Abstract. Correct description of the boundary layer mixing process of particle is an important prerequisite to understanding the mechanism of heavy pollution episodes. Turbulent mixing process of particles is usually denoted by the turbulent diffusion relationship of heat, meaning that the turbulent transport of particles and heat are similar. This similarity has, however, never been verified. Here we investigate the dissimilarity between particles and heat, indicating that the unified treatment of all scalars in the model is questionable. Using mixing-length theory, the turbulent diffusion relationship of particle is established, embedded in the model and verified on a long-term scale. Simulated results of PM2.5 concentration were improved by 8.3 % (2013), 17 % (2014), 11 % (2015) and 11.7 % (2017) in Eastern China, respectively. However, under the influence of complex topography, the turbulent diffusion process is insensitive to the simulation of the pollutant concentration. In addition to the PM2.5 concentration, the simulation of the CO concentration has also been improved, which shows that the turbulent diffusion process is extremely critical to the change in the concentration of pollutants.