DSSC with PEDOT-Carrageenan Electrolyte as Learning Media for Photovoltaic Concept Physics

This study aims to create a DSSC using PEDOT-Carrageenan-based electrolyte as a learning media for photovoltaic physics concepts. This research was experimental research conducted in the laboratory of subdepartment of physics education, Tadulako University. In this study, DSSC making process used a substrate made from TCO-FTO polymer. The TiO2 photoelectrode layer was deposited using the doctor blade technique and Ruthenizer as a dye-sensitizer and the platinum layer was deposited on the counter electrode using the sputtering technique. Process parameters that affect the characteristics of solar cells were analyzed and measured using the I-V characteristic curve. The samples measured consisted of several types of PEDOT-Carrageenan electrolytes, including Kappa, Lambda and Iota. The results of voltage measurements of each sample of the DSSC prototype were obtained quite well at a voltage of 91.8 mV using PEDOT-Carrageenan Kappa 1:2 electrolyte and the short circuit current obtained reached 57.6 uA. The best solar cell prototype produces an efficiency of 0.0003333728 %. It indicates that DSSC can be made by PEDOT-Carragenan electrolyte and can be used as a learning tool for photovoltaic physics concepts.

Dye-Sensitized Solar Cell for Building-Integrated Photovoltaic (BIPV) Applications

One of the important research directions in the field of photovoltaics is integration with construction. The integration of solar cell systems with a building can reduce installation costs and help optimize the used space. One of the interesting types of cells is dye-sensitized solar cells. In addition to their interesting properties, they also have aesthetic value. In the classic arrangement, they are constructed using glass with a transparent conductive layer (TCL). This article describes replacing a classic glass counter electrode with an electrode based on a ceramic tile and nickel foil. This solution makes it possible to expand their construction applications. The advantage of this solution is full integration with construction while simultaneously generating electricity. A dye-sensitized solar cell was built layer-by-layer on ceramic tile and nickel foil. An atomization method was used to deposit fluorine-doped tin oxide, and then a screen printing method was used to deposit a platinum layer. The electrical parameters of the manufactured DSSCs with and without a counter electrode tile were characterized by measuring their current-voltage characteristics under standard AM 1.5 radiation. A dye-sensitized solar cell integrated with ceramic tiles and nickel foil was produced and displayed an efficiency of over 4%.

Subterahertz spin pumping from an insulating antiferromagnet

Spin-transfer torque and spin Hall effects combined with their reciprocal phenomena, spin pumping and inverse spin Hall effects (ISHEs), enable the reading and control of magnetic moments in spintronics. The direct observation of these effects remains elusive in antiferromagnetic-based devices. We report subterahertz spin pumping at the interface of the uniaxial insulating antiferromagnet manganese difluoride and platinum. The measured ISHE voltage arising from spin-charge conversion in the platinum layer depends on the chirality of the dynamical modes of the antiferromagnet, which is selectively excited and modulated by the handedness of the circularly polarized subterahertz irradiation. Our results open the door to the controlled generation of coherent, pure spin currents at terahertz frequencies.

Micromagnetic modeling of silicate-hosted magnetic inclusions using SEM-FIB slice-and-view nanotomography

<p><span>Slice-and-view nanotomography uses a dual beam SEM-FIB to reconstruct the 3D volume of a mineralogical sample using a sequential series of nanoscale slices created with a focussed beam of Ga ions. This method reveals the true shapes and forms of naturally occurring magnetic inclusions hosted by the silicate minerals feldspar and pyroxene. High-resolution 3D morphological data for the magnetic minerals is extracted, converted to tetrahedral meshes, and micromagnetically modelled using the MERRILL software. </span></p><p><span>This study optimises the step-by-step process of extracting and processing micromagnetic data from polished thin-sections to generate a full rock magnetic classification of the remanence carriers in silicates. Slice-and-view nanotomography follows known preparation methods with a protective platinum layer, carbon rod guides and trenches, but also introduces a carbon slab along the Z-direction for e-beam alignment. This method reduces the need for auto focus, as the e-beam alignment will have a constant imaging distance and generates a good reference point for stack alignment. Image processing is limited to 3D a gaussian blur and 3D mean filters. Paraview is used to set the correct voxel dimensions and to generate the surface mesh. Freeware software Meshmixer and Meshlab are used for their powerful smoothing, mesh interaction tools and geometric calculations. The tetrahedral volume mesh is produced with iso2mesh in Matlab. </span></p><p><span>Micromagnetic hysteresis and back-field simulations of >400 inclusions with a broad range of morphologies have been performed using MERRILL using 20 different field directions, enabling average magnetic properties to be calculated for a random ensemble. The results give a detailed and direct description of the micromagnetic structure of naturally formed magnetic minerals that compliments macroscopic approaches, such as FORC analysis. </span></p>

Functionalization of PET Track-Etched Membranes by UV-Induced Graft (co)Polymerization for Detection of Heavy Metal Ions in Water

Nowadays, water quality monitoring is an essential task since environmental contamination and human exposure to heavy metals increased. Sensors that are able to detect ever lower concentrations of heavy metal ions with greater accuracy and speed are needed to effectively monitor water quality and prevent poisoning. This article shows studies of the modification of flexible track-etched membranes as the basis for the sensor with various polymers and their influence on the accuracy of detection of copper, cadmium, and lead ions in water. We report the UV-induced graft (co)polymerization of acrylic acid (AA) and 4-vinylpyridine (4-VPy) on poly(ethylene terephthalate) track-etched membrane (PET TeMs) and use them after platinum layer sputtering in square wave anodic stripping voltammetry (SW-ASV) for detection of Cu2+, Cd2+, and Pb2+. Optimal conditions leading to functionalization of the surface and retention of the pore structure were found. Modified membranes were characterized by SEM, FTIR, X-ray photoelectron spectroscopy (XPS) and colorimetric analysis. The dependence of the modification method on the sensitivity of the sensor was shown. Membrane modified with polyacrylic acid (PET TeMs-g-PAA), poly(4-vinylpyridine) (PET TeMs-g-P4VPy), and their copolymer (PET TeMs-g-P4VPy/PAA) with average grafting yield of 3% have been found to be sensitive to µg/L concentration of copper, lead, and cadmium ions. Limits of detection (LOD) for sensors based on PET TeMs-g-PAA are 2.22, 1.05, and 2.53 µg/L for Cu2+, Pb2+, and Cd2+, respectively. LODs for sensors based on PET TeMs-g-P4VPy are 5.23 µg/L (Cu2+), 1.78 µg/L (Pb2+), and 3.64 µg/L (Cd2+) µg/L. PET TeMs-g-P4VPy/PAA electrodes are found to be sensitive with LODs of 0.74 µg/L(Cu2+), 1.13 µg/L (Pb2+), and 2.07 µg/L(Cd2+). Thus, it was shown that the modification of membranes by copolymers with carboxylic and amino groups leads to more accurate detection of heavy metal ions, associated with the formation of more stable complexes.

Effect of Morphology and Mechanical Stability of Nanometric Platinum Layer on Nickel Foam for Hydrogen Evolution Reaction

Platinum thin films are deposited on open-cell nickel foam with porosity of 95% via spontaneous galvanic displacement. Ni foams with different morphologies and pore size are compared and characterized by electrochemical and structural analysis techniques. The effect of Pt coating on the electrochemical activity is studied by using the Pt coated foam as electrode material for hydrogen evolution reaction in an aqueous alkaline electrolyte. The electrocatalytic activity of the electrodes is evaluated using linear sweep voltammetry curves and Tafel plots as a function of deposition time. The comparison with scanning electron microscopy analyses demonstrates that the catalytic activity has a maximum when the platinum film completely covers the Ni surface. The further increase of the Pt thickness leads to mechanical instability with crack formation and delamination. The effect of the foam morphology on the Pt deposition rate has been evaluated and discussed, determining the minimum Pt amount required to achieve the maximum electrochemical activity, as well as the maximum thickness in order to assure stable characteristics before delamination occurs.

Janus-micromotor-based on–off luminescence sensor for active TNT detection

An active TNT (2,4,6-trinitrotoluene) catalytic sensor based on Janus upconverting nanoparticle (UCNP)-functionalized micromotor capsules, displaying “on–off” luminescence with a low limit of detection has been developed. The Janus capsule motors were fabricated by layer-by-layer assembly of UCNP-functionalized polyelectrolyte microcapsules, followed by sputtering of a platinum layer onto one half of the capsule. By catalytic decomposition of hydrogen peroxide to oxygen bubbles, the Janus UCNP capsule motors are rapidly propelled with a speed of up to 110 μm s−1. Moreover, the Janus motors display efficient on–off luminescent detection of TNT. Owing to the unique motion of the Janus motor with bubble generation, the likelihood of collision with TNT molecules and the reaction rate between them are increased, resulting in a limit of detection as low as 2.4 ng mL−1 TNT within 1 minute. Such bubble-propelled Janus UCNP capsule motors have great potential for contaminated water analysis.