Effect of TiO2 on the Sintering Behavior of Low-Grade Vanadiferous Titanomagnetite Ore

Low-grade vanadiferous titanomagnetite ore (LVTM) is as an important mineral resource for sintering ore manufacturing. Furthermore, TiO2 has a significant effect on the sintering process of iron ore fines. The effects of TiO2 on the metallurgical properties, microstructure, and mineral composition of LVTM sinter were investigated by sintering pot tests, X-ray diffraction (XRD), scanning electron microscopy (SEM), and mineral phase microanalysis. The results were as follows: as the TiO2 content increased from 1.75% to 4.55%, the flame front speed and productivity decreased, while the reduction degradation index (RDI) and softening properties deteriorated. In addition, the tumbler index (TI) values reached a maximum at TiO2 = 1.75%. In addition, with increasing TiO2 content, an increase in the magnetite and perovskite phase, and a decrease in calcium ferrite and hematite were found with an increase in TiO2 content. Thus, the lower the TiO2 content, the better the quality of the sinter.

Non-Isothermal Reduction Kinetics of Iron Ore Fines with Carbon-Bearing Materials

This study investigates the non-isothermal reduction of iron ore fines with two different carbon-bearing materials using the thermogravimetric technique. The iron ore fines/carbon composites were heated from room temperature up to 1100 °C with different heating rates (5, 10, 15, and 20 °C/min) under an argon atmosphere. The effect of heating rates and carbon sources on the reduction rate was intensively investigated. Reflected light and scanning electron microscopes were used to examine the morphological structure of the reduced composite. The results showed that the heating rates affected the reduction extent and the reduction rate. Under the same heating rate, the rates of reduction were relatively higher by using charcoal than coal. The reduction behavior of iron ore-coal was proceeded step wisely as follows: Fe2O3 → Fe3O4 → FeO → Fe. The reduction of iron ore/charcoal was proceeded from Fe2O3 to FeO and finally from FeO to metallic iron. The reduction kinetics was deduced by applying two different methods (model-free and model-fitting). The calculated activation energies of Fe2O3/charcoal and of Fe2O3/coal are 40.50–190.12 kJ/mole and 55.02–220.12 kJ/mole, respectively. These indicated that the reduction is controlled by gas diffusion at the initial stages and by nucleation reaction at the final stages.

Design modification of iron ore bearing transfer chute using discrete element method

Purpose The dryer feed chute of the pellet plant plays an important role in the pelletizing process. The chute discharges sticky and moist iron ore fines (<1 mm) to the inline rotary dryer for further processing. Since the inception of the installation of the dryer feed chute, the poor flowability of the feed materials has caused severe problems such as blockages and excessive wear of chute liners. This leads to high maintenance costs and reduced lifetime of the liner materials. Constant housekeeping is needed for maintaining the chute and reliable operation. The purpose of this study is to redesign the dryer feed chute to overcome the above challenges. Design/methodology/approach The discrete element method (DEM) has been used to model the flow of cohesive materials through the transfer chute. Physical experiments have been performed to understand the most severe flow conditions. A DEM material model is also developed for replicating the worst-case material condition. After identifying the key problem areas, concept designs were proposed and simulated to assess the design improvements to increase the reliability of chute operation. Findings Flow simulations correlated well with the existing flow behavior of the iron ore fines inside the chute. The location of the problematic areas has been validated with that of the previously installed chute. Subsequently, design modifications have been proposed. This includes modification of deflector plate and change in slope and cross-section of the chute. DEM simulations and analysis were conducted after incorporating these design changes. A comparison in the average velocity of particle and force on chute wall shows a significant improvement using the proposed design. Originality/value Method to calibrate DEM material model was found to provide accurate prediction and modeling of the flow behavior of bulk material through the real transfer chute. DEM provided greater insight into the performance of the chute especially modeling cohesive materials. DEM is a valuable design tool to assist chute designers troubleshoot and verify chute designs. DEM provides a greater ability to model and assess chute wear. This technique can help in achieving a scientific understanding of the flow properties of bulk solids through transfer chute, hence eliminate challenges, ensuring reliable, uninterrupted and profitable plant operation. This paper strongly advocates the use of calibrated DEM methodology in designing bulk material handling equipment.