Novel 2:1 structure of phyllosilicates formed by annealing Fe3+, Mg-rich dioctahedral mica

2007 ◽  
Vol 92 (8-9) ◽  
pp. 1531-1534 ◽  
Author(s):  
T. Kogure ◽  
J. Kameda ◽  
V. A. Drits
Keyword(s):  
2020 ◽  
Vol 8 (2) ◽  
pp. 84-89
Author(s):  
Noor Hindryawati ◽  
Aman Sentosa Panggabean ◽  
Dirgarini Julia Nurlianti Subagyono ◽  
Rinda Anisyah Putri ◽  
Prilianda Kusmiaty ◽  
...  

Degradation of blue dye waste in Sarong Samarinda production using WO3-bleaching earth (BE) has been conducted. Structural and morphological characterization has conducted using X-ray diffraction (XRD), and Scanning electron microscopy-energy dispersive spectroscopy (SEM-EDX). The X-ray diffraction results show the mineral on bleaching earth is rectorite dioctahedral mica layer and dioctahedral smectite with a ratio 2:1. The WO3 pattern is appeared after the calcination. After calcination at 500°C, the WO3 is deposited homogeneously on the BE surface. The catalytic performance of WO3-BE for photodegradation of the blue dye waste under the solar light is 99.85 % within 1 h.


2020 ◽  
Vol 1 (2) ◽  
pp. 7-19
Author(s):  
Vladimir Sergeevich PONOMAREV ◽  
◽  
Kirill Svyatoslavich IVANOV ◽  
Yuriy Viktorovich EROKHIN ◽  
◽  
...  

Relevance of the work. The Western Siberian megabasin is the main source of oil and gas in Russia. Therefore, the study of geological structure and evolution of the development of sedimentary cover rock complexes and the basement of the region is important for estimating the oil and gas potential of this vast territory. The object of this paperis the mineralogical and petro-geochemical study of volcanites from the pre-Jurassic basement of the Lakyuganskaya area (well no. 101) of the Longyugansk exploration acreage within the territory of the Nadym megadepression of the Western Siberian megabasin. Scope of work. This work can be useful when constructing geological maps of the basement of the northern part of the Western Siberian Plate. Results and conclusions. We have studied and described the mineralogy of strongly altered volcanites from the pre-Jurassic basement of the Lakyugansk area (well no. 101) of the Western Siberian Plate. According to chemical composition, the studied volcanites are classified as moderate and high potassic basalts, andesite-basalts and andesites. The rocks were subjected to significant secondary changes in the mineral composition, such as greenschist metamorphism and propylitization. Only titanomagnetite has been preserved from primary minerals in volcanites; all other minerals were subjected to changes. In general, we have determined the following minerals – albite, clinochlore, titanite, calcite, goethite, titanomagnetite (magnetite, ulvospinel), fluorapatite, and rutile. For the first time, ferroaluminoceladonite (dioctahedral mica) and three relatively rare secondary copper sulfides – spionkopite, yarrowite, and geerite – were identified and described in basalts from the basement of Western Siberia. Sulfide coppery mineralization in the studied basalts was due to overlapped propylization processes. The rocks have features of volcanites of island arcs, as well as evidence of calc-alkali and intraplate basalts. The petrological and geochemical characteristics of the studied volcanites are similar to basalts composing the Koltogorsko-Urengoysky rift of the Western Siberian Plate.


2020 ◽  
Vol 105 (5) ◽  
pp. 674-686 ◽  
Author(s):  
Adrián López-Quirós ◽  
Antonio Sánchez-Navas ◽  
Fernando Nieto ◽  
Carlota Escutia

Abstract Glauconite must be assessed as mica-rich mica-smectite R3 interstratified mineral, with the pure end-member mica also having intrinsic K-deficient chemical characteristics (K+ ~ 0.8 apfu). This assertion is in accordance with our X-ray diffraction (XRD) and high-resolution tranmission electron microscopy (HRTEM) studies and chemical analyses by electron probe microanalysis (EPMA) of mature glauconites in Cenozoic Antarctic sediments that indicate that: (1) It consists of a glauconite-smectite (R3 ordered) mixed-layer silicate, composed mainly of mica-type layers (>90%), but displaying slightly different proportions of Fe(III)-smectite layers (<10%). (2) More mature glaucony grains are characterized by major K+ and VIFe2+ (mica layers) and minor VIFe3+ (smectite layers) content in the interstratified glauconite-smectite. (3) Potassium is stabilized at the interlayer site by the octahedrally coordinated Fe2+. (4) Microtexture of the glauconite crystals are comparable with those of other micas and illite minerals, with straight, defect-free lattice fringes of ~10 Å spacings glauconite packets characteristic of mica with minor interstratified poorly crystalline smectite layers. In addition, our new findings give insights into the glauconitization process and at the same time investigate the potassium-deficient character of the dioctahedral mica “glauconite.” These findings show that glauconite crystallizes by a layer-growth mechanism at the expense of a poorly crystalline smectite precursor and that smectiteto-glauconite transformations are accompanied by a gradually higher octahedral charge deficiency (Fe2+/Fe3+) stabilized by K+ uptake into the interlayer sheet.


Clay Minerals ◽  
1968 ◽  
Vol 7 (3) ◽  
pp. 295-309 ◽  
Author(s):  
H. Kodama ◽  
J. E. Brydon

AbstractClays from the Ae and C horizons of five Podzol soil series in New Brunswick were examined by X-ray, chemical and infrared absorption methods. All the experimental evidence indicated that the Ae horizons contained predominantly a dioctahedral randomly interstratified mica-vermiculite-smectite clay, whereas the C horizons contained abundant dioctahedral mica (illite) and trioctahedral chlorite. Since no trace of chlorite as a separate phase or as one component of the interstratified structure was found in the Ae horizons, it was concluded that, while the inherited chlorite was decomposed in all of the Ae horizons, mica was differentially hydrated giving an interstratified structure. Fourier transforms of the three-component interstratified clay revealed different ratios of hydrated layers (vermiculite and smectite) to non-hydrated layers and different stacking sequences. The proportion of hydrated layers and randomness of stacking was related to the degree of weathering as measured by the accumulation of TiO2 in the Ae horizon and it was suggested that they may be related to the degree of podzolization.


1978 ◽  
Vol 9 (3) ◽  
pp. 129-136 ◽  
Author(s):  
Shinji TOMURA ◽  
Masao KITAMURA ◽  
Ichiro SUNAGAWA

1980 ◽  
Vol 43 (332) ◽  
pp. 959-966 ◽  
Author(s):  
G. A. Desborough ◽  
S. D. Ludington ◽  
W. N. Sharp

SummaryThe Precambrian Redskin stock is a high-silica alkalic granite that forms a late pluton related to the 1000 Ma-old Pikes Peak batholith. Zircon, fluorite, fluocerite, ilmenorutile, columbite, biotite, magnetite, and hematite are the most abundant accessory minerals. Thorite, monazite, and xenotime are sparse, and cassiterite and topaz very rare. The principal residences of Sn, Nb, and Ta are ilmenorutile and columbite. The occurrence of cassiterite intergrown with biotite and columbite and the high contents of Nb and Ta in cassiterite are evidence that cassiterite is also a primary mineral. The high concentrations of certain trace elements indicate a high degree of fractionation of magma prior to emplacement of the Redskin Granite. An extremely low crystallization temperature for the granite is indicated by the compositions of albite and K-feldspars, the presence of Fe-rich dioctahedral mica, the absence of Ti in magnetite, and the low content of Ti in biotite. This low crystallization temperature seems due largely to the high concentrations of F, Rb, and other volatile elements in the magma.


Soil Research ◽  
1981 ◽  
Vol 19 (1) ◽  
pp. 1
Author(s):  
AJ Koppi

A common toposequence on Bunya Phyllite in south-east Queensland was studied in detail at a representative site. Four sample profiles on the slope are described, and some physical and chemical properties are given. The clay minerals, derived from the weathering of the quartz-sericite-chlorite phyllite, comprise dioctahedral mica, dioctahedral vermiculite, an interstratification of these minerals, and kaolin. Properties are related to the slope; and the clay-rich horizon of the middle and lower slopes is considered to be formed mostly by in situ weathering. The classification of the genetic unit given by the slope and parent material is discussed.


1991 ◽  
Vol 15 (6) ◽  
pp. 249-260 ◽  
Author(s):  
Shoji HIGASHI ◽  
Sachihiro TAGUCHI

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