9959
Author(s):  
Paul Schanda ◽  
Matthias Huber ◽  
Jérôme Boisbouvier ◽  
Beat H. Meier ◽  
Matthias Ernst
Keyword(s):  
Solid State ◽  
Solid State Nmr ◽  
Dipolar Couplings ◽  
Side Chain ◽  
Side Chain Motion ◽  
Insight Into

Improving Techniques in Statically Equivalent Serial Chain Modeling for Center of Mass Estimation

2014 ◽  
Author(s):  
Bingjue Li ◽  
Andrew P. Murray ◽  
David H. Myszka
Keyword(s):  
Center Of Mass ◽  
Original System ◽  
Rigid Bodies ◽  
Joint Angles ◽  
Practical Applications ◽  
Serial Chain ◽  
System Of Rigid Bodies ◽  
Final Development ◽  
Data Error ◽  
Insight Into

Any articulated system of rigid bodies defines a Statically Equivalent Serial Chain (SESC). The SESC is a virtual chain that terminates at the center of mass (CoM) of the original system of bodies. A SESC may be generated experimentally without knowing the mass, CoM, or length of each link in the system given that its joint angles and overall CoM may be measured. This paper presents three developments toward recognizing the SESC as a practical modeling technique. Two of the three developments improve utilizing the technique in practical applications where the arrangement of the joints impacts the derivation of the SESC. The final development provides insight into the number of poses needed to create a usable SESC in the presence of data collection errors. First, modifications to a matrix necessary in computing the SESC are proposed. Second, the problem of generating a SESC experimentally when the system of bodies includes a mass fixed in the ground frame are presented and a remedy is proposed for humanoid-like systems. Third, an investigation of the error of the experimental SESC versus the number of data readings collected in the presence of errors in joint readings and CoM data is conducted. By conducting the method on three different systems with various levels of data error, a general form of the function for estimating the error of the experimental SESC is proposed.

scholarly journals Structure of a Talaromyces pinophilus GH62 arabinofuranosidase in complex with AraDNJ at 1.25 Å resolution

2018 ◽  
Vol 74 (8) ◽  
pp. 490-495 ◽  
Author(s):  
Olga V. Moroz ◽  
Lukasz F. Sobala ◽  
Elena Blagova ◽  
Travis Coyle ◽  
Wei Peng ◽  
...  
Keyword(s):  
Plant Biomass ◽  
Cellulosic Biomass ◽  
Structural Basis ◽  
Side Chain ◽  
Polymeric Substrates ◽  
Hydrolysis Of ◽  
Insight Into ◽  
Positively Charged ◽  
Talaromyces Pinophilus ◽  
Resolution Structure

The enzymatic hydrolysis of complex plant biomass is a major societal goal of the 21st century in order to deliver renewable energy from nonpetroleum and nonfood sources. One of the major problems in many industrial processes, including the production of second-generation biofuels from lignocellulose, is the presence of `hemicelluloses' such as xylans which block access to the cellulosic biomass. Xylans, with a polymeric β-1,4-xylose backbone, are frequently decorated with acetyl, glucuronyl and arabinofuranosyl `side-chain' substituents, all of which need to be removed for complete degradation of the xylan. As such, there is interest in side-chain-cleaving enzymes and their action on polymeric substrates. Here, the 1.25 Å resolution structure of the Talaromyces pinophilus arabinofuranosidase in complex with the inhibitor AraDNJ, which binds with a K d of 24 ± 0.4 µM, is reported. Positively charged iminosugars are generally considered to be potent inhibitors of retaining glycosidases by virtue of their ability to interact with both acid/base and nucleophilic carboxylates. Here, AraDNJ shows good inhibition of an inverting enzyme, allowing further insight into the structural basis for arabinoxylan recognition and degradation.

Molecular design and crystallization process control for thin sheet-shaped organic semiconductor crystals with two-dimensional packing

2021 ◽  
Author(s):  
Yuejuan Wan ◽  
Zejian Zhang ◽  
Haichao Liu ◽  
Jiadong Zhou ◽  
Liqun Liu ◽  
...  
Keyword(s):  
Organic Semiconductor ◽  
Essential Role ◽  
Crystallization Process ◽  
Molecular Design ◽  
Thin Sheet ◽  
Optoelectronic Devices ◽  
Two Dimensional ◽  
High Property ◽  
Practical Applications ◽  
Semiconductor Crystals

The sheet-liked organic semiconductor crystals with two-dimensional (2D) packed structures play an essential role in practical applications of high-property optoelectronic devices. Here, we reported a practical example in combination with...

The Temporal and the Eternal

2005 ◽  
pp. 611-636
Keyword(s):  
Rational Decision ◽  
Practical Applications ◽  
The World ◽  
The Universe ◽  
Insight Into

This chapter, taken from Josiah Royce's Gifford Lectures of 1899, argues that any rational decision as between a pessimistic and an optimistic view of the world, any account of the relations between God and Man, any view of the sense in which the evils and imperfections of the Universe can be comprehended or justified, any account of our ethical consciousness in terms reconcilable with our Idealism must turn in part upon a distinction between the Temporal and the Eternal, and upon an insight into their unity in the midst of their contrast. The problem at issue is one of the most delicate and, at the same time, one of the simplest of the great issues of philosophy. The chapter deals with it at first in a purely theoretical fashion and then proceeds to its practical applications.

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