Metamorphization of zonal hydrochemical composition of surface and groundwater of Ukraine under the influence of anthropogenic and natural factors

An integrated method of functional diagnostics of basin geosystems through quantitative assessment of anthropogenic (drainage reclamation) or natural factors (climate) on the change of hydrochemical composition of surface and groundwater is presented. The method is based on the natural latitudinal and vertical zonation of the hydrochemical composition of surface and groundwater, as a manifestation of the geomembrane properties of the pedosphere. The stages of the quantitative assessment of the impact of increasing drainage reclamation areas in the Styr and Irpin river basins, were a linear regression analysis of chronological series of the content of each of the macrocomponents of the river water composition in the closing line for 1947-1989, and also the dynamics of increasing reclamation areas and correlation analysis of the obtained dependencies. To increase the closeness of the correlation, the hydrochemical composition was presented in %-equivalent form, which most accurately characterizes the ratio of macrocomponents, but does not depend on the total mineralization of water. A decrease in the content of such typomorphic ions as hydrocarbons and calcium and an increase in the content of other macrocomponents and mineralization were found statistically significantly with increasing drainage areas. In general, with increasing areas of drainage reclamation, there is an aridization of the hydrochemical composition of river water. The change of hydrochemical type of river water according to the classification of О.О. Alekina. The obtained parametric models of time trends of the content of macrocomponents of hydrochemical composition allowed to determine the limiting area of reclamation of the basins of two rivers and to predict changes in the hydrochemical type of water in the direction of its aridization. Stopping the construction of new reclamation systems and reducing the efficiency of agricultural use of drained lands leads to the restoration of the hydrochemical composition of rivers in the direction of their reclamation development. Approbation of the created method of functional diagnostics was carried out on five reclamation systems of Prykarpattia and in the basin of the Western Bug river and its branches proved its high efficiency and perspective for the creation of parametric models of the influence of natural and anthropogenic factors on chemical composition and quality of water resources.

Geochemical evaluation of soils, surface and groundwater from natural protected areas from Romania. Case studies.

The purpose of this article was to present an assessment of the soil and water quality in some protected areas from Romania in order to establish a series of geochemical thresholds on a spatial and temporal scale. The activities and results presented in this article are based on extensive monitoring, being stage results because the monitoring activities will continue, the project is ongoing. Two protected areas, Cheile Nerei -Beusnita National Park and Piatra Craiului National Park were selected. Surface water, groundwater samples, and soil samples were collected in 2019, respectively 2021 from 16 sampling sites situated in both locations. For each sample, twenty quality parameters/indicators were analyzed and the values were compared with in-force legislations. For Arsenic, Copper, and Nitrates parameters have plotted the distribution of the values in each site. In future monitoring activities, the evolution of the parameters will be followed.

Assessment of streamflows in the Hornád river basin and analysis of trends

Climate change is a global phenomenon. The more frequent occurrence of dry periods, which last longer but also extreme rainfall, needs to be reduced for better water management. During the dry season, the quantity and quality of surface and groundwater decreases. Water is important for agriculture, agriculture and ecosystems. This study was focused on the occurrence of trends in daily flows in the Hornád basin at selected hydrological stations for the period 1960-2011. The Mann-Kendall trend test is used to evaluate trends in hydrometeorological time series.

Assessment of Capacity and Impacts of 8.5 MW Gas Fired Power Plant on Soil and Water Quality in Lekki, Lagos State Nigeria

The aim of this study is to evaluate the potential impacts of 8.5 MW thermal power plant on soil and water quality within its location, Lekki area, Lagos State. The study area was geo-referenced using the existing map and Geographical Positioning System. Auger was used to sample soil at three different locations within the power plant. The soil samples were prepared and analyzed for the following parameters using standard analytical methods. The parameters include soil texture, Exchangeable cations and anions (H+, Na+, Ca2+, Mg2+, Cl- and SO42-) Nutrients compounds (NO3-, Total Nitrogen (TN), Organic Carbon (OC) and heavy metals (Fe, Cd, As, and Mn). Surface and groundwater samples were collected within the power plant in triplicate and analyzed for true colour, turbidity, conductivity, salinity, THC and Coliform. Dissolved Oxygen (DO), BOD5, Total Organic Carbon (TOC), Organic Matter (OM) and heavy metals (As, Ag, Fe and Mn) of water samples were also analyzed. The soil from the study area is loamy-sand in texture. The average As, Ag, Fe and Mn in surface and groundwater samples were 0.055, 0.025, 3.150, 0.735 and 0.12, 0.080, 6.440 and 0.180 mg/L, respectively. The gas-fired power plant has contaminated the soil and water within its premises with petroleum and heavy metals. The engine stack should be modified to minimize the pollution effects of the power plant on the environment.