Role of particle aggregation in the structure of dried colloidal silica layers

The process of colloidal drying gives way to particle self-assembly in numerous fields including photonics or biotechnology.

Superparamagnetic Iron Oxide Nanoparticles Modified with Silica Layers as Potential Agents for Lung Cancer Treatment

Superparamagnetic iron oxide nanoparticles (SPIONs) are promising drug delivery carriers and hyperthermia agents for the treatment of cancer. However, to ensure their safety in vivo, SPIONs must be modified in order to prevent unwanted iron release. Thus, SPIONs were coated with silica layers of different morphologies: non-porous (@SiO2), mesoporous (@mSiO2) or with a combination of non-porous and mesoporous layers (@SiO2@mSiO2) deposited via a sol–gel method. The presence of SiO2 drastically changed the surface properties of the nanoparticles. The zeta potential changed from 19.6 ± 0.8 mV for SPIONs to −26.1 ± 0.1 mV for SPION@mSiO2. The Brunauer–Emmett–Teller (BET) surface area increased from 7.54 ± 0.02 m2/g for SPIONs to 101.3 ± 2.8 m2/g for SPION@mSiO2. All types of coatings significantly decreased iron release (at least 10 fold as compared to unmodified SPIONs). SPIONs and SPION@mSiO2 were tested in vitro in contact with human lung epithelial cells (A549 and BEAS-2B). Both nanoparticle types were cytocompatible, although some delay in proliferation was observed for BEAS-2B cells as compared to A549 cells, which was correlated with increased cell velocity and nanoparticles uptake.

Asbestiform anthophyllite, tremolite, and related fibrous amphibole chemistry, both as primary and secondary mineralization in metamorphic facies in asbestos occurrences in North American deposit comparisons

<p>As we continue to investigate the asbestos-forming minerals and their associated geology as they occur in North America, we have found that subtle variations can make the standardization of what is and what is not asbestos more difficult. On the other hand, some geochemical trends recently observed have given us significant insight into what we can expect in the ground, which we hope will lend much-needed information to medical investigators to better understand the relationship of mineral morphologic and chemical differences and the ramifications to human health for those potentially exposed. In efforts to understand why certain minerals form in the asbestiform habit, mineralogists still cannot fully explain the cause-and-effect of this phenomenon. Although we know that there are chemical variances and pressure or temperature regimes that are conducive to the formation of asbestos, a complete and absolute picture of how and why amphibole forms fibers, or serpentine forms chrysotile scrolls remains elusive. Research indicates however that there are two primary ways that sheet silicates compensate for the fundamental misfit between their tetrahedral silica layers (T) and their octahedrally-coordinated cation layers (O) that is by either tetrahedral rotation /stretching or by bending or modulation of the layers in concert. Rotation or stretching occurs in both the 1:1 layer silicates (T-O) such as serpentines, and the 2:1 phyllosilicates (T-O-T) such as vermiculite or talc. The other primary means of misfit compensation is structural bending, with the obvious examples of antigorite or chrysotile. Although it was originally hypothesized as early as the 1950s that this curving or bending of the sheet structure was entirely due to the T-O misfit, more recent research points to the importance and variances of hydroxyl bonding in the chrysotile structure. A secondary mode of compensation for the fundamental misfit is by the addition or subtraction of silica tetrahedra or octahedral cations in modulated fashion, which affects the overall chemistry of the mineral as a whole. In polysomatic hydrous biopyriboles we see the importance of hydration alteration reactions in the transformation of chain zippers. Thusly, a wide variety of intergrowth microstructures appear in Mg-rich 1:1 modulated layer silicates, analogous to the hydrous biopyriboles as is common intimate intermixing in a polysomatic series. It is therefore common that the means by which all of our regulated asbestos minerals form is through the combined action of T-O misfit compensation and the action of water in the crystallizing or re-crystallizing process. </p>

Influence of Water-Miscible Organic Solvent on the Activity and Stability of Silica-Coated Ru Catalysts in the Selective Hydrolytic Hydrogenation of Cellobiose into Sorbitol

Ruthenium nanoparticles supported on carbon black were coated by mesoporous protective silica layers (Ru/CB@SiO2) with different textural properties (SBET: 280–390 m2/g, pore diameter: 3.4–5.0 nm) and were tested in the selective hydrogenation of glucose into sorbitol. The influence of key parameters such as the protective layer pore size and the solvent nature were investigated. X-ray photoelectron spectroscopy (XPS) analyses proved that the hydrothermal stability was highly improved in ethanolic solution with low water content (silica loss: 99% in water and 32% in ethanolic solution). In this work, the strong influence of the silica layer pore sizes on the selectivity of the reaction (shifting from 4% to 68% by increasing the pores sizes from 3.4 to 5 nm) was also highlighted. Finally, by adding acidic co-catalyst (CB–SO3H), sorbitol was obtained directly through the hydrolytic hydrogenation of cellobiose (used as a model molecule of cellulose), demonstrating the high potential of the present methodology to produce active catalysts in biomass transformations.

Enhancement of the performance of Pd nanoclusters confined within ultrathin silica layers for formic acid oxidation

Ultrasmall Pd nanoclusters confined within silica layers show high activity for formic acid oxidation with excellent stability.