This chapter examines how electromagnetic waves—light, photons—interact with semiconductors through coupling between the electromagnetic wave and dipoles of various kinds and analyzed via a dipole interaction Hamiltonian. Phenomena in the energy range of micro eV to several eVs are explored, stressing surface interactions, absorption, emission and luminescence. The first involves coupled plasmon interactions. Absorption and emission arise across energy and through multiple mechanisms. Free carrier processes are pronounced for low energy. Direct electron-photon interactions—a direct transition—can involve allowed transitions and forbidden transitions across the gap. Indirect transitions of both these varieties can arise in phonon-assisted processes. Oscillator strength is fleshed out. Field dependence, doping dependence and temperature dependence are analyzed, broadening the discussion to the Franz-Keldysh effect as well as dependence due to impurities, excitons, plasmons and crystal oscillations, to unravel the dielectric function and reflectivity’s behavior at high frequencies and restrahlen often observed.