Environmental Safety Analysis of Red Mud-Based Cemented Backfill on Groundwater

As one of the main industrial solid wastes, there are a large number of free alkaloids, chemically bound alkaloids, fluoride, and heavy metal ions in Bayer process red mud (BRM), which are difficult to remove and easily pollute groundwater as a result of open storage. In order to realize the large-scale industrial application of BRM as a backfilling aggregate for underground mining and simultaneously avoid polluting groundwater, the material characteristics of BRM were analyzed through physical, mechanical, and chemical composition tests. The optimum cement–sand ratio and solid mass concentration of the backfilling were obtained based on several mixture proportion tests. According to the results of bleeding, soaking, and toxic leaching experiments, the fuzzy comprehensive evaluation method was used to evaluate the environmental impact of BRM on groundwater. The results show that chemically bound alkaloids that remained in BRM reacted with Ca2+ in PO 42.5 cement, slowed down the solidification speed, and reduced the early strength of red mud-based cemented backfill (RMCB). The hydration products in RMCB, such as AFT and C-S-H gel, had significant encapsulation, solidification, and precipitation inhibition effects on contaminants, which could reduce the contents of inorganic contaminants in soaking water by 26.8% to 93.8% and the leaching of toxic heavy metal ions by 57.1% to 73.3%. As shown by the results of the fuzzy comprehensive evaluation, the degree of pollution of the RMCB in bleeding water belonged to a medium grade Ⅲ, while that in the soaking water belonged to a low grade II. The bleeding water was diluted by 50–100 times to reach grade I after flowing into the water sump and could be totally recycled for drilling and backfilling, thus causing negligible effects on the groundwater environment.

Research on C30 Concrete Mix Proportion in Guangdong Province

The reasons of C30 concrete bleeding in winter in Guangdong province were studied by collecting the concrete mix proportions of C30 concrete mixing plants in Guangdong, Fujian, Henan, Hunan, Chongqing and Shaanxi regions, the difference between the concrete mix proportions in Guangdong and other regions was investigated. Based on the representative concrete mix proportion in Guangdong province, the concrete bleeding water test was carried out, and the correlation between the amount of different cementing materials and the bleeding rate was investigated. The results showed that compared with other regions, the C30 concrete mix proportion in Guangdong has the lowest total cementitious material, which made it more prone to bleeding. The amount of slag powder and the total amount of cementitious materials have a high correlation with the bleeding rate. With the increase of the amount of slag powder and the total amount of cementitious materials, the bleeding rate decreases.

Experimental Study on Backfilling Mine Goafs with Chemical Waste Phosphogypsum

To explore the feasibility of cemented paste backfill with phosphogypsum (PG), bleeding water and rheological tests (slump and on-site pipeline loop tests) were performed with PG backfill slurry (PGBS). In the bleeding water test, the PGBS concentration with minimal bleeding water was measured between 60.87 and 67.61%; in the rheological slump test, values of 61 to 68% were determined for the on-site pipeline loop test. The rheological pipeline loop test demonstrated that the resistance coefficient is lowest when the concentration is no higher than 65%. Through industrial experiments, PG slurry with a concentration of 64%–65% backfill was successfully applied to the goaf. The experimental results demonstrate that PGBS with characteristics of “less bleeding water” and “improved pumpability” is obtained when its concentration is between 61 and 65%. Paste-like PG slurry was proven to be optimal for cemented PG backfilling technology.

Research on Preparation and Properties of Backfilling Cementation Material Based on Blast Furnace Slag

The blast-furnace slag (BFS) has been characterized by chemical and phase composition to evaluate its hydration reactivity. It has high potential activity for its glassy structure, so its use to prepare new filling cementation material is possible. New backfilling cementation material composition has been formulated and optimized by activation of BFS. The optimal formula of new backfilling cementation material SL(Slag activated by lime) and SLG(Slag activated by lime and desulfurization gypsume) was 87% BFS ,13% lime and 78.4% BFS, 11.8% lime, 9.8% desulfurization gypsume respectively. Finally, the feature of cementation properties was analyzed through comparison between new cementation material and ordinary Portland cement with compressive strength, water requirement of normal consistence, setting time, bleeding water and slump. The result showed that material SL and SLG have superior performance to ordinary Portland cement used to mining cemented filling.