Sustainable Synthesis of Vinyl Methyl Ether from Biomass-derived Ethylene Glycol Dimethyl Ether over Solid Base Catalysts

Vinyl methyl ether (VME) is an important chemical intermediate for the production of functional polymers and fine chemicals. It is primarily produced in industry via the addition of methanol to...

Poly(ethylene glycol) dimethyl ether mediated oxidative scission of aromatic olefins to carbonyl compounds by molecular oxygen

A simple and practical O2 oxidized scission of monosubstituted, gem- and 1,2-disubstituted, trisubstituted and tetrasubstituted aromatic olefins to aldehydes and ketones in PEGDME has been developed.

Synthesis and Use of Zwitterion Bearing Sulfonyl(trifluoromethane sylfonyl)imide Anion as Additive for Polymer Electrolytes

In order to improve the electrochemical properties of poly(ethylene oxide), a well-known-solid polymer electrolyte, by adding zwitterion molecules, the synthesis of a new zwitterion (ZN) having imidazolium cation and sulfonyl(trifluoromethane sulfonyl)imide anion is investigated. The addition of different amounts of ZN to the mixture of lithium bis(trifluoromethane sulfonyl)imide (LiTFSI) and poly(ethylene glycol)dimethyl ether (PEGDM) of 1000 g mol−1 does not significantly affect the transition temperature of PEGDM but causes a slight decrease in ionic conductivity of the electrolyte mixtures. However, even with the presence of only 0.05 mole fraction of ZN, the anodic stability of LiTFSI/PEGDM based electrolytes is improved to over 4.5 V vs. Li+/Li at 25 °C. This makes the new synthesized zwitterion a promising electrolyte’s additive for high voltage batteries.

Influence of various cosolvents on the calcium oxide-catalyzed ethanolysis of sunflower oil

Ten organic solvents (triethanolamine, diethanolamine, ethylene glycol, methyl ethyl ketone, n-hexane, triethylamine, ethylene glycol dimethyl ether, glycerol, tetrahydrofuran and dioxane) were applied as cosolvents in the CaO-catalyzed ethanolysis of sunflower oil performed in a batch stirred reactor under the following reaction conditions: temperature 70 ?C, ethanol-to-oil mole ratio 12:1, initial catalyst concentration 1.374 mol?L-1 and amount of cosolvent 20 % based on the oil amount. The main goals were to assess the effect of the used cosolvents on the synthesis of fatty acid ethyl esters (FAEE) and to select the most efficient one with respect to the final FAEE content, reaction duration and safety profile. In the absence of any cosolvent, the reaction was rather slow, providing a FAEE content of only 89.7?1.7 % after 4 h. Of the tested cosolvents, diethanolamine, triethanolamine and ethylene glycol significantly accelerated the ethanolysis reaction, whereby the last two provided a final FAEE content of 93.1?2.1 and 94.1?1.5 %, respectively, within 0.5 h. However, because of its safety profile, triethanolamine was selected as the best cosolvent for the ethanolysis of sunflower oil catalyzed by calcined CaO.