Dislocation-related conductivity in Au(In)/Cd1–xZnxTe(x = 0, 0.1) Schottky contacts

Dislocation-related conductivity is studied in Schottky contacts Au(In)/Cd1-xZnxTe (x = 0, 0.1) prepared on the surface of single crystals modified by multiple irradiation with a ruby laser and mechanical polishing. The contacts were examined by measuring the DC current as a function of the applied bias and temperature as well as the photoelectric response. It is shown that both methods of surface modification result in p-to-n conversion of the conductivity type of the surface layer. The charge transfer in contacts is explained by the formation of dislocation networks buried under the surface. A model of two potential barriers is proposed for the interpretation of the photovoltaic response in contacts. Their existence is associated with compressive strains in the modified surface layer caused by dislocations, which leads to an increase in the band gap and the formation of a heterostructure.

Research of Electrolyte Plasma Treatment Impact on Wear Resistance and Roughness of 18HN3MA-SH Steel

This work provides the results of research of the wear resistance of the surface of samples of low carbon structural of 18HN3MA-SH steel, subjected to electrolytic-plasma treatment by nitriding and carbonitriding. The effect of the structure on the surface wear resistance of steel is shown. Changes in abrasive wear and dry friction characteristics were studied depending on temperature and processing time. The results of studies of tribological tests show that after electrolytic-plasma nitriding, the wear resistance of steel 18HN3MA-SH increases by 1.5–2 times compared with the initial state. The observed effects can be explained by the flowing surface modification - the formation of a modified surface layer with the formation of hardening phases. The nature of changes in the surface roughness Ra of steel samples after cementation, carbonitriding and nitriding was studied.

Plasma Electrolytic Cementation of 0.3C-1Cr-1Mn-1Si-Fe Steel

This work is devoted to research of the structural-phase condition and changes in the mechano-tribological properties of 0.3C-1Cr-1Mn-1Si-Fe structural steel after plasma electrolytic cementation. Using metallographic and X-ray analysis, mechano-tribological tests, it was found that 0.3C-1Cr-1Mn-1Si-Fe steel in the initial state belongs to the ferritic-pearlitic class, which contains ~ 65% of pearlite grain and 35% of ferrite grain. When samples of 30HGSA steel are saturated with carbon, a modified surface layer with a thickness of 25μm is formed on the surface of the studied samples, including α-Fe ferrite, cementite Fe3C, iron Fe3C2 carbide and an alloying element. It was established that the intensity of wear of the samples after modifying decreased by 2 times, and the surface microhardness after cementation increased 3 times, depending on the original sample.

OPERATIONAL PROPERTIES AND TECHNOLOGICAL CO-ACCEPTANCE OF FUNCTIONAL LAYERS AND COATINGS

The results of comparative studies of the dependence of the operational properties of surfaces with functional layers and coatings deposited on them on their technological compatibility with the main material of the parts are presented. Investigations were carried out on parts with a copper-modified surface layer, a nickel-phosphorus coating, and multicomponent functional layers based on a polymer. It has been established that the same coating or functional layer on different materials shows different values of the coefficient of friction and the different nature of its change from the time of contact interaction with the counterbody, as well as different indicators of endurance and corrosion-fatigue strength, which is explained by their technological compatibility with the main material of the part, depending on the method of preliminary surface treatment.

COMPARISON OF SALT BATH PREOXIDATION AND AIR PREOXIDATION FOR SALT BATH NITRIDING

<p class="AMSmaintext1">Salt bath preoxidation was primarily conducted prior to salt bath nitriding, and the effect on salt bath nitriding was compared with that of conventional air preoxidation. Characterization of the modified surface layer was made by means of optical microscopy, scanning electron microscope (SEM), micro-hardness tester and x-ray diffraction (XRD). The results showed that the salt bath preoxidation could significantly enhance the nitriding efficiency. The thickness of compound layer was increased from 13.3μm to 20.8μm by salt bath preoxidation, more than 60% higher than that by conventional air preoxidation under the same salt bath nitriding parameters of 560℃ and 120min. Meanwhile, higher cross-section hardness and thicker effective hardening layer were obtained by salt bath preoxidation, and the enhancement mechanism of salt bath preoxidation was discussed.</p>

Исследование изменения микротвердости поверхности циркония после лазерной модифицирующей обработки

The results of an investigation of the process of laser-induced hardening of zirconium (E110 alloy) are reported. It has been established that the laser treatment in air results in the formation of a uniformly distributed microrelief characterized by the presence of microparticles with various configurations. Overlap of the laser beam trajectories leads to the formation of a layered structure. The composition of laser-modified surface depends on the regime of processing and mostly comprises a mixture of zirconium oxides and nitrides. In addition, the formation of diffuse transition zones between the bulk metal and modified surface layer is established. The dependence of the thickness of the hardened layer on the regime of pulsed laser action is determined.