Низкотемпературная фотолюминесценция монослоя WSe-=SUB=-2-=/SUB=-, полученного механическим слоением с использованием золота

We studied the optical properties of an atomically thin WSe$_2$ film obtained by gold-assisted mechanical exfoliation. Raman scattering spectra, low-temperature photoluminescence, and micro-reflection from large-scale monolayer are investigated. At room temperature, the optical properties of such a film reproduce the properties of WSe$_2$ monolayers obtained by regular mechanical exfoliation. It is shown that at low temperatures, the radiation spectra of the resulting film are determined by standard mechanisms of radiative recombination involving free excitons, bound excitons, and trions. However, in contrast to room temperatures, there is a significant difference in the spectral width and intensity of the lines compared to monolayers WSe$_2$, obtained regular way from the same source material. The differences found, demonstrating a significant increase in background doping and structural disorder when using gold-assisted exfoliation, may be meaningful for a number of optoelectronic applications of atomically thin WSe$_2$ films.

A Simple Model of Radiation from a Magnetized Neutron Star: Accreted Matter and Polar Hotspots

A simple and well known model for thermal radiation spectra from a magnetized neutron star is further studied. The model assumes that the star is internally isothermal and possesses a dipole magnetic field (B≲1014 G) in the outer heat-insulating layer. The heat transport through this layer makes the surface temperature distribution anisotropic; any local surface element is assumed to emit a blackbody (BB) radiation with a local effective temperature. It is shown that this thermal emission is nearly independent of the chemical composition of insulating envelope (at the same taken averaged effective surface temperature). Adding a slight extra heating of magnetic poles allows one to be qualitatively consistent with observations of some isolated neutron stars.

Enhancing MAX-DOAS atmospheric state retrievals by multispectral polarimetry – studies using synthetic data

Ground-based Multi-AXis Differential Optical Absorption Spectroscopy (MAX-DOAS) is a widely-used measurement technique for the remote detection of atmospheric aerosol and trace gases. The technique relies on the analysis ultra-violet and visible radiation spectra of scattered sunlight (skylight) to obtain information on different atmospheric parameters. From an appropriate set of spectra recorded under different viewing directions (typically a group of observations at different elevation angles) the retrieval of aerosol and trace gas vertical distributions is achieved through numerical inversion methods. It is well known that the polarisation state of skylight is particularly sensitive to atmospheric aerosol content as well as aerosol properties, and that polarimetric measurement could therefore provide additional information for MAX-DOAS profile retrievals; however such measurement have not yet been used for this purpose. To address this issue, we have developed the RAPSODI (Retrieval of Atmospheric Parameters from Spectroscopic Observations using DOAS Instruments) algorithm. In contrast to existing MAX-DOAS algorithms, it can process polarimetric information, and it can retrieve simultaneously profiles of aerosols and various trace gases at multiple wavelengths in a single retrieval step; a further advantage is that it contains a Mie scattering model, allowing for the retrieval aerosol microphysical properties. The forward model component in RAPSODI is based on a linearized vector radiative transfer model with Jacobian facilities, and we have used this model to create a data base of synthetic measurements in order to carry out sensitivity analyses aimed at assessing the potential of polarimetric MAX-DOAS observations. We find that multispectral polarimetry significantly enhances the sensitivity, particularly to aerosol related quantities. Assuming typical viewing geometries, the degree of freedom for signal (DFS) increases by about 50 % and 70 % for aerosol vertical distributions and aerosol properties, respectively, and by approximately 10 % for trace gas vertical profiles. For an idealised scenario with a horizontally homogeneous atmosphere, our findings predict an improvement in the inversions results' accuracy (root-mean-square deviations to the true values) of about 60 % for aerosol VCDs as well as for aerosol surface concentrations, and by 40 % for aerosol properties. For trace gas VCDs, very little improvement is apparent, although the accuracy of trace gas surface concentrations improves by about 50 %.

Analog Particle Production Model for General Classes of Taub-NUT Black Holes

We derive a correspondence between the Hawking radiation spectra emitted from general classes of Taub-NUT black holes with that induced by the relativistic motion of an accelerated Dirichlet boundary condition (i.e., a perfectly reflecting mirror) in (1+1)-dimensional flat spacetime. We demonstrate that the particle and energy spectra is thermal at late times and that particle production is suppressed by the NUT parameter. We also compute the radiation spectrum in the rotating, electrically charged (Kerr–Newman) Taub-NUT scenario, and the extremal case, showing, explicitly, how these parameters affect the outgoing particle and energy fluxes.

Methods of Measuring Radiation Spectra in a Laboratory Workshop on Physics and Research

The authors single out the formation of research skills as one of the most important aspects of teaching students of higher educational institutions in the areas of engineering and technical profile. As part of a laboratory workshop in physics, students acquire professional skills in research and technological fields. In this paper, we consider the method of measuring the radiation spectra of various light sources, which the authors propose to use when setting up laboratory work in physics. The conditions of the experiment are described and the scheme of the working installation is given. Measurements of the radiation spectra are carried out using a monochromator and a photodetector pre-graded in terms of transmission and spectral sensitivity.Examples of the emission spectra of a green LED, a red semiconductor laser and a fluorescent lamp measured by the considered method are given. Recommendations of such experiments are given when conducting laboratory work and research work of students. The proposed method of performing laboratory research will help students acquire skills in working with spectral measuring equipment, teach them not only to measure and build the emission spectra of light sources, but also to calculate the spectral width of the gap at which the spectra were measured and to estimate measurement errors.

Inorganic Composites Luminophors in Lithium-Borate Glasses with Rare-Earth Elements for White-Emitting Diodes

The paper describes the synthesis of novel luminescent composite system, based on lithium-borate glass matrix with addition of rare-earth elements and yttrium-aluminum garnet finely divided powder. The new chemical composition of glass has been selected, composite’s fabrication technology was developed, the temperature conditions of glass and luminophore sintering as well. The spectral characteristics of the obtained luminescent composites are measured, and chromaticity diagrams are considered. The radiation spectra showed a maximum of about 560 nm, the maximum spectral intensity of the radiation is about 90 μw/cm2/nm. Powerful energy saving source of white light was produced.

Measurements of CFC-11, CFC-12, and HCFC-22 total columns in the atmosphere at the St. Petersburg site in 2009–2019

Monitoring atmospheric anthropogenic halocarbons plays an important role in tracking their atmospheric concentrations in accordance with international agreements on emissions of ozone-depleting substances and, thus, in estimating the ozone layer recovery. Within the Network for the Detection of Atmospheric Composition Change (NDACC), regular Fourier transform infrared (FTIR) measurements can provide information on the abundancies of halocarbons on a global scale. We improved retrieval strategies for deriving the CFC-11 (CCl3F), CFC-12 (CCl2F2), and HCFC-22 (CHClF2) atmospheric columns from IR solar radiation spectra measured by the Bruker IFS125HR spectrometer at the St. Petersburg site (Russia). We used the Tikhonov–Phillips regularization approach for solving the inverse problem with optimized values of regularization parameters. We tested the strategies developed by comparison of the FTIR measurements with independent data. The analysis of the time series of column-averaged dry air mole fractions (Xgas) measured in 2009–2019 gives mean values of 225 pptv (parts per trillion by volume; CFC-11), 493 pptv (CFC-12), and 238 pptv (HCFC-22). Trend values total −0.40 % yr−1 (CFC-11), −0.49 % yr−1 (CFC-12), and 2.12 % yr−1 (HCFC-22). We compared the means, trends, and seasonal variability in XCFC-11, XCFC-12, and XHCFC-22 to that of (1) near-ground volume mixing ratios (VMRs), measured at the observational site Mace Head, Ireland (GVMR), (2) the mean in the 8–12 km layer VMRs, measured by ACE-FTS and averaged over 55–65∘ N latitudes (SVMR), and (3) Xgas values of the Whole Atmosphere Community Climate Model (WACCM) for the St. Petersburg site (WXgas). In general, the comparison of Xgas with the independent data showed a good agreement of their means within the systematic errors of the measurements considered. The trends observed over the St. Petersburg site demonstrate the smaller decrease rates for XCFC-11 and XCFC-12 than that of the independent data and the same increase rate for XHCFC-22. As a whole, Xgas, SVMR, and WXgas showed qualitatively similar seasonal variations, while the GVMR variability is significantly less, and only the WXHCFC-22 variations are essentially smaller than that of XHCFC-22 and SVMRHCFC-22.