Modification of Spent Bleaching Earth with WO3 and the Application for Photocatalytic Degradation of Waste Dyestuff under Solar Light

Degradation of blue dye waste in Sarong Samarinda production using WO3-bleaching earth (BE) has been conducted. Structural and morphological characterization has conducted using X-ray diffraction (XRD), and Scanning electron microscopy-energy dispersive spectroscopy (SEM-EDX). The X-ray diffraction results show the mineral on bleaching earth is rectorite dioctahedral mica layer and dioctahedral smectite with a ratio 2:1. The WO3 pattern is appeared after the calcination. After calcination at 500°C, the WO3 is deposited homogeneously on the BE surface. The catalytic performance of WO3-BE for photodegradation of the blue dye waste under the solar light is 99.85 % within 1 h.

Сomposition of volcanites from pre-Jurassic basement of the Western Siberian megabasin (Lakyuganskaya oil exploration area, YNAD)

Relevance of the work. The Western Siberian megabasin is the main source of oil and gas in Russia. Therefore, the study of geological structure and evolution of the development of sedimentary cover rock complexes and the basement of the region is important for estimating the oil and gas potential of this vast territory. The object of this paperis the mineralogical and petro-geochemical study of volcanites from the pre-Jurassic basement of the Lakyuganskaya area (well no. 101) of the Longyugansk exploration acreage within the territory of the Nadym megadepression of the Western Siberian megabasin. Scope of work. This work can be useful when constructing geological maps of the basement of the northern part of the Western Siberian Plate. Results and conclusions. We have studied and described the mineralogy of strongly altered volcanites from the pre-Jurassic basement of the Lakyugansk area (well no. 101) of the Western Siberian Plate. According to chemical composition, the studied volcanites are classified as moderate and high potassic basalts, andesite-basalts and andesites. The rocks were subjected to significant secondary changes in the mineral composition, such as greenschist metamorphism and propylitization. Only titanomagnetite has been preserved from primary minerals in volcanites; all other minerals were subjected to changes. In general, we have determined the following minerals – albite, clinochlore, titanite, calcite, goethite, titanomagnetite (magnetite, ulvospinel), fluorapatite, and rutile. For the first time, ferroaluminoceladonite (dioctahedral mica) and three relatively rare secondary copper sulfides – spionkopite, yarrowite, and geerite – were identified and described in basalts from the basement of Western Siberia. Sulfide coppery mineralization in the studied basalts was due to overlapped propylization processes. The rocks have features of volcanites of island arcs, as well as evidence of calc-alkali and intraplate basalts. The petrological and geochemical characteristics of the studied volcanites are similar to basalts composing the Koltogorsko-Urengoysky rift of the Western Siberian Plate.

New insights into the nature of glauconite

Glauconite must be assessed as mica-rich mica-smectite R3 interstratified mineral, with the pure end-member mica also having intrinsic K-deficient chemical characteristics (K+ ~ 0.8 apfu). This assertion is in accordance with our X-ray diffraction (XRD) and high-resolution tranmission electron microscopy (HRTEM) studies and chemical analyses by electron probe microanalysis (EPMA) of mature glauconites in Cenozoic Antarctic sediments that indicate that: (1) It consists of a glauconite-smectite (R3 ordered) mixed-layer silicate, composed mainly of mica-type layers (>90%), but displaying slightly different proportions of Fe(III)-smectite layers (<10%). (2) More mature glaucony grains are characterized by major K+ and VIFe2+ (mica layers) and minor VIFe3+ (smectite layers) content in the interstratified glauconite-smectite. (3) Potassium is stabilized at the interlayer site by the octahedrally coordinated Fe2+. (4) Microtexture of the glauconite crystals are comparable with those of other micas and illite minerals, with straight, defect-free lattice fringes of ~10 Å spacings glauconite packets characteristic of mica with minor interstratified poorly crystalline smectite layers. In addition, our new findings give insights into the glauconitization process and at the same time investigate the potassium-deficient character of the dioctahedral mica “glauconite.” These findings show that glauconite crystallizes by a layer-growth mechanism at the expense of a poorly crystalline smectite precursor and that smectiteto-glauconite transformations are accompanied by a gradually higher octahedral charge deficiency (Fe2+/Fe3+) stabilized by K+ uptake into the interlayer sheet.

Vanadium occupation and its leachability differences in trioctahedral and dioctahedral mica

Vanadium in black shale prefers to locate in the octahedron of mica and can be more easily released from trioctahedral mica than dioctahedral mica.

Origin of mixed-layered (R1) muscovite-chlorite in an anchizonal slate from Puncoviscana Formation (Salta Province, Argentina)

Mica-chlorite mixed-layering was identified by X-ray diffraction (XRD) as a major or subordinate constituent in several slates of the Puncoviscana Formation from Sierra de Mojotoro (Eastern Cordillera, NW Argentina). In order to determine the crystallochemical characteristics of these mixed-layered sequences and interpret their petrological meaning, anchizonal slate P90 was chosen for TEM observations. In this slate, dioctahedral mica and chlorite form interleaved phyllosilicate grains (IPG) or stacks, up to 110 um long, preferentially oriented with (001) planes at a high angle to the slaty cleavage but also oblique to S0.In agreement with XRD results, the main phyllosilicates identified by transmission electron microscopy (TEM) were dioctahedral mica and random mixed-layer muscovite-chlorite, with chlorite in subordinate amounts and scarce smectite. In the lattice-fringe images of mixed-layer packets, a sequence of irregular stacking that produced apparent 24 Å (10 + 14) layers was observed, but it was frequently possible to distinguish the 10 Å layers from adjacent 14 Å layers. In nearly all packets, 14 Å layers prevail, exhibiting 14 Å:10 Å ratios between 1:1 and 3:1. Some elongated lenticular fissures which are probably a consequence of layer collapse caused by the TEM vacuum were identified in these packets. The straight, continuous appearance of lattice fringes plus the scarce evidence of collapsed layers identified suggest that these packets correspond principally to mixed-layer muscovite-chlorite, which is confirmed by analytical electron microscopy analyses. However, smectite-like layers are probably the third component of some of these mixed-layer sequences, which may account for their high Si and low (Fe + Mg) contents, their low interlayer charge in relation to theoretical interlayer muscovite-chlorite, and for the presence of Ca in the interlayer site.Textural relationships between chlorite and muscovite packets in IPG along with the observed transformations from 14 Å to 10 Å along the layer, is compatible with a prograde metamorphic replacement of chlorite in stacks by dioctahedral mica layers, probably in the presence of an aqueous fluid.