Abstract
Completed separation of water and solute is pursued as the ultimate goal of water treatment, for maximized resource recycling. However, commercialized approaches such as evaporative crystallizers consume a large amount of electricity with significant carbon footprint, which calls for energy-efficient and eco-friendly strategies. Here inspired by schooling fish, we demonstrate a collective system self-assembled by the expanded polystyrene (EPS)-core/Graphene oxide (GO)-shell particles, which enables autonomous, efficient, and complete water-solute separation powered by sunlight. By taking advantage of surface tension, these tailored particles school together naturally and are bonded as a system to function collectively and coordinatively, to nucleate, grow and output salt crystals continuously and automatically out of even saturated brine, till the complete water-solute separation. Solar-vapor conversion efficiency over 90% and salt production rate as high as 0.39 kg m–2 h–1 are achieved under 1-sun illumination for this system. It reduces the carbon footprint of ∼50 kg for treating 1 ton saturated brine compared with the commercialized approaches.