Measurement report: Comparison of wintertime individual particles at ground level and above the mixed layer in urban Beijing

Beijing has been suffering from frequent severe air pollution events, with concentrations affected significantly by the mixed-layer height. Major efforts have been made to study the physico-chemical properties, compositions, and sources of aerosol particles at ground level. However, little is known about the morphology, elemental composition, and mixing state of aerosol particles above the mixed layer. In this work, we collected individual aerosol particles simultaneously at ground level (2 m above ground) and above the mixed layer in urban Beijing (within the Atmospheric Pollution and Human Health in a Chinese Megacity, APHH-Beijing, 2016 winter campaign). The particles were analyzed offline by transmission electron microscopy coupled with energy dispersive X-ray spectroscopy. Our results showed that the relative number contribution of mineral particles to all measured particles was much higher during non-haze periods (42.5 %) than haze periods (18.1 %); in contrast, internally mixed particles contributed more during haze periods (21.9 %) than non-haze periods (7.2 %) at ground level. In addition, more mineral particles were found at ground level than above the mixed-layer height. Around 20 % of individual particles showed core–shell structures during haze periods, whereas only a few core–shell particles were observed during non-haze periods (2 %). The results showed that the particles above the mixed layer were more aged, with a larger proportion of organic particles originating from coal combustion. Our results indicate that a large fraction of the airborne particles above the mixed layer come from surrounding areas influenced by coal combustion activities. This source contributes to the surface particle concentrations in Beijing when polluted air is mixed down to the ground level.

Detecting cold pools from soundings during EUREC4A

<p>We develop a novel method to detect cold pools from atmospheric soundings over tropical oceans and apply it to sounding data from EUREC<sup>4</sup>A. The proposed method exploits the fact that the air in a cold pool is denser than the air above it. It leads us to define cold pool soundings as those for which the mixed-layer height is smaller than 400 m. We first test this criterion by verifying its consistency with surface temperature and precipitation in a realistic high-resolution simulation over the western tropical Atlantic. Applying to EUREC<sup>4</sup>A data, we then identify 7 % of EUREC<sup>4</sup>A dropsondes and radiosondes as cold pool soundings. In two selected case studies, we find that cold pool soundings coincide with mesoscale cloud arcs and temperature drops in the surface time series. Statistics for the entire campaign further characterize the signature of cold pools in temperature, humidity and wind profiles. In the presence of wind shear, we show in particular that the spreading of cold pools is favored downshear, suggesting downward momentum transport by unsaturated downdrafts. These results support the robustness of our simple method in different environmental conditions and illustrate the new insights it offers for the characterization of cold pools and their environment. </p>

Measurement report: Comparison of wintertime individual particles at ground level and above the mixed layer in urban Beijing

Beijing has been suffering from frequent severe air pollution events, with concentrations affected significantly by the mixed layer height. Major efforts have been made to study the physico-chemical properties, composition, and sources of aerosol particles at ground level. However, little is known on morphology, elemental composition, and mixing state of aerosol particles above the mixed layer. In this work, we collected individual aerosol particles simultaneously at ground level (2 m above ground) and above the mixed layer in urban Beijing (within the Atmospheric Pollution and Human Health in a Chinese Megacity (APHH-Beijing) 2016 winter campaign). The particles were analyzed off-line using transmission electron microscopy coupled with energy dispersive X-ray spectroscopy. Our results showed that the relative number contribution of mineral particles to all measured particles was much higher during non-haze periods (42.5 %) than haze periods (18.1 %); on the contrary, internally mixed particles contributed more during haze periods (21.9 %) than non-haze periods (7.2 %) at ground level. In addition, more mineral particles were found at ground level than above the mixed layer height. Around 20 % of individual particles showed core-shell structures during haze periods, whereas only a few core-shell particles were observed during non-haze periods (2 %). We found that the particle above the mixed layer tend to be more aged with a larger proportion of organic particles originated from coal combustion. Our results indicate that a significant fraction of the airborne particles above the mixed layer originated from surrounding areas influenced by coal combustion activities. This source contributes to the surface particle concentrations in Beijing when polluted air is mixed down to the ground level.

Implementation of a 2D Wavelet Method to Probe Mixed Layer Height Using Lidar Observations

A new method was developed to estimate mixed layer (ML) height with light detection and ranging (lidar) observations using a 2Dimensional (2D) wavelet method, which can consider the diurnal variation characteristics of ML height. Ideal signals and real lidar observations in Shanghai, China were used to evaluate the new method. The results showed that the new method is insensitive to the type of wavelet filters. The estimated ML heights obtained by the 2D wavelet method agreed well with both of the previous methods developed for the ML height probing using lidar, including the gradient method, the 1D-wavelet method, the standard deviation method, and the conventional radiosonde method. The primary differences among the results obtained via the different lidar methods occurred in the early morning or later afternoon; when the ML is well mixed, very small differences were observed among the different lidar methods. The new method showed better determination skills than other methods when compared to the radiosonde observation results. It also performed well when there were missing profiles or observation errors and it made the new method suitable for operations where data quality control may be missed.

Atmospheric boundary layer dynamics from balloon soundings worldwide: CLASS4GL v1.0

The coupling between soil, vegetation and atmosphere is thought to be crucial in the development and intensification of weather extremes, especially meteorological droughts, heat waves and severe storms. Therefore, understanding the evolution of the atmospheric boundary layer (ABL) and the role of land–atmosphere feedbacks is necessary for earlier warnings, better climate projection and timely societal adaptation. However, this understanding is hampered by the difficulties of attributing cause–effect relationships from complex coupled models and the irregular space–time distribution of in situ observations of the land–atmosphere system. As such, there is a need for simple deterministic appraisals that systematically discriminate land–atmosphere interactions from observed weather phenomena over large domains and climatological time spans. Here, we present a new interactive data platform to study the behavior of the ABL and land–atmosphere interactions based on worldwide weather balloon soundings and an ABL model. This software tool – referred to as CLASS4GL (http://class4gl.eu, last access: 27 May 2018) – is developed with the objectives of (a) mining appropriate global observational data from ∼15 million weather balloon soundings since 1981 and combining them with satellite and reanalysis data and (b) constraining and initializing a numerical model of the daytime evolution of the ABL that serves as a tool to interpret these observations mechanistically and deterministically. As a result, it fully automizes extensive global model experiments to assess the effects of land and atmospheric conditions on the ABL evolution as observed in different climate regions around the world. The suitability of the set of observations, model formulations and global parameters employed by CLASS4GL is extensively validated. In most cases, the framework is able to realistically reproduce the observed daytime response of the mixed-layer height, potential temperature and specific humidity from the balloon soundings. In this extensive global validation exercise, a bias of 10.1 m h−1, −0.036 K h−1 and 0.06 g kg−1 h−1 is found for the morning-to-afternoon evolution of the mixed-layer height, potential temperature and specific humidity. The virtual tool is in continuous development and aims to foster a better process understanding of the drivers of the ABL evolution and their global distribution, particularly during the onset and amplification of weather extremes. Finally, it can also be used to scrutinize the representation of land–atmosphere feedbacks and ABL dynamics in Earth system models, numerical weather prediction models, atmospheric reanalysis and satellite retrievals, with the ultimate goal of improving local climate projections, providing earlier warning of extreme weather and fostering a more effective development of climate adaptation strategies. The tool can be easily downloaded via http://class4gl.eu (last access: 27 May 2018) and is open source.

The first evaluation of formaldehyde column observations by improved Pandora spectrometers during the KORUS-AQ field study

The Korea–United States Air Quality Study (KORUS-AQ) conducted during May–June 2016 offered the first opportunity to evaluate direct-sun observations of formaldehyde (HCHO) total column densities with improved Pandora spectrometer instruments. The measurements highlighted in this work were conducted both in the Seoul megacity area at the Olympic Park site (37.5232∘ N, 27.1260∘ E; 26 m a.s.l.) and at a nearby rural site downwind of the city at the Mount Taehwa research forest site (37.3123∘ N, 127.3106∘ E; 160 m a.s.l.). Evaluation of these measurements was made possible by concurrent ground-based in situ observations of HCHO at both sites as well as overflight by the NASA DC-8 research aircraft. The flights provided in situ measurements of HCHO to characterize its vertical distribution in the lower troposphere (0–5 km). Diurnal variation in HCHO total column densities followed the same pattern at both sites, with the minimum daily values typically observed between 6:00 and 7:00 local time, gradually increasing to a maximum between 13:00 and 17:00 before decreasing into the evening. Pandora vertical column densities were compared with those derived from the DC-8 HCHO in situ measured profiles augmented with in situ surface concentrations below the lowest altitude of the DC-8 in proximity to the ground sites. A comparison between 49 column densities measured by Pandora vs. aircraft-integrated in situ data showed that Pandora values were larger by 16 % with a constant offset of 0.22 DU (Dobson units; R2=0.68). Pandora HCHO columns were also compared with columns calculated from the surface in situ measurements over Olympic Park by assuming a well-mixed lower atmosphere up to a ceilometer-measured mixed-layer height (MLH) and various assumptions about the small residual HCHO amounts in the free troposphere up to the tropopause. The best comparison (slope =1.03±0.03; intercept =0.29±0.02 DU; and R2=0.78±0.02) was achieved assuming equal mixing within ceilometer-measured MLH combined with an exponential profile shape. These results suggest that diurnal changes in HCHO surface concentrations can be reasonably estimated from the Pandora total column and information on the mixed-layer height. More work is needed to understand the bias in the intercept and the slope relative to columns derived from the in situ aircraft and surface measurements.

The First Evaluation of Formaldehyde Column Observations by Pandora Spectrometers during the KORUS-AQ Field Study

The KORUS-AQ field study conducted during May–June 2016 offered the first opportunity to evaluate direct-sun observations of formaldehyde (HCHO) total column densities with improved Pandora spectrometer instruments. The measurements highlighted in this work were conducted both in the Seoul megacity area at the Olympic Park site (latitude: 37.5232° N, longitude: 127.1260° E, 26 m a.s.l.) and at a nearby rural site downwind of the city at the Mount Taehwa Research Forest site (latitude: 37.3123° N, longitude: 127.3106° E, 160 m a.s.l.). Evaluation of these measurements was made possible by concurrent ground-based in situ observations of HCHO at both sites as well as overflight by the NASA DC-8 research aircraft. The flights provided in situ measurements of HCHO to characterize its vertical distribution in the lower troposphere (0–5 km). Diurnal variation in HCHO total column densities followed the same pattern at both sites, with the minimum daily values typically observed between 6:00–7:00 local time, gradually increasing to a maximum between 13:00 and 17:00 before decreasing into the evening. Pandora vertical column densities were compared with those derived from the DC-8 HCHO in-situ measured profiles augmented with in-situ surface concentrations below the lowest altitude of the DC-8 in proximity to the ground sites. A comparison between 49 column densities measured by Pandora versus aircraft integrated in-situ data showed that Pandora values were larger by 16 % (intercept = 0.22 DU, R2 = 0.68). Pandora HCHO columns were also compared with columns calculated from the surface in-situ measurements over Olympic Park by assuming a well-mixed lower atmosphere up to a ceilometer measured mixed-layer height (MLH) and various assumptions about the small residual HCHO amounts in the free troposphere up to the tropopause. The best comparison (slope = 1.03 ± 0.03, intercept = 0.29 ± 0.02 DU and R2 of 0.78 ± 0.02) was achieved assuming equal mixing within ceilometer measured MLH combined with an exponential profile shape. These results suggest that diurnal changes in HCHO surface concentrations can be reasonably estimated from the Pandora total column and information on the mixed-layer height. More work is needed to understand the bias in the intercept and the slope relative to columns derived from the in-situ aircraft and surface measurements.