Influence of granitic rock fines addition in the alkali-aggregate reaction (AAR) in cementitious materials

According to previous studies, fine materials originated from reactive aggregates can act as a Alkali-Aggregate Reaction mitigator, having its effectiveness dependent on their reactivity, fineness and added content. Thus, the present work aims to study if reactive granitic rock fines can mitigate or reduce the AAR and how the fineness of the material influences its mitigation capacity. For this purpose, granitic rock fines (GRF) from 2 different deposits and Pyrex glass fines (PGF) were tested as concrete addition. Each one of these fines were used in two different finesses and added to the concrete in the contents of 20% by mass of cement. It was observed that the addition of GRF did not affect the physical-mechanical properties of concrete and allowed the reduction in the AAR, being more accentuated with the increase of its specific surface.

Monolithically Integrated Diffused Silicon Two-Zone Heaters for Silicon-Pyrex Glass Microreactors for Production of Nanoparticles: Heat Exchange Aspects

We present the design, simulation, fabrication and characterization of monolithically integrated high resistivity p-type boron-diffused silicon two-zone heaters in a model high temperature microreactor intended for nanoparticle fabrication. We used a finite element method for simulations of the heaters’ operation and performance. Our experimental model reactor structure consisted of a silicon wafer anodically bonded to a Pyrex glass wafer with an isotropically etched serpentine microchannels network. We fabricated two separate spiral heaters with different temperatures, mutually thermally isolated by barrier apertures etched throughout the silicon wafer. The heaters were characterized by electric measurements and by infrared thermal vision. The obtained results show that our proposed procedure for the heater fabrication is robust, stable and controllable, with a decreased sensitivity to random variations of fabrication process parameters. Compared to metallic or polysilicon heaters typically integrated into microreactors, our approach offers improved control over heater characteristics through adjustment of the Boron doping level and profile. Our microreactor is intended to produce titanium dioxide nanoparticles, but it could be also used to fabricate nanoparticles in different materials as well, with various parameters and geometries. Our method can be generally applied to other high-temperature microsystems.

A Novel 3D Encapsulation Structure Based on Subwavelength Structure and Inserted Pyrex Glass for RF MEMS Infrared Detectors

A novel wafer-level three-dimensional (3D) encapsulation structure was designed for radio-frequency microelectromechanical system (RF MEMS) infrared detectors and investigated by using the finite element method (FEM) simulation. A subwavelength structure with a circular array of coaxial apertures was designed to obtain an extraordinary optical transmission (EOT) on top of a silicon substrate. For perpendicular incident light, a maximum transmission of 56% can be achieved in the long-wave infrared (LWIR) region and the transmission bandwidth covered almost the full LWIR region. Moreover, the maximum transmission could be further promoted with an increase in the incident angle. The vertical silicon vias, insulated by inserted Pyrex glass, were used to generate electrical contacts. With the optimized structure parameters, a feed-through level lower than −82 dB, and a transmission coefficient of one single via of more than −0.032 dB were obtained at a frequency from 0 to 2 GHz, which contributed to the low-loss transmission of the RF signals. Due to the matched thermal expansion coefficients (TECs) between silicon and Pyrex glass, the proposed via structure has excellent thermal reliability. Moreover, its thermal stress is much less than that of a conventional through-silicon via (TSV) structure. These calculated results demonstrate that the proposed 3D encapsulation structure shows enormous potential in RF MEMS infrared detector applications.

CHARACTERIZATION OF OCTADECYLTRICHLOROSILANE SELF-ASSEMBLED MULTILAYERS ON PYREX GLASS

In this paper, octadecyltrichlorosilane (OTS) self-assembled multilayer (SAM) films are fabricated on Pyrex glass by dipping method. The hydrophobicity, constituent and surface morphology of OTS SAM at various dipping times in solutions of 1, 2 and 5[Formula: see text]mM concentrations are investigated. Characteristic absorption peaks around 2850 and 2920[Formula: see text]cm[Formula: see text] are observed by FTIR and island-like structures on samples are detected by AFM. After 15[Formula: see text]min dipping time for solution of 5[Formula: see text]mM, water contact angle of the sample reaches the maximum value of 116.4[Formula: see text] with relatively low surface root mean square (Rms) roughness of 0.152[Formula: see text]nm. The critical surface tension ([Formula: see text] of the analyzed sample is 18.2[Formula: see text]dyne/cm. The optimum dipping time in the solution of 5[Formula: see text]mM for a complete SAM film is about 30[Formula: see text]min. The study of the optimal conditions for the formation of integrated OTS SAM has significant scientific and practical values in modification of solid surfaces.